电化学沉积法制备稀土掺杂氧化钇荧光薄膜的发光性能

通过改变氧化钇薄膜中掺杂稀土元素的种类,来控制发光薄膜的荧光发射波长.利用电化学沉积法制备稀土掺杂氧化钇荧光薄膜.电化学沉积法制备的薄膜结晶效果好,掺杂离子分布较均匀,且不需要高温高压或者真空条件,成本很低.所制备的Y2O3:Ln荧光发光薄膜经XRD分析具有立方晶体结构;不同稀土掺杂的氧化钇呈现出不同的表面形貌;掺杂的Ln离子均匀地分布在薄膜中,经测试所有的Y2O3:Ln荧光发光薄膜都显示出较强的发射强度,且发光波长随着掺杂离子的不同而不同:Y2O3:Er3+发绿光,Y2O3:Ce3+发黄绿光,Y2 O3:Sm3+发蓝光,Y2O3:Pr3+发橙光.因此,电化学沉积法可用于制备具有不同发光波长的氧化钇荧光薄膜.     

氨气在4A分子筛上的吸附动力学研究

采用固定床中4A分子筛吸附的方法,研究不同NH3浓度和吸附床温度条件对分子筛吸附效果的影响.通过吸附穿透曲线和吸附床中的吸附平衡质量测定分子筛的吸附容量,并利用Langmuir等温方程对吸附等温线进行拟合.结果表明:分子筛的吸附容量随吸附床温度升高而降低,随吸附质初始浓度升高而升高,吸附平衡符合Langmuir方程.     

Methane absorption and application of mixed organic aggregate prepared from Span80 and alkaline salt

The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model of mine gas, and the absorptions of methane with different complex materials were studied using head space gas chromatography. Then the state of aqueous material was characterized with laser light scattering instrument and the effects of different complex materials on explosion suppression were preliminarily studied in explosion chamber which can simulate mine gas explosion. The research results showed that complex material could absorb methane and there was some correlation between the mean diameter of organic aggregate in aqueous material and the absorption effect. Additionally, the aqueous material could suppress the methane explosion to some degree. The material can absorb mine gas in atomization condition, therefore, degrease mine gas concentration and influence the distribution of mine gas in the space, and then suppress the mine gas explosion to some extent.     

Synthesis and self-assembly of comb oligomers having rigid racemic or chiral binaphthyl macrocyclic pendant groups

In this article, we described the synthesis of comb oligomers having rigid racemic or chiral binaphthyl macrocyclic pendant groups via the free radical polymerization. Oligomers obtained were well characterized by MALDI-TOF-MS, ¹H NMR, FT-IR, UV, CD and SEC. These comb oligomers having macrocyclic pendant groups showed very good solubility in common organic solvents at room temperature. Furthermore, the oligomers could self-assemble into different morphologies by dropping their THF solutions of different concentrations on the surface of water. At a relatively low concentration, the oligomers self-aggregated into hollow spheres. When the concentration was increased, the aggregates changed into solid spheres. The morphologies of the hollow or solid spheres were observed by TEM and ESEM.     

PP／交联POE共混物力学性能和形态的研究

采用过氧化二异丙苯（DCP）引发POE弹性体交联，溶解性实验与熔体流动速率实验结果表明，当DCP含量从0．5‰（质量含量，下同）增加至5．0‰时，凝胶含量从0．8％增加至12．8％，对应的共混物的熔体流动速率从2．80g／10min下降至0．80g／10min，这是POE弹性体交联的结果。将交联后的POE与PP共混，其与PP的共混物的冲击强度在较低的交联度时有一小范围的提高，当DCP含量超过2．0‰后，共混物的冲击性能明显下降。扫描电镜观察表明，随着POE交联度的增加，共混物中POE在基体中的分散明显变差，这与其冲击性能有很好的相关性。     

基于JMY-502模块的IC卡读写器的设计

随着非接触IC的大量使用,其成本越来越低。可以用单片机和IC读写模块来设计IC卡读写器,读写器分两种,一种是连接微机的,主要应用在收费管理部门,另一种是应用于现场收费部门,一般只具有自动收费功能。介绍了一种基于JMY-502的IC卡读卡器的设计,JMY-502是PHILIPS公司生产的微型嵌入式非接触式IC卡读写模块。给出了两种读卡器的硬件原理图及程序框图,读卡器实现了射频卡的制卡、收费及充值等功能,设计方案简单、成本低,适合各种收费场合。     

IWSNs中的混合式共享链路调度

针对工业无线传感器网络中的链路调度问题,提出一种混合式共享链路调度方案.通过对现有典型集中式调度方案存在的不足进行分析,将属于同一路径或多跳路由的节点间的共享链路集中分配给属于同一路径的节点,采用分布式决策决定哪些节点应当在每个时间点使用共享链路;推导出描述调度方案的可靠性和延迟性能指标的解析表达式,表明提出方案能灵活分配和利用链路,具有更好的防止传输差错和减小延迟的能力.仿真结果表明,与现有IWSNs链路调度方案相比,提出方案可以提高可靠性和延迟性能,更有效地利用链路资源.     

基于改进迭代最近点算法的接骨板贴合性快捷计算方法

为了快速计算出接骨板在断骨表面的最佳贴合位置,以减少手术中接骨板反复调整的次数,提出了一种基于改进迭代最近点（ICP）算法的接骨板贴合性快捷计算方法。首先,由医生指导在断骨表面选取贴合区域,并利用接骨板表面点的法向量之间的夹角提取接骨板的内曲面点云;然后,在对两组点云模型进行平滑处理并采用格点采样的方式来简化点云模型后,利用点云之间的特征关系进行初始配准;最后,对接骨板内曲面点云模型进行边界及内部特征关键点提取,并采用K-维树（KD-Tree）搜索邻近点,对接骨板的特征关键点和断骨表面选取区域执行ICP精确配准。以胫骨为例进行实验,实验结果表明,所提算法相较于近年所提配准算法在保持较高配准度的同时提高了配准效率,能够实现胫骨不同受损类型与接骨板之间的快速配准,并且对其他受损骨骼具有通用性。     

Further Study on Networked Control Systems with Unreliable Communication Channels

This paper focuses on the fundamental problems of linear quadratic gaussian (LQG) control and stabilization problems for networked control systems (NCSs) with unreliable communication channels (UCCs) where packet dropout, input delay and observation delay occur. These basic issues have attracted extensive attentions due to broad applications. Our contributions are as follows. For the finite horizon case, without time-stamping technique, the optimal estimator is derived by using the novelty method of innovation sequences based on the delayed intermittent observations; A necessary and sufficient condition for the optimal control problem is presented on the basis of the solution to the forward and backward difference equations (FBDEs) and two coupled Riccati equations. For the infinite horizon case, it is shown that under certain assumption, the system can stay bounded in the mean square sense if and only if the algebraic Riccati equation admits the unique positive solution.