Morphology and properties of poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene]/silica nanoparticle hybrid films

Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry     

即时通讯软件的安全性分析

在互联网服务中,即时通讯已成为了最流行的服务模式之一,人们对即时通讯的依赖程度也与日俱增。但是, 频频出现的病毒和黑客攻击使广大用户深受其害,即时通讯的安全问题也日益严峻。为了从根本上解决问题,本文对即时通讯软件的架构和协议进行了深入分析,目的是找出漏洞根源,给开发者和使用者提供防止漏洞的依据。     

Preparation of flexible polyhedral particles via concentrated emulsion templating polymerization

This paper presents recent efforts on the preparation of flexible polyhedral particles via concentrated emulsion templating polymerization in which the hydrophilic monomer (acrylamide) and hydrophobic monomer (butyl acrylate) are polymerized simultaneously in the continuous and dispersed phase, respectively. Such templating polymerization has been enhanced in our systems owing to the introduction of acrylamide monomer and their higher polymerization rate in continuous phase as compared with butyl acrylate in dispersed phase. Diffusion between the different phases was also inhibited. Furthermore, the stability of the concentrated emulsion and the molecular weight of the produced poly(butyl acrylate) were found to be significantly affected by the amount of redox initiator. The morphology of the particles could be controlled by varying the volume fraction of the dispersed phase and the polyhedral particles were achieved at higher volume fraction. Copyright © 2005 Society of Chemical Industry     

�Ĵ������Ȼ�����������б�����Դ̽��

本文应用天然气中甲烷、乙烷的碳同位素,甲烷的氢同位素,汞含量及天然气成分等指标,探讨了四川盆地天然气成因分类;并结合地质情况对气源层进行了探讨。     

印染废水处理工艺研究及实例

本文简要介绍了印染废水水质特征,提出了处理工艺,并利用两个工程实例说明了该工艺的可行性.     

Effect of boron on the low-cycle fatigue behavior and deformation structure of INCONEL 718 at 650 °C

Symmetrical push-pull low-cycle fatigue (LCF) tests were performed on INCONEL 718 (IN718) containing 12, 29, 60, and 100 ppm B at 650 °C. The results showed that all the alloys experienced a relatively short period of initial cyclic hardening at low strain amplitudes, followed by a regime of saturation or slightly continuous cyclic softening. The initial cyclic hardening phase decreased with increasing strain amplitudes, and disappeared at the high strain amplitudes. A serrated flow was observed in the plastic regions of cyclic stress-strain hysteresis loops. The saturated cyclic stress amplitude at a given strain amplitude was highest for the alloy with 60 ppm B, and lowest for the alloy with 12 ppm B. The LCF lifetime increased with increasing B concentration up to 60 ppm, and then decreased as the B content increased from 60 to 100 ppm. Fractographic analysis suggested that the fracture mode changed from intergranular to transgranular cracking as the B concentration increased. The characteristic deformation microstructures produced by LCF tests at 650 °C, examined via transmission electron microscopy, were regularly spaced arrays of planar deformation bands on {111} slip planes in all four alloys. A ladderlike structure was observed in some local regions in the alloy with 12 ppm B. Heavily deformed planar deformation bands were observed in the fatigued specimens with 100 ppm B. The mechanism of improvement in the LCF life of IN718 due to B addition is discussed.     

Effects of Na, Cu, Ni and Co Modifications on the Activity and Characteristics of Rh/Al2O3 Catalysts for NO Reduction

This study used different metals to modify Rh/Al₂O₃ catalysts for NO reduction in a simulated waste incineration flue gas containing 6% O₂. The characteristics of the modified catalysts were analyzed using BET, TEM and XRD. The results of the experiment reveal that Na addition can significantly affect the properties of Rh/Al₂O₃ catalysts on the BET surface area and Rh metal dispersion. Furthermore, Na addition was found to significantly enhance the NO conversion of Rh/Al₂O₃ at 250–350 °C. On the contrary, Cu, Ni, and Co addition was found to have slight suppression effects.