Modified Mackenzie Equation and CVOA Algorithm Reduces Delay in UASN

In Underwater Acoustic Sensor Network (UASN), routing and propagation delay is affected in each node by various water column environmental factors such as temperature, salinity, depth, gases, divergent and rotational wind. High sound velocity increases the transmission rate of the packets and the high dissolved gases in the water increases the sound velocity. High dissolved gases and sound velocity environment in the water column provides high transmission rates among UASN nodes. In this paper, the Modified Mackenzie Sound equation calculates the sound velocity in each node for energy-efficient routing. Golden Ratio Optimization Method (GROM) and Gaussian Process Regression (GPR) predicts propagation delay of each node in UASN using temperature, salinity, depth, dissolved gases dataset. Dissolved gases, rotational and divergent winds, and stress plays a major problem in UASN, which increases propagation delay and energy consumption. Predicted values from GPR and GROM leads to node selection and Corona Virus Optimization Algorithm (CVOA) routing is performed on the selected nodes. The proposed GPR-CVOA and GROM-CVOA algorithm solves the problem of propagation delay and consumes less energy in nodes, based on appropriate tolerant delays in transmitting packets among nodes during high rotational and divergent winds. From simulation results, CVOA Algorithm performs better than traditional DF and LION algorithms.     

Development of a Multi-phase AlCuTaVW High-Entropy Alloy Using Powder Metallurgy Route and its Mechanical Properties

Transactions of the Indian Institute of Metals - Equiatomic AlCuTaVW high-entropy alloy (HEA) composition have resulted in a single-phase solid solution with a bcc crystal structure after...     

Capacitated lot-sizing problem with production carry-over and set-up splitting: mathematical models

This work proposes mathematical models (MMs) for the capacitated lot-sizing problem with production carry-over and set-up splitting, which can handle two scenarios, namely (1) situation/scenario where the set-up costs and holding costs are product dependent and time independent, and with no backorders or lost sales, and (2) situation where the set-up costs and holding costs are product dependent and time dependent, and with no backorders or lost sales. Previously, in an existing study the authors had developed a MM for the same problem and situation where the set-up costs and holding costs are product dependent and time independent, i.e. our Scenario 1. We compare our proposed models with the model in the existing study that appears to be incorrect.     

Montmorillonite/graphene oxide nanocomposite as superior adsorbent for the adsorption of Rhodamine B and Nickel ion in binary system

A series of montmorillonite reduced graphene oxide (MrGO) composites were synthesized using different ratios (5, 10, 15 and 20) of montmorillonite (MMt) to GO. The synthesized composites were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, surface area analyzer (BET), and Fourier transform- infrared spectroscopy. The adsorption capacity and efficiency of the synthesised composites were examined towards removal of Rhodamine B (RhB) and Nickel ion (Ni²⁺). The results were compared with that of GO and commercial MMt clay. The kinetic sorption models were evaluated, and it was observed that sorption follows the pseudo-second-order kinetics. Adsorption isotherm was best fit into the Langmuir model (R²?=?0.996 for RhB & 0.957 for Ni²⁺). Among all the synthesized composites, MrGO-2, a composite of GO and montmorillonite with (1:10) ratio, showed maximum activity towards the adsorption of Rhodamine B and Ni²⁺ calculated to be 625?mg/g and 178?mg/g respectively at neutral pH condition. From the calculated ΔG⁰ (?3.99 & ?0.71?kJ?mol^?1), ΔH (28.6 & 4.61?kJ?mol^?1) and ΔS (?107.5 & ?17.8?J?mol^?1 K) values for RhB & Ni²⁺ respectively, it can be unambiguously inferred that the adsorption process was feasible, endothermic and exhibiting least randomness, respectively. The prepared MrGO composites showed good adsorption capacity towards efficient removal of RhB and Ni²⁺ in single as well as binary system.     

Synthesis and characterization of sulfonated poly(phenylene oxides) as membranes for polymer electrolyte membrane fuel cells

The synthesis of a thermally stable proton conducting polymer based on poly(phenylene oxide) (PPO) was carried out using 2,6‐dimethylphenol (DMP) and 2‐allylphenol (AP) as monomers. The copolymers using the two monomers were prepared with DMP to AP molar ratios of 20:80, 40:60, 60:40, and 80:20. The polymers and the copolymers were blended with poly(vinylidene fluoride) and cast as membranes. All the membranes were sulfonated and characterized for their suitability as a polymer electrolyte membrane. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1792–1798, 2002     

Synthesis and Biological Evaluation of 4‐Sulfamoylphenyl/Sulfocoumarin Carboxamides as Selective Inhibitors of Carbonic Anhydrase Isoforms hCA II,IX, and XII

With the aim to develop potent and selective human carbonic anhydrase inhibitors (hCAIs), we synthesized 4‐sulfamoylphenyl/sulfocoumarin benzamides (series 5 a – r and series 7 a – q ) and evaluated their inhibition profiles against five isoforms of the zinc‐containing human carbonic anhydrase (hCA, EC 4.2.1.1): cytosolic hCA I and II, and the transmembrane isozymes hCA IV, IX, and XII. Compounds 5 a – r were found to selectively inhibit hCA II in the nanomolar range, while being less effective against the other hCA isoforms. As noted from the literature, sulfocoumarin (1,2‐benzoxathiine 2,2‐dioxide) acts as a “prodrug” inhibitor and is hydrolyzed by the esterase activity of hCA to form 2‐hydroxyphenylvinylsulfonic acid, which thereafter binds to the enzyme in a manner similar to that of coumarins and sulfoxocoumarins. All these sulfocoumarins (compounds 7 a – q ) were found to be very weak or ineffective as inhibitors of the housekeeping off‐target hCA isoforms I and II, and effectively inhibited the transmembrane tumor‐associated isoforms IX and XII in the high nanomolar to micromolar ranges. Further structural modifications of these molecules could be useful for the development of effective hCA inhibitors used for the treatment of glaucoma, epilepsy, and cancer.     

Observer-based state tracking control of uncertain stochastic systems via repetitive controller

This paper develops the repetitive control scheme for state tracking control of uncertain stochastic time-varying delay systems via equivalent-input-disturbance approach. The main purpose of this work is to design a repetitive controller to guarantee the tracking performance under the effects of unknown disturbances with bounded frequency and parameter variations. Specifically, a new set of linear matrix inequality (LMI)-based conditions is derived based on the suitable Lyapunov–Krasovskii functional theory for designing a repetitive controller which guarantees stability and desired tracking performance. More precisely, an equivalent-input-disturbance estimator is incorporated into the control design to reduce the effect of the external disturbances. Simulation results are provided to demonstrate the desired control system stability and their tracking performance. A practical stream water quality preserving system is also provided to show the effectiveness and advantage of the proposed approach.     

Graphene oxide modified non-noble metal electrode for alkaline anion exchange membrane water electrolyzers

This paper reports the performance of a graphene oxide modified non noble metal based electrode in alkaline anion exchange water electrolyzer. The electrolytic cell was fabricated using a polystyrene based anion exchange membrane and a ternary alloy electrode of Ni as cathode and oxidized Ni electrode coated with graphene oxide as anode. The electrochemical activity of the graphene oxide modified electrode was higher than the uncoated electrode. The anion exchange membrane water electrolyzer (AEMWE) with the modified electrode gave 50% higher current density at 30 °C with deionised water compared to that of an uncoated electrode at 2 V. Performance was found to increase with increase in temperature and with the use of alkaline solutions. The results of the solid state water electrolysis cell are promising method of producing low cost hydrogen.     

Impact of Mutual Coupling on Adaptive Switching Between MIMO Transmission Strategies and Antenna Configurations

Adaptive switching between multiple-input multiple-output (MIMO) transmission strategies like diversity and spatial multiplexing is a flexible approach to respond to channel variations. It is desirable to obtain accurate estimates of the switching points between these transmission schemes to realize the capacity gains made possible by adaptive switching. In this paper, it is shown that the accuracy of switching point estimates for switching between statistical beamforming and spatial multiplexing is improved by taking into account the effects of mutual coupling between antenna array elements. The impact of mutual coupling on the ergodic capacities of these two transmission strategies is analyzed, by deriving expressions for the same. Adaptive switching between combinations of transmission strategies and antenna array configurations (using reconfigurable antenna arrays) is shown to produce maximum capacity gains. Expressions for the switching points between transmission strategies and/or antenna configurations, including mutual coupling effects, are derived and used to explore the influence of mutual coupling on the estimates. Finally, measurements taken from reconfigurable rectangular patch antenna arrays are used to validate the analytical results.     

Defected Ground Structure Multiple Input-Output Antenna For Wireless Applications

In this paper, the investigation of a novel compact 2 × 2, 2 × 1, and 1 × 1 Ultra-Wide Band (UWB) based Multiple-Input Multiple-Output (MIMO) antenna with Defected Ground Structure (DGS) is employed. The proposed Electromagnetic Radiation Structures (ERS) is composed of multiple radiating elements. These MIMO antennas are designed and analyzed with and without DGS. The feeding is introduced by a microstrip-fed line to significantly moderate the radiating structure’s overall size, which is 60 × 40 × 1 mm. The high directivity and divergence characteristics are attained by introducing the microstrip-fed lines perpendicular to each other. And the projected MIMO antenna structures are compared with others by using parameters like Return Loss (RL), Voltage Standing Wave Ratio (VSWR), Radiation Pattern (RP), radiation efficiency, and directivity. The same MIMO set-up is redesigned with DGS, and the resultant parameters are compared. Finally, the Multiple Input and Multiple Output Radiating Structures with and without DGS are compared for result considerations like RL, VSWR, RP, radiation efficiency, and directivity. This projected antenna displays an omnidirectional RP with moderate gain, which is highly recommended for human healthcare applications. By introducing the defected ground structure in bottom layer the lower cut-off frequencies of 2.3, 4.5 and 6.0 GHz are achieved with few biological effects on radio propagation in human body communications. The proposed design covers numerous well-known wireless standards, along with dual-function DGS slots, and it can be easily integrated into Wireless Body Area Networks (WBAN) in medical applications. This WBAN links the autonomous nodes that may be situated either in the clothes, on-body or beneath the skin of a person. This system typically advances the complete human body and the inter-connected nodes through a wireless communication channel.