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排序方式: 共有2798条查询结果,搜索用时 15 毫秒
71.
72.
Mohammad Soheilmoghaddam Pooria Pasbakhsh Mat Uzir Wahit Hossein Cheraghi Bidsorkhi Raheleh Heidar Pour Wong Tuck Whye R.T. De Silva 《Polymer》2014
Green nanocomposites of regenerated cellulose/exfoliated graphite nanosheets films with low nanofiller loadings were prepared using environmentally benign 1-butyl-3-methylimidazolium chloride (BMIMCl) ionic liquid. X-ray diffraction revealed well developed intercalated nanocomposites. The tensile strength and Young's modulus of the prepared nanocomposites were increased by 97.5% and 172% respectively when 0.75 wt.% and 1 wt.% exfoliated graphite nanosheets were added. The results were validated using the Halpin–Tsai model. The exfoliated graphite nanosheets were unidirectionally aligned in the regenerated cellulose parallel to the surface of the nanocomposites as revealed by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM). Also, the TEM and FESEM revealed uniform dispersion of the exfoliated graphite nanosheets and good interaction between the nanofillers and the matrix. The addition of the exfoliated graphite nanosheets enhanced the thermal stability and reduced the water absorption and diffusivity of the nanocomposites. 相似文献
73.
Amir Saeid Pakdel Mohammad Reza Saeb Hossein Abedini Hossein Ali Khonakdar Regine Boldt 《Polymer Bulletin》2014,71(10):2487-2506
This work is targeted to study emulsion polymerization of vinyl chloride monomer (VCM) using experimental and mathematical methods. To fulfill this goal, a computer code was developed on the basis of zero–one population balance by which the effects of initiator and emulsifier concentration on the evolution of VCM conversion were investigated in the course of polymerization. The model was also trained to capture the coagulation of the particles. This enabled to adopt a reliable way of evaluating the particle size distribution (PSD). In particular, the rates of homogeneous and micellar nucleation mechanisms were simulated and reasonably predicted alterations in the PSD and the number of polymer particles under the influence of aforementioned parameters. The results from modeling were satisfactorily consistent with the experimental outputs and obviously visualized the impact of initiator and surfactant concentration on the PSD of the prepared PVC latexes. 相似文献
74.
Hasan Kouchakzadeh Seyed Abbas Shojaosadati Fazel Shokri 《Chemical Engineering Research and Design》2014
Herein, the poorly water-soluble drug, Tamoxifen (Tmx), was loaded in the amphipathic matrix of human serum albumin (HSA) nanoparticles by a modified desolvation method. In order to enhance the drug loading (DL) and drug entrapment efficiency (DEE) (<2% and 10%, respectively), ultrasonication of Tmx-HSA mixture was performed prior to desolvation process. Tmx loading and entrapment efficiency were optimized by employment of the response surface methodology (RSM)-central composite design (CCD) of experiments. Under the optimum conditions of 1.59 mg Tmx/ml concentration, 7.76 pH and 5 h incubation of HSA-Tmx, the DL of 6.7% and DEE of 74% are achievable. Particles with the average size of 195 nm, zeta potential of −21 mV and polydispersity index of 0.09 were produced under these conditions. A more sustained Tmx release behavior was observed from polyethylene glycol (PEG) conjugated nanoparticles in comparison to the non-PEGylated ones. The short-term stability investigation showed no alteration in physicochemical properties of nanoparticles at 4 and 37 °C, but small increase in nanoparticles size was observed after three months of storage at room temperature. This is the first report for efficient production of a Tmx delivery system based on HSA nanoparticles. 相似文献
75.
Ahmad Hosseini-Bandegharaei Mohammad Karimzadeh Masoud Sarwghadi Aliasghar Heydarbeigi Seyyed Hossein Hosseini Mehdi Nedaie Hassan Shoghi 《Chemical Engineering Research and Design》2014
Adsorption of Pb(II) ion by a novel extractant-impregnated resin, EIR, was studied as a function of various experimental parameters using batch adsorption experiments. The new EIR was prepared by impregnating gallocyanine (GCN) onto Amberlite XAD-16 resin beads. The EIR was characterized by nitrogen analysis and SEM micrographs. The new EIR showed excellent selectivity factor values (α) for Pb(II) adsorption respect to other metal ions. The effects of some chemical and physical variables were evaluated and the optimum conditions were found for Pb(II) removal from aqueous solutions. The equilibrium adsorption isotherm was fitted with the Langmuir adsorption model. The maximum adsorption capacity (qmax) of EIR for Pb(II) ions was found to be 367.92 mg g−1. The kinetic studies showed that the intra-particle diffusion is the rate-controlling step. Also, the intra-particle diffusion coefficients, Dip values, were of the order of 10−12 m2 s−1. The values of enthalpy (ΔH°) were positive, which confirms the endothermic nature of adsorption process. Also, the positive entropy changes (ΔS°) were showed that the randomness increased along with the adsorption process. In addition, the obtained negative values of Gibbs free energy (ΔG°) indicated feasible and spontaneous nature of the adsorption process at different temperatures. The new adsorbent was very stable so that it can be successfully used for many consecutive cycles without significant loss in its adsorption capacity. 相似文献
76.
Recent Developments in Predicting Impact and Shock Sensitivities of Energetic Materials (英) 总被引:1,自引:0,他引:1
Mohammad Hossein Keshavarz Arash Shokrolahi Karim Esmailpoor Abbas Zali Hamid Reza Hafizi Jamshid Azarniamehraban 《含能材料》2008,16(1):113-120
Empirical, quantum mechanical and artificial neural network methods are three usual methods in recent years that were used to predict sensitivity of different classes of high explosives. Some recent developments in predicting sensitivity by various methods are reviewed and discussed for various classes of energetic materials. 相似文献
77.
Phase behaviour modelling of reservoir fluid is a fundamental step for reservoir simulation. Furthermore, as the complexity of the recovery process increases, the fluid model plays a more important role in the reliability of the simulation outputs. Although the in situ combustion enhanced oil recovery method (ISC) is one of the most complex recovery techniques available in the petroleum engineering literature, for most of the simulation jobs related to this elaborate process only simple and rudimentary fluid characterization layouts are considered. In this work, the principal fluid properties of Athabasca bitumen with regard to the ISC process are recognized, extracted from the literature, validated for consistency, and used for the development of an inclusive and accurate fluid model. Then the fluid model is fully developed while considering the ISC reaction kinetics so that the model has both accuracy, indispensable for phase behaviour modelling, and consistency, essential for the reactions definitions. 相似文献
78.
Akylbek Sydykov Himal Luitel Argen Mamazhakypov Malgorzata Wygrecka Kabita Pradhan Oleg Pak Aleksandar Petrovic Baktybek Kojonazarov Norbert Weissmann Werner Seeger Friedrich Grimminger Hossein Ardeschir Ghofrani Djuro Kosanovic Ralph Theo Schermuly 《International journal of molecular sciences》2020,21(23)
Although the response of the right ventricle (RV) to the increased afterload is an important determinant of the patient outcome, very little is known about the underlying mechanisms. Mast cells have been implicated in the pathogenesis of left ventricular maladaptive remodeling and failure. However, the role of mast cells in RV remodeling remains unexplored. We subjected mast cell-deficient WBB6F1-KitW/W-v (KitW/KitW-v) mice and their mast cell-sufficient littermate controls (MC+/+) to pulmonary artery banding (PAB). PAB led to RV dilatation, extensive myocardial fibrosis, and RV dysfunction in MC+/+ mice. In PAB KitW/KitW-v mice, RV remodeling was characterized by minimal RV chamber dilatation and preserved RV function. We further administered to C57Bl/6J mice either placebo or cromolyn treatment starting from day 1 or 7 days after PAB surgery to test whether mast cells stabilizing drugs can prevent or reverse maladaptive RV remodeling. Both preventive and therapeutic cromolyn applications significantly attenuated RV dilatation and improved RV function. Our study establishes a previously undescribed role of mast cells in pressure overload-induced adverse RV remodeling. Mast cells may thus represent an interesting target for the development of a new therapeutic approach directed specifically at the heart. 相似文献
79.
Sakhaeinia Hossein Zare-Neyestanak Elaheh Shokouhi Mohammad 《Theoretical Foundations of Chemical Engineering》2020,54(5):949-960
Theoretical Foundations of Chemical Engineering - In this study the solubility of Hydrogen Sulfide (H2S) in four ionic liquids: 1-Ethyl-3-methylimidazoliom Hexafluorophosphate [Emim][PF6],... 相似文献
80.
Today, millions of electrocommunication, electric, medical, and industrial devices use battery. Batteries with long life and high energy density seem to be essential in medical, military, oil and mining, aerospace areas as well as conditions in which access is difficult and in situations where replacement or recharging of battery is costly.In this regard, the use of radiation energy resulting from radioactive materials and its conversion to electric energy can be effective in making batteries. In the present study,various Mo-99 radioisotope values with a half-life of 65.98 h were used as a soluble radioactive source in two materials of water and aqua regia. Then, by comparing the results of the Monte Carlo simulations program MCNPX for these two solutions, it was found that when the water is used instead of aqua regia(for idealization), the values of the superficial current of electrons, the volumetric flux of electrons, and the deposited energy in the volume containing the radioactive solution increased by 10.80, 4.10,and 13.80%, respectively. Also, the short-circuit current and energy conversion efficiency of this battery with a concentration of 0.01 molar, Mo-99 dissolved in the aqua regia are 0.79μA and 16.47%, respectively. 相似文献