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Wet sewage sludge pyrolysis is an attractive method for producing H2-rich fuel gas. To reduce energy consumption for excess moisture evaporation, deep dewatered sludge was used instead of traditional high-moisture sludge in this study. The emphasis was placed on elucidating the effects of residual moisture on tar, char, and on syngas generation, and clarifying the mechanisms involved. Results show that residual bound water exerted a stronger influence on products yields and distributions than free water, since the former could work inside sludge particles while the later only acted as steam outside. At low temperature (873 K), sludge moisture increased the relative ratio of cyclic, unsaturated, and hydroxyl, aldehyde or carboxyl-containing compounds in tar, in whose generation process H2 and carbonaceous gas were produced. When the temperature rose, water in sludge increased the surface area of the char. The breaking of C–C bonds caused by residual moisture would promote the macromolecular organic matters conversion to smaller ones, which were easy to undergo steam gasification, thus giving rise to the transformation of char–C to gas–C and enhancing H2 yield. Therefore, the production of syngas, containing large amounts of H2 and CO, was improved efficiently. 相似文献
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Photo-hydrogen production rate of a PVA-boric acid gel granule containing immobilized photosynthetic bacteria cells 总被引:1,自引:0,他引:1
Xin Tian Qiang LiaoWei Liu Yong Zhong WangXun Zhu Jun LiHong Wang 《International Journal of Hydrogen Energy》2009
The polyvinyl alcohol (PVA)-boric acid gel granule facilitates the light penetration and mass transport as it has the features of the transparency and adequate porous structure. In this work, a hydrogen production bioreactor with the indigenous photosynthetic bacteria (PSB) Rhodopseudomonas palustris CQK 01 immobilized in a PVA-boric acid gel granule is developed to enhance the rate of photo-hydrogen production. Particular attention is paid to exploring the effects of illumination wavelength and intensity, as well as the effects of concentration, flow rate, pH, and temperature of influent substrate solution on the hydrogen production rate. The immobilized PSB gel granule exhibited the maximum hydrogen production rate of 3.6 mmol/g cell dry weight/h in all tests. The experimental results show that the hydrogen production rate of an immobilized PSB granule illuminated at 590 nm is distinctly higher than that at 470 and 630 nm. Photo-inhibition of the gel granule occurs as the long-wavelength illumination intensity exceeds 7000 lux. In addition, there exists an optimal pH of 7.0 and temperature of 30 °C for PSB immobilized in the granule to produce hydrogen. More importantly, the feasibility of PSB immobilized in the PVA-boric acid gel granule for the enhancement of the photo-hydrogen production is demonstrated. 相似文献
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Abrasives play an important role in chemical mechanical polishing (CMP) processes. Compact solid silica particles, which have been widely used as abrasive in CMP slurries, may cause surface defects because of their high hardness. Porous silica abrasive exhibits better surface planarization and fewer scratches than traditional solid silica abrasive during the polishing of hard disk substrates. However, the improvement in material removal rate (MRR) was not significant. Therefore, porous Fe2O3/SiO2 nanocomposite abrasives were prepared and their CMP performances on hard disk substrates were investigated. Experiment results indicate that the MRR of slurry containing porous Fe2O3/SiO2 nanocomposite abrasives is obviously higher than that of slurry containing pure porous silica abrasive under the same testing conditions. MRR increases with the increase of the molar content of iron in porous Fe2O3/SiO2 nanocomposite abrasives. Moreover, surfaces polished by slurries containing the porous Fe2O3/SiO2 nanocomposite abrasives exhibit lower surface roughness, fewer scratches as well as lower topographical variations than that by pure porous silica abrasive. 相似文献
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China is the biggest country of rice production and consumption in the world; more than 50% of the population feeds chiefly on rice. The quality of rice and its role as a staple food carry much weight. The rice qualities are those aspects concerning processing,appearance, cooking, nutrition and safety of the product.The study, formulation and implementation of standards on rice qualities and testing bear heavily on the improving of rice qualities, human health, substitution of rice varieties, promoting quality rice production and regulating rice market. 相似文献
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介绍了计算机存储的关键技术,并结合企业级GIS数据的特点,全面阐述了如何运用这些技术,来解决GIS数据管理中遇到的问题。最后给出了建立GIS存储备份系统的技术路线。 相似文献
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Shao Wei Wang Wei LuNing Li Zhi Feng LiHong Wang Min WangXue Chu Shen 《Materials Research Bulletin》2002,37(10):1691-1697
Crack-free Bi2Ti2O7 thin films on silicon substrates were prepared using chemical solution decomposition technique, and then treated by rapid thermal annealing. The microstructure of the films was studied by scanning electron microscopy. The effects of different fabricating procedures and various annealing temperatures and times on the leakage current density were investigated. The results show that the leakage current density decreases with increasing annealing temperature, while increases with increasing annealing time. Annealing temperature has a much stronger effect on the insulating properties of Bi2Ti2O7 thin films than that of annealing time. 相似文献
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Quantitative deterministic versus probability analyses based on a safety margin criterion 总被引:1,自引:0,他引:1
This paper proposes a new criterion called the ratio of safety margin(RSM)for use in the areas of the global factor of safety,reliability and limit states analyses with reference to their respective allowable criteria.An equation for calculating RSM based on the reliability index is formulated.Efforts for proving the applicability of this criterion include a theoretical demonstration in a simple one-variable case;an investigation on a test problem involving two random variables,followed by a slope stability study on a 156 m high embankment dam and an illustrative example presented in a EuroCode 7 guidebook.Calculation of the ratios of safety margin in the three areas provides a quantitative way to accommodate the analytical results within the same theoretical framework and makes the outcomes mutually comparable and supportive,which is much more enlightening than that would be the case by considering only one of them.Calculating RSMs for reliability and limit states methods has also helped solve the key issue concerning the uniqueness of the partial factors calibrated from a particular‘target case’. 相似文献
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