The adsorption behaviour of faba bean proteins at a sunflower oil-water interface

The present study aims at investigating the absorption behaviour of acetylated (AFBPI) and non-acetylated (FBPI) faba bean protein isolate at a sunflower oil-water interface in dependence on different environmental conditions (protein concentration, pectin addition).     

Implementing polarization shift keying over satellite – system design and measurement results

Polarization shift keying (PolSK) is a digital modulation technique using the state of polarization of an electromagnetic wave as the signalling quantity. PolSK comes from fibre communications, where the channel offers two orthogonal states of polarization. This article develops on the idea to adapt this technology to satellite communications, where similar channel conditions exist. For this purpose, a digital PolSK modem was implemented on a programmable logic board. A proposal for constellation design as well as thoughts on synchronization of PolSK over satellite is presented. The modem was used to demonstrate a 16‐state Polarization Shift Keying link over a commercial satellite in K_u band. Measurements have been conducted in a back‐to‐back setup on intermediate frequency and on a K_u band transponder simulator to assess the impact of path‐length differences, carrier recovery and non‐linearity. Copyright © 2015 John Wiley & Sons, Ltd.     

Social environment of the church and feelings of gratitude toward god.

The purpose of this study was to see whether the social environment of the church is associated with changes in feelings of gratitude toward God over time. The theoretical thrust of the authors’ analyses is captured in the following conceptual linkages: (a) People who attend church frequently are more likely to believe that their congregation is highly cohesive; (b) individuals who worship in more cohesive congregations will receive more emotional support from fellow church members; (c) people who receive more emotional support from coreligionists will be more likely to feel they have a close spiritual connection with others; and (d) people who feel they are closely connected with other individuals will feel especially grateful to God. Data from a nationwide longitudinal survey of older adults provide support for each of these hypothesized relationships. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Zur Darstellung und Charakterisierung von Vinylsenfölen

Synthesis and Characterisation of Vinylisothiocyanates The preparation of vinylisothiocyanates by treatment of γ-chloroallylchlorides with KSCN followed by rearrangement of the γ-chloroallylthiocyanates is described. The structure is proved by the reaction of the vinylisothiocyanates with mercaptides and by spectroscopic methods.     

Synthese von nitro- und aminosubstituierten Thiobenzamiden durch Thiolierungsreaktionen mit elementarem Schwefel unter milden Bedingungen

Synthesis of Nitro- and Amino-Substituted Thiobenzamides by Thiolation Reactions with Elemental Sulfur at Mild Conditions The Synthesis of thiobenzamides 2 – 7 by basecatalyzed thiolation of nitro-benzyl-halides (type 1 ), especially at low temperatures, and the selective synthesis of p- and m-nitro-thio-benzamides ( 2 , 3 ) or p-and m-amino-thiobenzamides ( 5 , 6 ), respectively, are described. o-Nitro-benzylhalides (→ 4 , 7 ) are less reactive than p- and m-nitro-benzylhalides. The reaction of nitrobenzylhalides (type 1 ) with elemental sulfur and amines occuring at low temperatures to give 2 – 4 leads via structures of the type 11 , 15 and 16 .     

Herstellung von Phenolharzen unter Verwendung von Stärkeprodukten

Usage of Starchy Products for Preparation of Phenolic Resins. Incorporation of starches and starch hydrolysates in phenolic resins of novolak and resol type has been investigated via acid catalyzed dehydration to 5-hydroxymethylfurfural (HMF) in the presence of phenol and formaldehyde. Due to formation of HMF/phenol-condensates savings up to 40% phenol and 65% formaldehyde are possible in comparison to commercial resins. Besides very low amounts of residual monomers, curing is accelerated with increased carbohydrate incorporation, which can be used to reduce time consuming manufacturing processes. Especially starch hydrolysates with different average molecular weights can be used in a very flexible way to achieve special requirements like softening points, mol weight distributions, viscosities and curing behaviour.     

Titanium and bioactive glass-ceramic coated titanium as materials for keratoprosthesis

The current problem with keratoprosthesis is the ingrowth of corneal or conjunctival epithelium into the anterior chamber. This may lead to infections and extrusion of the prosthesis as well as to the development of retroprosthetic membrane and secondary glaucoma. Glass-ceramic coated and uncoated titanium has been tested as material for the keratoprosthesis to prevent epithelial ingrowth. Twenty-two Supra-Descemet's membrane keratoprostheses were inserted in the eyes of 22 rabbits for 1, 2, 4, 8, or 12 months. The prosthesis had an optic part made of polymethylmetacrylate (PMMA). The support for the optic part and the flange of the prosthesis were made of titanium. Eleven of the prostheses were coated with glass-ceramic. The histological sections of the enucleated eyes were prepared through the central part of the cornea and the prosthesis using a cutting-grinding method. The histological analysis was made on both halves of the implants separately giving two analysis areas in each eye. All 11 titanium prostheses were retained for the time period planned. Two glass-ceramic coated prostheses were lost at 2 and 4 weeks, respectively. This was caused by difficulties at surgery due to a thick coating. These eyes were excluded from the histological analysis. No significant ingrowth of epithelium was seen in 15/18 (83%) and in 16/22 (73%) of the analysed areas of the glass-ceramic coated and titanium prostheses, respectively. Titanium appears to be a suitable material for the keratoprosthesis. The ingrowth of the epithelium may be hindered further by coating the titanium with bioactive glass-ceramic.     

Fibrolytic enzyme treatment of barley grain and source of forage in high-grain diets fed to growing cattle

We conducted a study to determine the effects of treating barley grain with a fibrolytic enzyme mixture on chewing activities, ruminal fermentation, and total tract digestibility in cattle. We also investigated the potential benefits of using barley straw rather than barley silage as a roughage source in high-grain diets for feedlot cattle. Steers were given ad libitum access to one of four diets that consisted of 95% barley-based concentrate and 5% forage (DM basis). The concentrate was either control or enzyme-treated, and the forage was either barley silage or barley straw. Applying the enzyme mixture onto the barley lowered the concentrations of dietary ADF and NDF. However, it is not certain when this fiber hydrolysis occurred relative to feed consumption because the fiber analyses were conducted after the study was completed. Enzyme treatment of barley increased total tract dietary ADF digestibility by 28% (P<.05). Acetate-to-propionate ratio tended to decrease, which suggests that enzymes may have increased ruminal starch digestion as a result of enhanced digestion of barley hulls. Replacing silage with straw increased ADF intake (P<.05) and resulted in 1-h/d increase in rumination time (P<.05). Even though there was no effect of diet on ruminal pH, replacing silage with straw increased ruminal acetate, as a percentage of total VFA, and total tract ADF digestion (P<.01). This study demonstrates that using a fibrolytic enzyme mixture in high-grain diets that contain mainly barley grain can improve fiber digestion and grain utilization, but the mode of action is unclear. Straw can be used rather than silage to increase the effective fiber content of a high-grain feedlot diet.     

Incubation of curing brines for the production of ready-to-eat, uncured, no-nitrite-or-nitrate-added, ground, cooked and sliced ham

Salt concentration, vegetable juice powder (VJP) concentration and temperature were investigated to determine necessary conditions for incubation of curing brines including VJP and a starter culture containing Staphylococcus carnosus prior to production of naturally cured, no-nitrate/nitrite-added meat products. Subsequently, incubated brines were utilized to produce no-nitrate/nitrite-added sliced ham in which quality characteristics and residual nitrite concentrations were measured to determine feasibility of brine incubation for nitrate conversion prior to injection. Two ham treatments (one with VJP and starter culture; one with pre-converted VJP) and a nitrite-added control were used. No differences (P>0.05) were found for color in the VJP treatments. Control sliced ham was redder after 42 days of storage, retaining significantly (P<0.05) greater a* (redness) than either of the VJP treatments. Residual nitrite concentration was greater (P<0.05) in the control hams during the first week of storage. While the nitrite-added control retained greater red color and initially had more residual nitrite than the VJP treatments, the two VJP treatments did not differ from each other.