Novel Hyperbranched predominantly Alternating Copolymers Made From A Charge Transfer Complex monomer pair of p-(chloromethyl)styrene and Acrylonitrile via Controlled Living Radical Copolymerization

Summary Novel hyperbranched copolymers were successfully synthesized by the controlled charge transfer complex inimer and living radical copolymerization of p-(chloromethyl)styrene (PCMS) and acrylonitrile (AN). The resulting copolymers were characterized by SEC, NMR, FTIR, DSC and elemental analysis etc.. The influences of reaction conditions, such as the polymerization temperature, the catalyst (CuBr) concentration and the monomer ratio, on the resulting copolymers were investigated in detail. The monomer reactivity ratios were evaluated to be r_PCMS=0.937 and r_AN=0.088 respectively by the Fineman-Ross method. The higher are the polymerization temperature and the ratio of catalyst to monomer, the higher is the branching degree of the resulting copolymer. When the amount of monomer AN was used in excess than that of the monomer PCMS in the raw feed, the hyperbranched predominantly alternating copolymers HP[PCMS-co-AN] could be obtained. These hyperbranched copolymers were successfully used as functional macroinitiators to synthesize the star-shaped poly(PCMS-co-AN)/poly(MMA) block copolymers.     

泥沙输移矢量式及其应用

本文基于Parker等人泥沙输移矢量式的分析和研究，增加了上举力的作用，并考虑了泥沙颗粒受力非平衡条件，采用牛顿力学的矢量分析法，推导了泥沙输移的通用矢量式。经对公式简化，且用Ikeda和笔者试验资料的验证，证明计算值与试验值吻合较好。     

某型杀伤枪榴弹引信弹道炸原因分析及再设计思考

通过对某型杀伤枪榴弹引信所发生的三次弹道炸的原因进行分析，提出用延期索替代延期药盘，并对有关机构进行再设计的对策。     

气体绝缘封闭电器的高速瞬变过程和现场试验

随着ＧＩＳ的工作电压不断提高和发展，一系列新的现象和问题也同时出现。从国外一些科研，设计，制造部门所研究发表的内容看，大致有隔离开关操作和高速瞬变过程，粒子影响和对干扰定位的技术，元件的监督，现场试验等课题，本文对以上问题加以综合介绍。     

科技期刊编辑专业化和学者化是保证期刊学术质量的关键

一般科技期刊刊载的论文内容都具有很强的专业性,这就要求科技期刊编辑必须具有丰富的专业知识和较高的学术水平才能胜任编辑工作.从编辑过程的选题组稿、论文初审、选择审稿专家和编辑加工四个方面对此进行了阐述,指出了提高科技期刊编辑的相关专业知识和学术水平的措施.     

川东石炭系气藏排水采气工艺技术及其应用

四川盆地东部石炭系气藏是中国石油西南油气田公司的主力气藏之一，经过20多年的开发，出水气井增多、开发难度加大，必须进行排水采气才能维持正常生产。由于石炭系气藏大部分生产井存在井深、地层压力系数低、温度高、静液面深、复产后井口套压高的特点，常规排水采气工艺不能满足气藏的要求。针对这些难点，研究出深井高压气举、低压深井的优选管柱、深井高温泡排三项适合石炭系气藏的排水采气工艺，并在现场十多口井上进行了试验，增产效果显著。     

On the behavior of microstructures with multiple length scales

The current study aims to provide fundamental insight into the behavior of microstructures containing grain sizes that span multiple length scales. A commercial 5083 Al alloy was selected as the material of interest to facilitate comparison with recently published data. The materials studied here were prepared via the thermal consolidation of powders that were cryomilled for different times (i.e., 0, 2, 4, and 8 hours). Following consolidation, the resultant microstructure was characterized by an equiaxed grain morphology with a size distribution centered around 200∼300 nm. Dispersed among the 200- to 300-nm grains were coarse-grained regions or ligaments with a grain size ranging from 600 nm to 2 μm. The occurrence of coarse-grained regions is rationalized on the basis of recrystallization or subgrain coarsening, whereas the occurrence of equiaxed fine regions is proposed to be a result of continuous grain growth. Two types of microstructures were selected for study, containing coarse-grained volumes of approximately 28 pct and 43 pct that corresponded to an ultimate tensile strength (UTS) of 566 MPa and 535 MPa, and a fracture strain of 3.2 pct and 3.5 pct, respectively. The observed ductility and the relevant toughening mechanisms were discussed in light of the presence of multiple length scales.     

Mechanical properties of iron processed by severe plastic deformation

In the present study, the mechanical properties of Fe processed via severe plastic deformation (equal-channel angular pressing (ECAP)) at room temperature were investigated for the first time. The grain size of annealed Fe, with an initial grain size of about 200 μm, was reduced drastically during ECAP. After eight passes, the grain size reaches 200 to 400 nm, as documented by means of transmission electron microscopy (TEM). The value of microhardness during pressing increases 3 times over that of the starting material after the first pass and increases slightly during subsequent pressing for higher-purity Fe. Examination of the value of microhardness after eight passes as a function of post-ECAP annealing temperature shows a transition from recovery to recrystallization, an observation that resembles the behavior reported for heavily deformed metals and alloys. The tensile and compression behaviors were examined. In tension, a drop in the engineering stress-engineering strain curve beyond maximum load was observed both in the annealed Fe and the ECAP Fe. This drop is related to the neck deformation. The fracture surface, examined by scanning electron microscopy (SEM), shows vein patterns, which is different from the dimples found on the fracture surface of annealed Fe. In compression, an initial strain-hardening region followed by a no-strain-hardening region was observed in the ECAP Fe. The yield strength in tension of the ECAP Fe was observed to be higher than that in compression. The strengthening mechanisms and softening behavior are discussed.     

长庆油田苏平1井固井技术研究与应用

苏平l井完井方式运用了技术套管一次上返、悬挂尾管和筛管技术。该井技术套管段井眼大、裸眼段长，加上大斜度、小间隙的尾管段．对水泥浆体系的性能要求较高。总结分析了长庆天然气水平井苏平l井的固井技术问题，介绍了苏平l井的井身结构与地层性质。通过研究．确定采用低失水GSJ水泥浆体系。该体系成功地应用在三次工程建井过程中，解决了长裸眼、大灰量、大斜度、尾管小间隙等固井技术问题。固井质量达到工程要求。     

纤维体积分数对K3D/MCPA复合材料力学性能的影响

本文研究了纤维体积分数对三维编织芳纶纤维增强铸性尼龙(简称K3D／MCPA)复合材料力学性能的影响。研究表明，K3D／MCPA复合材料有优异的抗冲击性能，冲击强度比三维编织芳纶纤维增强铸性尼龙(简称C3D／MCPA)和纯基体均有大幅度的提高，且随着纤维体积的提高而升高。K3D／MCPA复合材料剪切强度随纤维体积比的增大而增大，其纵向剪切强度低于纯基体和C3D／MCPA复合材料，但其横向剪切强度高于它们。K3D／MCPA复合材料弯曲强度与弯曲模量随纤维体积比的提高而提高，但与相同体积比的C3D／MCPA相比，K3D／MCPA的弯曲强度与弯曲模量均较低。