离子色谱法测定镀液中的六价铬离子

建立了用单柱阴离子色谱测定镀液中六价铬离子的方法.采用HPIC-CS5阴离子交换柱,以5.0 mmol/L碳酸钠和1.0 mmol/L碳酸氢钠的混合溶液作为流动相,电导检测器在20 min内完成镀液中六价铬的测定.该法具有良好的线性(相关系数约为0.996)和重复性(相对标准偏差小于5％),回收率在93％ ～107％的范围内.     

烟气氨法脱硫脱碳技术研究进展

介绍了湿式氨法脱硫技术和氨法脱碳技术.对湿式氨法脱硫技术中存在的氨逃逸、气溶胶以及铵盐结晶问题进行了阐述;对氨法脱碳技术中存在的氨逃逸以及富液再生问题进行了分析,针对这两种气体污染物处理技术所面临的问题提出了解决办法.氨水作为吸收剂可以同时吸收CO2和SO2,氨法同时脱硫脱碳技术在理论上是完全可行的.     

Nb微合金化汽车用TWIP钢的研究进展

汽车是日常生活中主要交通工具之一,其用钢质量的优劣直接关系到汽车本身及乘坐人员的安全,因此研发高性能汽车用钢至关重要。微合金化是有效改善汽车用钢性能的手段之一,微合金元素铌可细化晶粒,提高材料的强韧性及氢致延迟断裂性能,备受研究者的青睐。总结了微合金元素铌对汽车用TWIP钢组织的影响,综述了铌对汽车TWIP钢力学性能、耐磨性能及抗氢致延迟断裂性能等的作用及相应机制,并提出了现阶段铌微合金化汽车用TWIP钢研究过程中存在的问题,为后续低成本、高效地发挥铌元素在高强度汽车钢中的应用提供参考依据。     

控轧控冷工艺对高强度锚杆钢组织和性能的影响

随着矿井深度的增加,对锚杆支护强韧性的要求越来越高,为了应对这一情况,需要研发出更高强度的锚杆钢。利用锚杆钢研究了轧制工艺、冷却工艺与珠光体、铁素体相比例,析出相析出行为及力学性能的关系。研究结果表明,在中轧后、精轧前采用适当水冷+回复段处理的复合工艺可使晶粒更细小、组织更均匀。对超高强度锚杆钢进行热压缩变形试验,由热模拟试验结果确定相转变温度为A_c1=737 ℃、A_c3=886 ℃。最终筛选出入精轧温度为810 ℃、回复段温度为800 ℃时,可获得的晶粒尺寸达4 μm,珠光体体积分数为66.8%,铁素体体积分数为33.2%,珠光体片层间距达200 nm;另外调整V、Cr、N等析出以提高锚杆钢的强韧性,较低的回复温度有利于细小、弥散、V(C/N)析出相的析出,V(C/N)的析出可进一步改善锚杆钢的力学性能。由该控轧控冷工艺轧制的锚杆钢屈服强度为780 MPa、抗拉强度为930 MPa、硬度为291HV、伸长率为20%。     

Numerical simulation of microstructure formation ofAZ91 using mCA method

A stochastic model for simulating the microstructure formation of Mg alloy AZ91 during solidification was developed based on the finite element method（FEM） for macroscopic model of heat transfer calculation and a modified Cellular Automaton （mCA） for microscopic modeling of nucleation, growth of crystal. In this model, the effect of solute redistribution, interface curvature and preferred orientation was considered. A numerical simulation was developed with C＋＋ program language. The computation was carded out to understand the effect of varying processing parameters, such as nucleation parameters and heat transfer coefficient, on the microstructure formation of AZ91. The result of simulation was displayed on screen.     

一种发动机气缸体气孔缺陷分析及改进

以一种发动机气缸体气孔缺陷问题为例,通过合理优化浇注系统,更改局部结构,提高排气能力等方面提出解决思路,最终将气缸体的气孔缺陷率降至较低水平。     

铝合金牺牲阳极电流效率损耗的微观分析

探针（EPMA）和能谱分析技术(EDAX)，考察了铝合金牺牲阳极的显微结构和腐蚀后的边缘形貌，讨论了电流效率和显微组织之间的关系.结果表明：晶界腐蚀引起的晶粒脱落是铝合金牺牲阳极电流效率损耗的重要原因.      

EFFECT OF SURFACE OXIDATION ON THERMAL STABILITY OF AMORPHOUS Pd_(80)Si_(20)

<正> 本工作是在电子显微镜内原位加热的同时,观察α-Pd_(80)Si_(20)的氧化过程及其对晶化的影响。 用双喷制备的试样安装在JEM-200CX电子显微镜的加热台上,以不同的速度进行加热,并对氧化过程进行原位观察。试样室的真空度保持在～10~(-5)Pa,然后将原位观察过的试样,在Auger谱仪中用Ar~+离子对试样表面逐层剥离,以分析成分随深度的变化。为了对比,试样也在Auger谱仪中(真空度～10~(-7)Pa)进行加热,观察表面层成分随温度的变化。     

New inverse method for identification of constitutive parameters

A new inverse method by coupling iSIGHT and ABAQUS was proposed to determine the constitutive parameters of Al2O3sf/LY12 composite deforming at elevated temperature. It combined the merits of the f＇mite element simulation and optimization technique. The direct model was simulated with finite element code ABAQUS. The inverse problem associated with the identification of the constitutive parameters was expressed as a least square optimization problem. The direct simulation and the parameters optimization were implemented in iSIGHT integrated environment. The aim was to match the output of the direct simulation with the experiment data. The capability of the proposed inverse method was demonstrated through the identification of constitutive parameters of Al2O3sf/LY12 composite. The proposed new inverse method is also applicable to other parameters identification which is hardly determined through experiments or direct analytical method.     

Preparation of alumina-doped yttria-stabilized zirconia nanopowders by microwave-assisted peroxyl-complex coprecipitation

Alumina-doped yttria-stabilized zirconia （ADYSZ） nanopowders were prepared by microwave-assisted peroxyl-complex coprecipitation （MAPCC） using ZrOCl2-8H2O, Y2O3 and AICly6H2O as starting materials, NH2-H2O as precipitant and H2O2 as complexant. The effects of adding H2O2 and microwave drying on the preparation and properties of ADYSZ were investigated. The precursors and nanopowders were studied by EDX, XRD, SEM and TEM techniques. The results show that the uniformity of component distribution within ADYSZ nanopowders is improved by adding appropriate dosage of H2O2. Complexing reaction between H2O2 and Zr^4＋ ion restrains the hydrolyzation and precipitation of Zr^4＋ ion. With the addition of H2O2, Al^3＋, y^3＋ and Zr^4＋ ions can be precipitated synchronously in a relatively narrow range of pH value. H2O2 also improves the filterability of the wet precipitate. The highly hydrophilic precipitates can be quickly and effectively separated from aqueous solution. During microwave drying process, the moisture of wet precursors is selectively heated. Quick expansion of steam vapor within the wet colloidal particles causes the aggregations burst into numerous tiny lumps. Compared with oven drying, microwave drying can not only shorten drying time but also reduce aggregation intensity of the resultant ADYSZ nanopowders.