Emerging porous nanosheets: From fundamental synthesis to promising applications

Metal-organic framework(MOF)nanosheets and covalent organic framework(COF)nanosheets as emerging porous materials nanosheets have captured increasing attention owing to their attractive properties originating from the advantages of large lateral size,ultrathin thickness,tailorable physiochemical environment,flexibility and highly accessible active sites on surface,and the applications of them have been explored in a wide range of fields.Although MOF and COF nanosheets own many similar properties,their applications in various fields show significant differences,probably due to their different compositions and bonding modes.Hence,we summarize the recent progress of MOF and COF nanosheets by comparative analysis on their advantages and limitations in synthesis and applications,providing a more profound and full-scale perspective for researchers or beginners to understand this field.Herein,the categories of preparation methods of MOF and COF nanosheets are firstly discussed,including top-down and bottom-up methods.Secondly,the applications of MOF and COF nanosheets for separation,catalysis,sensing and energy storage are summarized.Finally,based on current achievements,we put forward our personal insights into the challenges and outlooks on the synthesis,characterizations,and promising applications for future research of MOF and COF nanosheets.     

The effect of ISO 9000 implementation on flow management

This study proposes an innovative flow management system that includes product (product and logistics) and process (human, information and decision) flow management. We identify three levels of ISO 9000 implementation (basic, advanced and supportive) as enablers, and operational performance as the outcome. The model was tested using the data-set collected from 133 ISO 9001 certified manufacturing companies in Australia. The results show that advanced implementation is positively related to both product and process flow management; supportive implementation is only positively related to process flow management while basic implementation has no significant effect on either product or process flow management. The results also show that both product and process flow management are positively related to operational performance. This study provides managerial guidelines for companies that wish to improve their innovation capabilities through ISO 9000 implementation and flow management. It also contributes to the ISO 9000 and flow management literature.     

Critical Relation Path Aggregation-Based Industrial Control Component Exploitable Vulnerability Reasoning

With the growing discovery of exposed vulnerabilities in the Industrial Control Components (ICCs), identification of the exploitable ones is urgent for Industrial Control System (ICS) administrators to proactively forecast potential threats. However, it is not a trivial task due to the complexity of the multi-source heterogeneous data and the lack of automatic analysis methods. To address these challenges, we propose an exploitability reasoning method based on the ICC-Vulnerability Knowledge Graph (KG) in which relation paths contain abundant potential evidence to support the reasoning. The reasoning task in this work refers to determining whether a specific relation is valid between an attacker entity and a possible exploitable vulnerability entity with the help of a collective of the critical paths. The proposed method consists of three primary building blocks: KG construction, relation path representation, and query relation reasoning. A security-oriented ontology combines exploit modeling, which provides a guideline for the integration of the scattered knowledge while constructing the KG. We emphasize the role of the aggregation of the attention mechanism in representation learning and ultimate reasoning. In order to acquire a high-quality representation, the entity and relation embeddings take advantage of their local structure and related semantics. Some critical paths are assigned corresponding attentive weights and then they are aggregated for the determination of the query relation validity. In particular, similarity calculation is introduced into a critical path selection algorithm, which improves search and reasoning performance. Meanwhile, the proposed algorithm avoids redundant paths between the given pairs of entities. Experimental results show that the proposed method outperforms the state-of-the-art ones in the aspects of embedding quality and query relation reasoning accuracy.     

Homologous Heterostructured NiS/NiS2@C Hollow Ultrathin Microspheres with Interfacial Electron Redistribution for High-Performance Sodium Storage

Nickel sulfides with high theoretical capacity are considered as promising anode materials for sodium-ion batteries (SIBs); however, their intrinsic poor electric conductivity, large volume change during charging/discharging, and easy sulfur dissolution result in inferior electrochemical performance for sodium storage. Herein, a hierarchical hollow microsphere is assembled from heterostructured NiS/NiS₂ nanoparticles confined by in situ carbon layer (H-NiS/NiS₂@C) via regulating the sulfidation temperature of the precursor Ni-MOFs. The morphology of ultrathin hollow spherical shells and confinement of in situ carbon layer to active materials provide rich channels for ion/electron transfer and alleviate the effects of volume change and agglomeration of the material. Consequently, the as-prepared H-NiS/NiS₂@C exhibit superb electrochemical properties, satisfactory initial specific capacity of 953.0 mA h g⁻¹ at 0.1 A g⁻¹, excellent rate capability of 509.9 mA h g⁻¹ at 2 A g⁻¹, and superior longtime cycling life with 433.4 mA h g⁻¹ after 4500 cycles at 10 A g⁻¹. Density functional theory calculation shows that heterogenous interfaces with electron redistribution lead to charge transfer from NiS to NiS₂, and thus favor interfacial electron transport and reduce ion-diffusion barrier. This work provides an innovative idea for the synthesis of homologous heterostructures for high-efficiency SIB electrode materials.     

蚌埠市生活垃圾填埋场工程地质勘察

蚌埠市生活垃圾填埋场工程是城市基础设施,该工程规模大,位于平山半山坡上,工程区地质条件复杂,工作难度大,防渗设计要求严苛.本勘察项目采用钻探、原位取土试样、标准贯入试验、单孔法波速测试试验、室内土工试验、岩石饱和单轴抗压强度试验、水质分析等综合手段勘察,取得了科学准确的参数.本文对填埋场的地基持力层的选择、设计参数、防渗处理等提出了经济合理的结论和建议,为优化设计、节省投资、安全施工奠定了基础.     

基于STD工控机的浓密自动控制系统

根据浓密工艺特点 ,采用STD工控机和模糊控制技术开发了浓密自动控制系统。该系统在红布金矿成功应用 ,具有性价比高 ,稳定可靠的特点。本文对控制任务 ,控制方案 ,系统特点 ,系统设计进行了介绍     

Effect of the Inside Placement of Electrically Conductive Beads on Electric Field Uniformity in a Microwave Applicator

Non-uniform heating is a major issue in microwave applications, mainly due to inherently uneven distribution of electromagnetic energy in the microwave applicator. In this work, our aim is to improve electric field distribution uniformity by utilizing microwave reflection from electrically conductive beads placed in the microwave oven. The effects of position, size, and number of electrically conductive beads on the electric field distribution were numerically investigated, and validated through water-load experiments in the cavity. It is found that uniform electric field distribution was realized to some extent by appropriate placement of electrically conductive beads; meanwhile, average electric field intensity in the microwave oven was increased.     

基于连续级配方程的粗粒料压实密度缩尺效应试验研究

根据双江口心墙堆石坝堆石料的原型平均设计级配曲线,采用剔除法、等量替代法、相似级配法和混合法等4种不同缩尺方法得到室内最大干密度试验成果。结合土的连续级配方程,采用级配面积与小于5 mm的颗粒质量分数P₅构建的函数式作为级配量化指标,拟合出最大干密度与试验前级配曲线面积、P₅及最大粒径之间的关系,据此可推求出原型级配的最大干密度。通过分析得到试验前后级配量化指标之间的拟合公式,并利用试验前后级配量化指标的相对变化量B_w作为颗粒破碎的定量指标,探讨了缩尺方法对压实过程粗粒料颗粒破碎的影响。结果表明,采用等量替代法缩尺,B_w随粒径的增大呈减小趋势;而采用剔除法、相似级配法和混合法缩尺,B_w随粒径增大呈增大趋势。     

技术之巅的生态表达--诺曼·福斯特建筑创作新趋势

近年来,福斯特凭借技术优势,将生态概念引入建筑设计中,创作了许多成功作品,实现以技术服务大众的梦想.该文通过对福斯特生态策略的深入分析,结合实例,探讨了其建筑创作的新趋势.     

一种检测运行栈与静态数据区重叠的新方法

嵌入式系统中由于内存限制,容易出现运行栈和数据区重叠的错误。已有的两种检测该错误的方法在准确性和易用性方面存在缺陷,不适用于基于软件模拟器的大规模回归测试。文章通过改变运行栈与静态数据区的布局,将运行栈与静态数据区重叠的错误转化为运行栈超越内存地址空间的错误。新方法大大简化了这种运行时错误的检测和调试。