Accelerated testing of on‐board diagnostics

Modern products frequently feature monitors designed to detect actual or impending malfunctions. False alarms (Type I errors) or excessive delays in detecting real malfunctions (Type II errors) can seriously reduce monitor utility. Sound engineering practice includes physical evaluation of error rates. Type II error rates are relatively easy to evaluate empirically. However, adequate evaluation of a low Type I error rate is difficult without using accelerated testing concepts, inducing false alarms using artificially low thresholds and then selecting production thresholds by appropriate extrapolation, as outlined here. This acceleration methodology allows for informed determination of detection thresholds and confidence in monitor performance with substantial reductions over current alternatives in time and cost required for monitor development. Copyright © 2006 John Wiley & Sons, Ltd.     

NICE h : a higher-order explicit numerical scheme for integration of constitutive models in plasticity

The article introduces, as a result of further development of the first-order scheme NICE, a simple and efficient higher-order explicit numerical scheme for the integration of a system of ordinary differential equations which is constrained by an algebraic condition (DAE). The scheme is based on the truncated Taylor expansion of the constraint equation with order h of the scheme being determined by the highest exponent in the truncated Taylor series. The integration scheme thus conceived will be named NICE ^h , considering both principal premises of its construction. In conjunction with a direct solution technique used to solve the boundary value problem, the NICE ^h scheme is very convenient for integrating constitutive models in plasticity. The plasticity models are defined mostly by a system of algebraic and differential equations in which the yield criterion represents the constraint condition. To study the properties of the new integration scheme, which, like the forward-Euler scheme, is characterised by its implementation simplicity due to the explicitness of its formulations, a damage constitutive model (Gurson–Tvergaard–Needleman model) is considered. The general opinion that the implicit backward-Euler scheme is much more accurate than the thus-far known explicit schemes is challenged by the introduction of the NICE ^h scheme. The accuracy of the higher-order explicit scheme in the studied cases is significantly higher than the accuracy of the classical backward-Euler scheme, if we compare them under the condition of a similar CPU time consumption.     

Adaptive atomic capture of multiple molecules

Facing the scale, heterogeneity and dynamics of the global computing platform emerging on top of the Internet, autonomic computing has been raised recently as one of the top challenges of computer science research. Such a paradigm calls for alternative programming abstractions, able to express autonomic behaviours. In this quest, nature-inspired analogies regained a lot of interest. More specifically, the chemical programming paradigm, which envisions a program’s execution as a succession of reactions between molecules representing data to produce a result, has been shown to provide some adequate abstractions for the high-level specification of autonomic systems.     

Wet Chemical Treatment and Mg Doping of p-InP Surfaces for Ohmic Low-Resistive Metal Contacts

Manufacturing a low-resistive Ohmic metal contact on p-type InP crystals for various applications is a challenge because of the Fermi-level pinning via surface defects and the diffusion of p-type doping atoms in InP. Development of wet-chemistry treatments and nanoscale control of p-doping for InP surfaces is crucial for decreasing the device resistivity losses and durability problems. Herein, a proper combination of HCl-based solution immersion, which directly provides an unusual wet chemical-induced InP(100)c(2 × 2) atomic structure, and low-temperature Mg-surface doping of the cleaned InP before Ni-film deposition is demonstrated to decrease the contact resistivity of Ni/p-InP by the factor of 10 approximately as compared to the lowest reference value without Mg. Deposition of the Mg intermediate layer on p-InP and postheating of Mg/p-InP at 350 °C, both performed in ultrahigh-vacuum (UHV) chamber, lead to intermixing of Mg and InP elements according to X-ray photoelectron spectroscopy. Introducing a small oxygen gas background (O₂ ≈ 10⁻⁶ mbar) in UHV chamber during the postheating of Mg/p-InP enhances the indium outdiffusion and provides the lowest contact resistivity. Quantum mechanical simulations indicate that the presence of InP native oxide or/and metal indium alloy at the interface increases In diffusion.     

Coupling of light from an LED into a thin light guide by diffractive gratings

Ring-shaped and radial diffractive gratings are designed with rigorous diffraction theory to couple light of a nearly monochromatic LED into a thin planar light guide on the bottom side. The theoretical coupling efficiencies for ring-shaped and radial gratings are 41% and 66%, respectively. Optimized diffractive elements are manufactured with direct electron-beam lithography and reactive-ion-etching into SiO2 substrates. Good agreement between experimental and theoretical results for selected radial gratings is reached. Furthermore, the mass production tests using injection molding are carried out with good replicability.     

A large-displacement 65Pb(Mg1/3Nb2/3)O3–35PbTiO3/Pt bimorph actuator prepared by screen printing

In this paper we present a novel approach to preparing large-displacement 65Pb(Mg_1/3Nb_2/3)O₃–35PbTiO₃/Pt (65/35 PMN–PT/Pt) bimorph actuators. These “substrate-free”, bending-type actuators were prepared by screen-printing the 65/35 PMN–PT and Pt thick-film pastes as the electrodes on alumina substrates. After this screen printing and the subsequent firing the 65/35 PMN–PT/Pt composites were peeled off from the substrates. Displacements of nearly 100 μm at 18 V were achieved for actuators with dimensions of 1.8 cm × 2.5 mm × 50 μm for the 65/35 PMN–PT layer. The normalized displacement (the displacement per unit length) was 40 μm/cm at 18 V. The experimental results together with a computation procedure were used to obtain the material parameters for a finite-element analysis of the 65/35 PMN–PT/Pt bimorph actuators.     

Hydrogen Bonding Drives Helical Chirality via 10-Membered Rings in Dipeptide Conjugates of Ferrocene-1,1′-Diamine

Considering the enormous importance of protein turns as participants in various biological events, such as protein–protein interactions, great efforts have been made to develop their conformationally and proteolytically stable mimetics. Ferrocene-1,1′-diamine was previously shown to nucleate the stable turn structures in peptides prepared by conjugation with Ala (III) and Ala–Pro (VI). Here, we prepared the homochiral conjugates of ferrocene-1,1′-diamine with l-/d-Phe (32/35), l-/d-Val (33/36), and l-/d-Leu (34/37) to investigate (1) whether the organometallic template induces the turn structure upon conjugation with amino acids, and (2) whether the bulky or branched side chains of Phe, Val, and Leu affect hydrogen bonding. Detailed spectroscopic (IR, NMR, CD), X-ray, and DFT studies revealed the presence of two simultaneous 10-membered interstrand hydrogen bonds, i.e., two simultaneous β-turns in goal compounds. A preliminary biological evaluation of d-Leu conjugate 37 showed its modest potential to induce cell cycle arrest in the G0/G1 phase in the HeLa cell line but these results need further investigation.