KINETICS OF HYDROCARBON GAS GENERATION FROM MARINE KEROGEN AND OIL: IMPLICATIONS FOR THE ORIGIN OF NATURAL GASES IN THE HETIANHE GASFIELD, TARIM BASIN, NW CHINA

In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C_1‐5) and methane (C₁) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C_1‐5 (Ea = 59‐72kcal, A = 1.0×10¹⁴ s^?1) and C₁ (Ea = 61‐78kcal, A = 6.06×10¹⁴ s^?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×10¹⁴ s^?1 for C_1‐5; and Ea = 48‐72kcal, A=3.9×10¹³ s^?1 for C₁, respectively). Using these kinetic parameters, both the yields and timings of C_1‐5 and C₁ hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression.     

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An integrated system of biological and catalytic oxidation for the removal of o-xylene from exhaust

Biofiltration is an efficient technology for treatment of gaseous waste. Its disadvantages, however, include large volume of bioreactor and slow adaptation to fluctuating concentrations in waste gas. Catalytic oxidation offers a high destructive efficiency at relatively low operating temperature and small unit. A bench scale system integrated with a biofilter and a catalytic oxidation unit for the treatment of gases containing o-xylene was investigated in this study. The catalytic oxidation unit was packed with Cu/Al₂O₃ catalyst. The results showed that 90% of o-xylene could be removed in the biofilter at the load below 38.2 g m⁻³ h⁻¹. High o-xylene concentration in inlet gas resulted in an overload of the biofilter. Using the Cu/Al₂O₃ catalytic oxidation unit, the concentration of o-xylene could be reduced evidently. The combination of the chemical and microbial processes not only led to a high and stable efficiency of o-xylene conversion, but also improved capacity resisting the shock loads. The Cu/Al₂O₃ was studied for o-xylene oxidation in temperature range of 90–320 °C. The o-xylene conversion was improved correspondingly with the increasing of oxidation temperature. The reaction mechanism of o-xylene oxidation on Cu/Al₂O₃ was also investigated using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).     

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为适应城市发展需要,必须加强城市水利工作,通过对舒兰市水资源现状分析,对解决城市供水水源工程建设的措施进行探讨。     

优化改造油田生产工艺 增产增效提高环保水平——涠洲11-4油田生产工艺优化改造实践

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基于WebGIS的粗泥沙集中来源区电子地图系统建设，以粗泥沙集中来源区作为研究区域，以黄河中游粗泥沙集中来源区水土保持工作流程（包括规划设计、计划管理、综合治理、预防监督和淤地坝管理等）为主线，依托黄河流域水土保持生态与环境监测系统网络、黄河流域水土保持监测系统数据库，建立覆盖黄河流域、黄土高原区、多沙粗沙区、粗泥沙集中来源区，面向不同水土保持管理层的水土保持监测与管理信息系统。     

Highly active lanthanum doped nickel anode for solid oxide fuel cells directly fuelled with methane

Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane.     

山东省水利系统推行政务公开工作探讨

1水利部门政务公开的重要意义水是基础性的自然资源和战略性的经济资源,又是控制性的生态要素。水利工作事关全省经济社会发展大局,事关广大人民群众的根本利益。在全省水利系统推行政务公开,是实践"三个代表"重要思想,坚持治     

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对科研人员业绩的考核，应具有一定程度可量化的考核指标和一套完整的考核体系。文章对科研人员业绩评价的内容及其指标体系、考核与管理办法进行了设计，认为科研人员业绩考核指标可以分为劳动数量、劳动质量和劳动成果3类，具体内容包括其科研工作量、科研责任、科研成果的表现形式及其数量、成果的学术价值与利用率，以及科研人员科研技能水平等。