Aromatization of n-butane over new LD-HBS catalysts. Effect of the gallium oxide support

It is shown that even pure quartz, other silicas or aluminas can enhance the aromatization activity of a ZSM-5 zeolite. Incorporation of gallium oxide onto these supports increases further the production of aromatics. The use of supported gallium oxide co-catalyst obtained by co-evaporation of a colloidal silica and a Ga salt has led to extremely high aromatization performance for the hybrid catalyst.     

A pair of parallel differential magnetic‐field probes with high measurement accuracy and high electric‐field suppression ratio

Magnetic‐field probes can be used for electromagnetic interference measurement of high‐speed circuits. The main magnetic probe performance includes sensitivity, spatial resolution, electric‐field suppression ratio (EFSR), and measurement accuracy. In this article, a pair of differential magnetic‐field probes is proposed to improve measurement accuracy without reducing sensitivity. The proposed differential probes consist of two asymmetric loop probes, which are designed in the same plane and separated by a row of periodic vias. The proposed differential probes are fabricated under PCB process. High accuracy can be achieved by measuring difference between outputs of the two probes. In addition, EFSR can be improved by size optimization of the differential magnetic‐field probes. Simulation and measurement results show the operating bandwidth is from 100 MHz to 12 GHz, the measurement error is 3.4% and the EFSR is about 40 dB. The proposed probes have higher measurement accuracy and higher EFSR than the conventional single probe, and larger operation bandwidth than the stacked differential probes.     

基于二次EEMD的工业电能需量多步预测

电力大用户最大需量控制是降低电网峰值负荷、节约用户电费成本的重要技术手段.面向强波动性和冲击性工业电能需量控制,研究了超短期需量负荷的多步预测问题.基于集成经验模态分解(EE-MD)方法,通过二次分解有效分离时间序列中不同频率的信号,采用长短期记忆网络(LSTM)对各信号子序列进行独立预测,最后组合预测结果.实验结果表明,本方法能很好的预测工业需量负荷变化,M A PE/MAE/NRMSE精度指标基本控制在2％ 以内,明显优于多种现行主流时序预测模型和最新文献方法,且消除了多步预测的传递误差,预测模型精度和稳定性满足需量控制要求.     

Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

颗粒强化钛基复合材料的氧化特性

研究了以ＴｉＣ颗粒增强的钛基复合材料的氧化特性。指出ＴｉＣ增强的钛基复合材料在６５０℃以上高温有着其它耐热钛合金不可比拟的高温抗氧化性能；ＴｉＣ／Ｔｉ的反应界面层有利于氧原子的扩散，使复合材料在６５０℃以下的氧化初期氧化速度较快；但在６５０℃以下经长时间保温，其氧化特性和其它耐热钛合金相似。     

高强度复合材料整铸辙叉前期研究

辙叉是线路上工作条件最为严峻的轨道部件之一。用高强度复合材料整铸的辙叉替代普通辙叉的研究具有重要意义。以ＰＤ３钢轨钢作为基体材料，在其表面熔合上一层新型具有更好耐磨性能的材质。新材料１、新材料２分别在ＰＤ３基础上把Ｖ的含量提高到０．１５％～０．２５％和０．３５％～０．４５％。采用合适的工艺措施，使新材料１、２与ＰＤ３轨道钢很好地熔合在一起。它们的σｂ、ａｋ、δ、τｂ均不低于ＰＤ３，而Ｈｖ却有了提高。     

Mn对Fe_3Al合金室温力学性能的影响

Ｍｎ对Ｆｅ_３Ａｌ合金室温力学性能的影响楼白杨，刘茂森，毛志远，涂江平，肖延龄，钟映宏（浙江大学）Ｆｅ３Ａｌ金属间化合物具有抗氧化耐腐蚀性良、比强度高和成本低等特点［１，２］，从而具有可观的工程应用前景。对这种材料目前国内研究的热点之一是改善其室温塑?..     

IMPROVING SOLIDS SUSPENSION USING DEFLECTING BAFFLES IN GASLIFT LOOP REACTORS

ＩＭＰＲＯＶＩＮＧＳＯＬＩＤＳＳＵＳＰＥＮＳＩＯＮＵＳＩＮＧＤＥＦＬＥＣＴＩＮＧＢＡＦＦＬＥＳＩＮＧＡＳＬＩＦＴＬＯＯＰＲＥＡＣＴＯＲＳ￥ＬｕａｎＭｅｉｌａｎｇ；ＭａｏＺａｉｓｈａ；ＷａｎｇＲｏｎｇ；ＣｈｅｎＪｉａｙｏｎｇ（ＩｎｓｔｉｔｕｔｅｏｆＣｈ...     

BNi—2钎焊条的真空吸铸工艺

研究了ＢＮｉ－２钎焊条真空吸铸原理，并由试验得出：当ＢＮｉ－２合金加热到１５００℃，真空控制阀门开口为φ６ｍｍ以上，真空度５０ｋＰａ，铸型预热温度５００℃，并用φ内２ｍｍ×５００ｍｍ石英管进行真空吸铸时，吸铸高度可达到４０ｃｍ以上。     

稀土La细化再生铝硅合金中β-Fe相的机理研究

研究了再生副牌ZL102合金中稀土La的加入量和β-Fe相平均长度的关系，分析了La在合金和β-Fe相中的分布情况。结果表明，La在熔体中形成了稳定金属间化合物，凝固时促进了β-Fe相形核，同时La在β-Fe相表面富集，阻碍了β-Fe相长大。因此，加入稀土La能很好地细化再生铝合金中的β-Fe相。