Comparative study of high concentrating photovoltaics integrated with phase‐change liquid film cooling system

In high concentrating photovoltaic systems, thermal regulation is of great importance to the conversion efficiency and the safety of solar cells. Direct‐contact liquid film cooling technique is an effective way of thermal regulation with low initial investment. Tilt of solar cells is common in concentrating solar systems. An evaluation of direct‐contact liquid film cooling technique behind tilted high concentration photovoltaics was performed using both experimental and computational approaches. In the experiment, deionized water was used as the coolant at the back of simulated solar cells. Solar cell inclination of 0° to 75° with inlet water flow rate of 100–300 L/hour and inlet temperature of 30°C to 75°C were experimentally investigated. A two‐dimensional model was developed using computational fluid dynamics technique and validated by experimental results. The effects of inclination on average temperature, temperature uniformity, and heat transfer coefficient were discovered in this paper. The results indicated that 20° is the optimum angle for liquid film cooling. In addition, optimum inlet width, temperature, and velocity for inclination over 30° are 0.75 mm, 75°C, and 0.855 m/s, respectively.     

1 000 MW高效宽负荷率的超超临界锅炉开发

根据反平衡法对电站锅炉各项效率损失进行分析,潜力较大的是排烟损失和未完全燃烧损失,主要影响因素有过量空气系数、排烟温度、燃烧效率;1 000 MW高效宽负荷率超超临界煤粉锅炉的开发采用低过量空气系数设计理念,在炉膛选型、受热面布置、燃烧系统设计、降低锅炉漏风等方面采取措施。与传统设计相比,50% THA负荷下锅炉效率提升了0.96%。     

Deformation and fracture mechanisms of in situ synthesized TiC reinforced TC4 matrix composites produced by selective laser melting

In this study, TiC/TC4 composites were fabricated using selective laser melting (SLM), and the deformation mechanism and fracture characteristics of the composites with nano-sized TiC particles formed in situ were studied. The experimental results showed that the rapid melting and solidification characteristics of SLM and the Marangoni effect of the liquid pool promoted a considerably homogeneous dispersion of the in situ-formed nanoscale-TiC reinforcement in the TiC/TC4 composites. In particular, an enhanced compressive strength of 1490.2 MPa and a considerable fracture elongation of 21.5% were simultaneously achieved for the TiC/TC4 composites, which could be attributed to the load transfer effect and the formation of denser and more uniformly distributed dimples. Combined with the finite element (FE) analysis, the uneven stress distribution in the shear band of the TiC/TC4 composites led to the fracture. Further, the fracture surface analysis showed that the in situ nanoscale TiC reinforcement promoted the fracture of microbubbles from the α/β interface with the concentrated distribution of the V element to the interface between TiC and the Ti matrix because of the load transfer, which promoted the uniform distribution of the V element in the dimple.     

Electrochemical performance of in situ LiFePO4 modified by N-doped graphene for Li-ion batteries

LiFePO₄ modified by N-doped graphene (NG) with a three-dimensional conductive network structure was synthesized via a one-step in situ hydrothermal method. The effects of N amount of NG on the phase structure, morphology, and electrochemical properties of LiFePO₄ are investigated in this study. X-ray diffraction (XRD) results show that doping suitable N amounts in NG do not alter the crystal structure of LiFePO_4, and scanning electron microscopy (SEM) images show that NG can slightly reduce the particle size of LiFePO₄. The high-resolution transmission electron microscopy (HRTEM) results show that the LiFePO₄ particles are well covered and connected by NG. The electrochemical performance confirms that LiFePO₄ modified by 20% N-doped graphene (named LFP/NG-4) displays a perfect specific capacity of 166.6 mAh·g^?1 at a rate of 0.2C and can reach 125 mAh·g^?1 at a rate of 5 C. Electrochemical impedance spectroscopy (EIS) results illustrate that the charge transfer resistance value of the LFP/NG-4 composite is only 58.6 Ω, which is very low compared with LiFePO₄. Cyclic voltammetry (CV) tests indicate that the addition of 20% N-doped graphene can effectively reduce electrode polarization and improve reversibility. The LFP/NG-4 composite with a three-dimensional conductive network structure can be regarded as a promising cathode material for Li-ion batteries.     

Novel TiC-based composites with enhanced mechanical properties

Novel TiC-based composites were synthesized by reactive hot-pressing at 1800 °C for 1 h with ZrB₂ addition as a sintering aid for the first time. The effects of ZrB₂ contents on the phase composition, microstructure evolution, and mechanical properties were reported. Based on the reaction and solid solution coupling effects between ZrB₂ and TiC, the product ZrC may be partially or completely dissolved into the TiC matrix, and then phase separation within the miscibility gap is observed to form lamellar nanostructured ZrC-rich (Zr, Ti)C. The TiC-10 mol.% ZrB₂ (starting batch composition) exhibits good comprehensive mechanical properties of hardness 27.7 ± 1.3 GPa, flexural strength 659 ± 48 MPa, and fracture toughness of 6.5 ± 0.6 MPa m^1/2, respectively, which reach or exceed most TiC-based composites using ceramics as sintering aids in the previous reports.     

Nb2O5-doped NiZnCo ferrite ceramics with ultra-high magnetic quality factor and low coercivity for high-frequency electronic devices

This work investigates the influence of niobium pentoxide (Nb₂O₅) as dopant, on the structural, magnetic, and dielectric properties of NiZnCo ferrites. The results showed that Nb₂O₅ was an effective dopant, and the Nb⁵⁺ ions entered the B site to replace Fe³⁺ ions, which altered the electromagnetic properties of the NiZnCo ferrite. In particular, the coercivity (H_c) was 20～24 Oe, and the magnetic quality factor (Q), was more than 200 at x = 0 and x = 0.1 wt%, which is 4～5 times higher than that of NiZn and NiCuZn ferrites. Excellent electromagnetic properties were obtained for 0.1 wt% Nb₂O₅-doped NiZnCo ferrite, i.e., M_s = 88.3 emu/g, H_c =20.4 Oe, ρ = 2.4 × 10⁵ Ω m and Q = 202 @20 MHz. These excellent electromagnetic properties of Nb₂O₅-doped NiZnCo ferrites could be potentially applied to resonators and capacitors at high frequency.     

Interactions and complex stabilities of grape seed procyanidins with zein hydrolysate

The objective of this paper was to investigate the complex of grape seed procyanidins (GSP) with zein hydrolysate (ZH). The interaction was determined using isothermal titration calorimetry (ITC) and fluorescence spectroscopy. The particle size, ζ-potential, scanning electronic microscopy (SEM) and stability test of the ZH-GSP complex were measured. The results of ITC, particle size and SEM suggested that there was a hydrogen bond-dominated interaction between GSP and ZH, and the ZH-GSP complex presented as a spherical shape with particle size of 234 nm, polydispersity index of 0.11 and ζ-potential of −46.4 mV. The results of the fluorescence spectroscopy showed that the fluorescence quenching effect of GSP on ZH was GSP concentration-dependent and the quenching process was mainly static quenching. The ZH-GSP complex had better physical stability in aqueous solution, and their solution was more stable than GSP solution under illumination and high-temperature treatment at 75°C.     

电镀行业固体废物环境审计方法研究与展望——以珠三角地区为例

固体废物环境审计是固体废物管理的一项重要手段,能够减少政府管理部门与企事业单位之间的信息不对称,促使企业加强环境管理,达成预期的环境保护目标.我国的固体废物环境审计工作起步较晚,目前主要为理论研究,尚未形成系统的工作方法.本文结合文献研究与实践经验,介绍了国内外环境审计的定义及发展历程,并以珠三角地区为例,阐述了电镀行...     

5500 m3高炉高产操作实践

分析了首钢京唐公司1#、2#两座5 500 m~3高炉开炉后快速达产、高产情况。选取连续10天以上日产量完成13 000 t的4个典型阶段,研究了高炉主要技术经济指标与操作制度的对应情况关系,总结提炼了操作经验和冶炼参数,为大型高炉高产、稳产提供了参考。