Synthesis of ZSM-5 zeolite membranes without organic templates using a varying-concentration technique

Template-free nanosized ZSM-5 seeds with an average size of 15 nm were prepared from a synthesis solution with the composition 12Na2O:100SiO2:2Al2O3:2500H2O. By the use of these seeds, thin ZSM-5 zeolite membranes were prepared on the outer surface of a porous α-alumina tube with a pore size of 2 μm in a gel system by varying-concentration synthesis with organic-free template. The first composition synthesis sol-gel was the same as seeds of molar composition and the second one was 12Na2O:100SiO2:2Al2O3:5000H2O at 180 ℃ for 10 h, respectively. XRD shows that the film consists of well-crystallized ZSM-5 zeolite. SEM investigation indicats that the zeolite films on the supports are defect free and the film thickness is approximately 8 μm. The permeances for H2, N2, CH4 and CO2 are 8.94×10-7 , 3.27×10-7 , 3.9×10-7 , 3.14×10-7 and 0.874×10-7 mol·m2·s-1·Pa-1 , respectively. The ideal selectivity of membrane at room temperature for H2/CO2, H2/N2, H2/CH4 are 2.84, 2.73 and 2.29, respectively.     

纳秒级上升时间的高压脉冲群电源

按照IEC 61000-4-4/GB 17626.4—1998的要求，首先应用PSPICE仿真确定电路中各元件的参数值，然后基于拉普拉斯变换用MATLAB求解二阶电路验证各元件参数。在此基础上研制了一台以开关电源作为高压直流电源、以氢闸流管作为主控开关的脉冲群电源。该电源体积小、重量轻、效率高、成本低廉。试验结果表明，其输出信号符合标准要求，可用于快速瞬变脉冲群抗扰度试验。     

论薄板坯连铸连轧产品质量优势

通过对薄板坯连铸连轧工艺的分析，深入研究了其产品的质量优势，同时还指出了在产品生产过程中需要重点注意解决的一些问题。     

The impact of Ajax on network performance

Web 2.0 has been becoming the new tendency of the Internet development. In order to get better management of web 2.0 network resource and guarantee of service quality, the architecture and the advantages of web 2.0 over Ajax technology is analyzed, and the impact of Ajax on bandwidth performance of web application is discussed.     

星型聚合物中间体环硅氧烷核的合成研究

以甲基二氯硅烷、四甲基四乙烯基环四硅氧烷(DVi4)为原料,采用硅氢加成反应合成了星型聚合物的中问体环硅氧烷核,并用红外光谱和核磁共振谱进行了表征.反应的最佳条件是:采用预先活化、反应温度72℃、催化荆与DVi4的量之比为1.0×10-4,反应转化率可达95%,且选择性很好,产物主要为β-加成产物.     

有限元仿真分析中的结构周期差异探讨

针对有限元仿真分析中结构自振周期减小的问题，讨论了几种主要的影响因素，并借用商品化设计软件TBSA，ETABS 和有限元分析软件ANSYS，通过对一个简单结构的多次计算，比较了这些因素的影响大小。     

Disposal of Waste Plastics With Traditional Coking Process

A new technology for treating waste plastics （WP） by traditional coking process was introduced. With a thermo-balance and a 10 g atmospheric fixed bed reactor, the thermo-gravimetric behavior and product were studied during co-coking of WP with blended coal. And then, using a coke-oven with capacity of 200 kg, the characteristics of products were assessed. The results showed that there is an overlapping temperature range （200-550℃ ） of decomposition between WP and blended coal, and the pyrolysis synergism index η and synergism strength β proposed could evaluate the synergism between them. 1% of added WP results in the maximum synergism in all series experiments. The increase of added WP decreases the synergism. Tar yield in co-coking is increased with the decrease of water yield for synergism. Moreover, it was also found that the quality indexes of coke, such as M10, M40, CRI and CSR, are degraded with the increase of WP until 4%, though the quality of tar and gas is optimized for WP addition.     

霍尼韦尔TPS系统的概况及安全策略

介绍TPS系统结构,TPS系统在我厂的使用过程中遇到的问题以及解决办法,TPS系统安全策略的实施。     

微粒混凝土受压应力应变全曲线试验研究

采用一种特制的刚性辅助装置,进行了微粒混凝土和普通混凝土的应力应变全曲线试验研究,得到一系列应力应变曲线。对微粒混凝土和普通混凝土的立方体抗压强度与棱柱体抗压强度的关系、棱柱体抗压强度与峰值应力所对应应变的关系及棱柱体抗压强度与初始弹性模量的关系进行了分析,虽然微粒混凝土的力学性能与普通混凝土的力学性能存在一定的差别,但主要力学性能还是相似的,在模型试验中微粒混凝土是可以用来代替普通混凝土进行结构试验的。同时也验证了刚性辅助装置在测量微粒混凝土和普通混凝土的应力应变全曲线时的有效性。