Photoinitiated crosslinking of ethylene‐vinyl acetate copolymers and characterization of related properties

Photoinitiated crosslinking of EVA in the presence of benzophenone (BP) as photoinitiator and triallyl isocyanurate (TAIC) as crosslinker and characterization of the related properties have been studied by gel determination, heat extension, DSC, DMTA, TGA, and mechanical measurements. The photoinitiated crosslinking efficiency of the EVA‐BP‐TAIC system and various factors affecting the crosslinking process, such as photoinitiator and crosslinker and their concentrations, irradiation temperature, and irradiation atmosphere were studied in detail and optimized by comparison of gel contents. The results show that the EVA samples with a thickness of 1 mm are readily crosslinked to a gel content of above 80% with 5 s UV‐irradiation under optimum conditions. The data from the heat extension and DSC show that the crosslinking density of photocrosslinked EVA increase and their crystallinities decrease with increasing the UV‐irradiation time. At the same time, photocrosslinking of EVA leads to a lowering of the melt temperature and a decrease of heat of fusion. The DMTA results show that photocrosslinking increases the amorphous phase and storage modulus of the crosslinked EVA, but does not change the glass transition temperature. The data from TGA and mechanical tests give evidence that the thermal stability and mechanical properties of photocrosslinked EVA samples are much better than those of the uncrosslinked EVA. POLYM. ENG. SCI., 47:1761–1767, 2007. © 2007 Society of Plastics Engineers     

Low-temperature catalytic combustion of methane over MnO x –CeO2 mixed oxide catalysts: Effect of preparation method

The effect of preparation method on MnO _x –CeO₂ mixed oxide catalysts for methane combustion at low temperature was investigated by means of BET, XRD, XPS, H₂-TPR techniques and methane oxidation reaction. The catalysts were prepared by the conventional coprecipitation, plasma and modified coprecipitation methods, respectively. It was found that the catalyst prepared by modified coprecipitation was the most active, over which methane conversion reached 90% at a temperature as low as 390 °C. The XRD results showed the preparation methods had no effect on the solid solution structure of MnO _x –CeO₂ catalysts. More Mn⁴⁺ and richer lattice oxygen were found on the surface of the modified coprecipitation prepared catalyst with the help of XPS analysis, and its reduction and BET surface area were remarkably promoted. These factors could be responsible for its higher activity for methane combustion at low temperature.     

Application of ACO algorithm in protein structure prediction

The hydrophobic-polar (HP) lattice model is an important simplified model for studying protein folding. In this paper, we present an improved ACO algorithm for the protein structure prediction. In the algorithm, the "lone"ethod is applied to deal with the infeasible structures, and the "oint mutation and reconstruction"ethod is applied in local search phase. The empirical results show that the presented method is feasible and effective to solve the problem of protein structure prediction, and notable improvements in CPU time are obtained.     

一种高效的电子政务系统的设计与应用

计算机网络技术的出现,全球信息化改变着人们的生活方式,世界各国高度重视发展电子政务,它是一个国家及城市竞争力水平的标志之一.在这样严峻的社会形势下,建立一个高效的电子政务系统是十分必要的.首先,分析了建立电子政务系统的必要性、特点、功能;然后,提出了电子政务系统的体系模型,设计出了功能结构图和网络结构图,详细地描述了方案思路;最后,把此模型应用到商洛市旅游行业中,经过调查数据研究分析,政务系统的出现给旅游业带来巨大的变化,整个城市的经济、影响力大幅度上升.     

FGTO — A fine structured GTO-thyristor with improved switching characteristics

Contents A fine structured GTO thyristor, abbreviated FGTO, has been developed to improve the switching characteristics. The new device has a cathode finger width of only 20 m and can be turned off without a negative gate bias at an anode current level of more than 200 A/cm². The turn-off time can be shortened down tot _off 500 ns by increasing the negative gate current. A snubber circuit is not necessary to turn off the FGTO's. The maximum rate of rise of anode voltage du/dl reaches more than 10 kV/s. Analytical models are developed to describe the turn-off transients of the FGTO's. Good agreement between the theoretical and experimental results could be achieved.

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FGTO — Ein feinstrukturierter GTO-Thyristor mit verbessertem Schaltverhalten

Übersicht Zur Verbesserung des Schaltverhaltens ist ein feinstrukturierter GTO-Thyristor, abgekürzt FGTO, entwickelt worden. Dieses neue Bauelement hat eine Kathoden-streifenbreite von nur 20 m und kann ohne negative Gatevorspannung bei einer Anodenstromdichte von mehr als 200 A/cm² abgeschaltet werden. Die Abschaltzeit läßt sich durch Erhöhung des negativen Gatestroms bis zut _off 500 ns verkürzen. Beim Abschalten von FGTOs ist keine RC-Beschaltung erforderlich. Der maximale du/dl-Wert erreicht mehr als 10 kV/s. Zur Beschreibung des Abschalt-verhaltens von FGTOs werden analytische Modelle entwickelt, die eine gute Übereinstimmung mit den Meßergebnissen liefern.

     

Differential amplification method for flow structures analysis of centrifugal pump between design and off-design points

Journal of Central South University - The three-dimensional internal flow field of centrifugal pump is complex and variable with design parameters and operation conditions. The post-processing...     

基于LDA和word2vec的英文作文跑题检测

针对目前国内的英语作文辅助批阅系统缺少准确而高效的跑题检测算法的问题,提出了一种结合LDA和Word2vec的跑题检测算法。该算法利用LDA模型对文档建模并通过Word2vec对文档训练,利用得到的文档主题和词语之间的语义关系,对文档中各主题及其特征词计算概率加权和,最终通过设定合理阈值筛选出跑题作文。实验中通过改变文档的主题数而得到的不同F值,确定了最佳主题数。实验结果表明所提出的方法比基于向量空间模型的方法更具有效性,可以检测到更多的跑题作文并且准确率较高,F值达到89%以上,实现了作文跑题检测的智能化处理,可以有效地应用在英语作文教学中。     

粉末注射成形Fe-50%Ni软磁合金

Fe-50%Ni合金是一种典型的高磁导率和低矫顽力的软磁材料,有着广阔的应用前景.本次实验以羰基铁粉和羰基镍粉为原料粉末,采用注射成形方法制取Fe-50%Ni软磁合金,研究了高能球磨制备粉末对注射成形工艺以及材料性能的影响.研究结果表明与未经过高能球磨的混合粉末相比,高能球磨改变了原料粉末的粒度和粒度组成,提高了粉末的振实密度,进而提高了装载量.通过显微组织分析得知,高能球磨能使两种粉末发生塑性变形并冷焊合,形成了复合粉,促进了两种成分之间发生扩散和固态反应,同时还增加了粉末颗粒的能量,使颗粒表面活化,促进了烧结,提高了烧结材料的致密度.本实验最终获得了高性能的软磁合金材料磁导率41.27 mH/m,饱和磁感应强度1.498 T,矫顽力7.533 A/m.所得到的软磁材料性能优于相应传统粉末冶金方法获得的材料性能.     

TiAl基合金热处理显微组织缺陷

研究了等温锻造和热处理后ＴｉＡｌ基合金显微组织中晶粒尺寸不均匀参数，讨论了这种缺陷对ＴｉＡｌ基合金室温抗拉笥能的影响，提出了这种显微组织缺陷形成机理。     

Accelerated electrospark deposition and the wear behavior of coatings

Electrospark deposition (ESD) is a coating process that is featured by low heat input to the substrate. Low coating efficiency and other limitations influence its wider application. The present paper introduces newly designed ESD equipment, by which a higher coating rate can be reached. The relationship among coating thickness, surface roughness, and process parameters such as pulse energy, pulse frequency, and deposition time are presented. Electrospark deposition coating by the new equipment on AISI 1045 steel (with WC-8% Co as electrode) increases the wear resistance by 5 to 8 times. The micromechanism is investigated by scanning electron microscopy observation.