混合溶剂对Ru(Ⅳ)萃取的研究

一、前言 在一定浓度盐酸介质中,Ru(Ⅳ)以RuCl_6~(2-)络阴离子状态存在,可被C类溶剂TOA(三辛胺)以离子缔合机制定量地萃入有机相。由实验得到在相同条件下,TOA对Ru(Ⅳ)的萃取率随稀释剂介电常数的增加而下降。     

Site occupations and ordering behaviour of O phase in Ti2AlNb—based intermetallics

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｏｒｔｈｏｒｈｏｍｂｉｃａｌｌｏｙｓａｒｅｏｆｇｒｅａｔｔｅｃｈ ｎｏｌｏｇ ｉｃａｌｉｎｔｅｒｅｓｔｉｎｈｉｇｈｔｅｍｐｅｒａｔｕｒｅａｐｐｌｉｃａｔｉｏｎｓｓｉｎｃｅｔｈｅｙｈａｖｅａｇｏｏｄｂａｌａｎｃｅａｍｏｎｇｓｔ     

Study on diffusion welding SiCp/ZL101 with Cu interlayer

Through the vacuum diffusion welding SiCp/ZL101 aluminum with Cu interlayer,the effect of welding parame-ter and the thickness of Cu on the welded joint property was investigated,and the optimal welding parameters were putforward at the same time.The microstructure of joint was analyzed by means of optical-microscope,scanning electron mi-croscope in order to study the relationship between the macro-properties of joint and the microstructure.The results showthat diffusion welding with Cu interlayer could be used for welding aluminum matrix composites SiCp/ZL101 successfully.     

铸造用CO2硬化冷芯盒材料及工艺的发展

铸造用CO2硬化粘结剂系统具有气硬冷芯盒的优点,同时又具有环保方面的优势。主要介绍了水玻璃-CO2法、聚丙烯酸钠-CO2法、酚醛树脂-CO2法三种工艺。这些工艺方法近年来国内外研究较多,并且取得了很大进展。     

岗位体验式教学法在雷达装备实践教学中的应用

针对雷达装备实践教学中演示式教学法对于学员能力的拓展和装备的综合运用等方面存在的问题,将岗位体验式教学法运用于雷达装备实践教学中.首先分析岗位体验式教学法的基本内涵;然后提出前期准备、场景设置、教学实施、交流研讨和总结讲评等5个方面的具体实施方法,进行实例分析;最后给出岗位体验式教学法的实施效果.教学实践结果验证了该方法的有效性.     

火电厂高温再热器小集箱管排热处理工艺优化

某火电厂检修项目更换炉顶集箱层内高温再热器小集箱,其高合金材质部件涉及热处理作业,由于高温再热器小集箱管排部件施工空间狭小,对热处理工艺提出较高的要求.制定初步的焊后热处理工艺,经过实践发现热处理后焊缝硬度存在偏高和偏低的问题,分析后通过调整热电偶布置及优化保温棉的包裹工艺,形成较为理想的高温再热器管排热处理工艺.热处理后焊缝及母材硬度检测指标符合规范要求,该工艺可应用于电厂后期检修相同类型系统的热处理工作中.     

Red-Blood-Cell-Membrane-Coated Metal-Drug Nanoparticles for Enhanced Chemotherapy

To overcome high toxicity, low bioavailability and poor water solubility of chemotherapeutics, a variety of drug carriers have been designed. However, most carriers are severely limited by low drug loading capacity and adverse side effects. Here, a new type of metal-drug nanoparticles (MDNs) was designed and synthesized. The MDNs self-assembled with Fe(III) ions and drug molecules through coordination, resulting in nanoparticles with high drug loading. To assist systemic delivery and prolong circulation time, the obtained MDNs were camouflaged with red blood cell (RBCs) membranes (RBCs@Fe-DOX MDNs) to improve their stability and dispersity. The RBCs@Fe-DOX MDNs presented pH-responsive release functionalities, resulting in drug release accelerated in acidic tumor microenvironments. The outstanding in vitro and in vivo antitumor therapeutic outcome was realized by RBCs@Fe-DOX MDNs. This study provides an innovative design guideline for chemotherapy and demonstrates the great capacity of nanomaterials in anticancer treatments.     

HIGH TEMPERATURE LOW CYCLIC FATIGUE BEHAVIOUR OF DIRECTIONALLY SOLIDIFIED Ni-BASE ALLOY DK3

研究了镍基定向凝固高温合金DK3和普通铸造合金K3在760℃应变控制和应力控制下的高温低周疲劳行为。结果表明:这两种合金的高温低周疲劳行为可以用常规的应力疲劳曲线来表征。DK3合金不存在“过渡疲劳寿命”N_T,K3合金则很低。在各种不同应变或应力水平下,DK3合金的低周疲劳寿命高于K3合金,当应力水平为785至980MPa时,其寿命约差1倍,当应力水平为490至685MPa时,则差2倍多。     

ELECTRICAL RESISTANCE MINIMA THEORY OF CuNi ALLOY

<正> 在稀磁合金中发现低温下电阻率的Kondo效应以后,一个非常引人注目的现象是含30—42at.-％Ni的Cu合金中,也存在电阻率低温反常,实验结果为图1中圆圈所示(最近在AuNi合金中也观测到相同的现象)。这个电阻异常的特点是极小值的宽度和出现极小值的温度,都随Ni含量的增加明显地加大。这个现象普遍认为是磁性集团效应引起的,不是单个Ni原子引起的。但是,至今尚无一个理论对此现象作出定量的解释。本文应用无序自旋集团模型导出一个电阻率公式,对此现象作了定量的解释。