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141.
Having analyzed the drawbacks on the design of control system of hydraulic momentadjusted brake system, the author presents a closed loop control system in the process of start and braking of the conveyer. On the basis of the concept of the critical time and the critical acceleration and its deductions, the working mode of the conveyer can be identified and controlled in feedback, furthermore, thus realize the process of soft start. In the deceleration process, the author points out the problems that exist in the present control system and sets forward the control process that acted by the combined function of brake moment of motor and the drag torque of hydraulic brake at the beginning of deceleration, it will further improved reliability of conveyor system. 相似文献
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Catalysis Letters - Photocatalytic technology provides a new strategy for mitigating energy crisis. The development of photocatalytic materials with high efficiency and stable visible light... 相似文献
145.
Linlin You Yandong Guo Yanjing He Feng Huo Shaojuan Zeng Chunshan Li Xiangping Zhang Xiaochun Zhang 《Frontiers of Chemical Science and Engineering》2022,16(2):141
Ionic liquid(IL)/polyimide(PI)composite membranes demonstrate promise for use in CO2separation applications.However,few studies have focused on the microscopic mechanism of CO2in these composite systems,which is important information for designing new membranes.In this work,a series of systems of CO2in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide composited with 4,4-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)-based PI,6FDA-2,3,5,6-tetramethyl-1,4-phenylene-diamine,at different IL concentrations were investigated by all-atom molecular dynamics simulation.The formation of IL regions in PI was found,and the IL regions gradually became continuous channels with increasing IL concentrations.The analysis of the radial distribution functions and hydrogen bond numbers demonstrated that PI had a stronger interaction with cations than anions.However,the hydrogen bonds among PI chains were destroyed by the addition of IL,which was favorable for transporting CO2.Furthermore,the self-diffusion coefficient and free energy barrier suggested that the diffusion coefficient of CO2decreased with increasing IL concentrations up to 35 wt-%due to the decrease of the fractional free volume of the composite membrane.However,the CO2selfdiffusion coefficients increased when the IL contents were higher than 35 wt-%,which was attributed to the formation of continuous IL domain that benefitted the transportation of CO2. 相似文献
146.
Yan Shi Fangjun Huo Yongkang Yue Caixia Yin 《Frontiers of Chemical Science and Engineering》2022,16(1):64
Heterocyclic compound quinoline and its derivatives exist in natural compounds and have a broad spectrum of biological activity.They play an important role in the design of new structural entities for medical applications.Similarly,indoles and their derivatives are found widely in nature.Amino acids,alkaloids and auxin are all derivatives of indoles,as are dyes,and their condensation with aldehydes makes it easy to construct reaction sites for nucleophilic addition agents.In this work,we combine these two groups organically to construct a rapid response site(within 30 s)for H2S,and at the same time,a ratiometric fluorescence response is presented throughout the process of H2S detection.As such,the lower detection limit can reach 55.7 nmol/L for H2S.In addition,cell imaging shows that this probe can be used for the mitochondrial targeted detection of endogenous and exogenous H2S.Finally,this probe application was verified by imaging H2S in nude mice. 相似文献
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This work has obtained polyaniline/manganese dioxide (PANI/MnO2) nanofibers microsphere by interfacial chemical synthesis with 4‐amino‐thiophenol (4‐ATP) as the structure‐directing agent on the Au substrate. The cyclic voltammograms, galvanostatic charge–discharge, and electrochemical impedance spectroscopy were used to determine their capacitive performance. Powder X‐ray diffraction, thermogravimetry and differential scanning calorimetry, Fourier transformed infrared spectroscopy, Brunauer–Emmett–Teller surface area measurements, and scanning electron microscope were performed for physical and chemical characterization. The effect of 4‐ATP and acids on the capacitive performance of PANI/MnO2 nanofibers microsphere was elucidated. The as‐prepared PANI/MnO2 was nanofiber about 30 nm diameters, and they further self‐assembled into sphere. Its specific capacitance is up to 765 F g?1 at 1.0 mA cm?2 in 1.0M Na2SO4 solution. And it shows a high stability with a capacitance fade of only 14.9% after 400 charge–discharge cycles. The symmetric capacitor of PANI/MnO2 (PM10+)/PANI/MnO2 (PM10?) is assembled in 1.0M Na2SO4 solution, and its capacitive performance is compared with that of PANI (+)/PANI (?) and MnO2 (+)/MnO2 (?). © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40575. 相似文献
149.
Doubly thermo-responsive brush-linear diblock copolymers and formation of core-shell-corona micelles
Doubly thermo-responsive brush-linear diblock copolymer of poly[poly(ethylene glycol) methyl ether vinylphenyl]-block-poly(N-isopropylacrylamide) (PmPEGV-b-PNIPAM) is prepared by RAFT polymerization. The obtained brush-linear diblock copolymer exhibits two lower critical solution temperatures (LCSTs) corresponding to the linear poly(N-isopropylacrylamide) (PNIPAM) block and the brush poly[poly(ethylene glycol) methyl ether vinylphenyl] (PmPEGV) block in water. This brush-linear diblock copolymer undergoes a two-step temperature sensitive micellization. At temperature above the first LCST, the brush-linear diblock copolymer self-assembles into core-corona micelles with the dehydrated PNIPAM block forming the core and the solvated brush PmPEGV block forming the corona. When temperature increases above the second LCST, the polystyrene backbone in the brush PmPEGV block collapses onto the dehydrated PNIPAM core to form core-shell-corona micelles, in which the dehydrated PNIPAM block forms the core, the collapsed polystyrene backbone in the brush PmPEGV block forms the shell and the solvated poly(ethylene glycol) side-chains forms the corona. The effect of the length of the PNIPAM block and the length of the poly(ethylene glycol) side-chains on the thermo-responsive micellization and the size of core-shell-corona micelles is investigated. 相似文献
150.
Non-uniform heating is a major issue in microwave applications, mainly due to inherently uneven distribution of electromagnetic energy in the microwave applicator. In this work, our aim is to improve electric field distribution uniformity by utilizing microwave reflection from electrically conductive beads placed in the microwave oven. The effects of position, size, and number of electrically conductive beads on the electric field distribution were numerically investigated, and validated through water-load experiments in the cavity. It is found that uniform electric field distribution was realized to some extent by appropriate placement of electrically conductive beads; meanwhile, average electric field intensity in the microwave oven was increased. 相似文献