In Situ Polymerizing Internal Encapsulation Strategy Enables Stable Perovskite Solar Cells toward Lead Leakage Suppression

Despite the outstanding power conversion efficiency (PCE) of perovskite solar cells (PSCs) achieved over the years, unsatisfactory stability and lead toxicity remain obstacles that limit their competitiveness and large-scale practical deployment. In this study, in situ polymerizing internal encapsulation (IPIE) is developed as a holistic approach to overcome these challenges. The uniform polymer internal package layer constructed by thermally triggered cross-linkable monomers not only solidifies the ionic perovskite crystalline by strong electron-withdrawing/donating chemical sites, but also acts as a water penetration and ion migration barrier to prolong shelf life under harsh environments. The optimized MAPbI₃ and FAPbI₃ devices with IPIE treatment yield impressive efficiencies of 22.29% and 24.12%, respectively, accompanied by remarkably enhanced environmental and mechanical stabilities. In addition, toxic water-soluble lead leakage is minimized by the synergetic effect of the physical encapsulation wall and chemical chelation conferred by the IPIE. Hence, this strategy provides a feasible route for preparing efficient, stable, and eco-friendly PSCs.     

Metal Single-Site Molecular Complex–MXene Heteroelectrocatalysts Interspersed Graphene Nanonetwork for Efficient Dual-Task of Water Splitting and Metal–Air Batteries

Development of multifunctional electrocatalysts with high efficiency and stability is of great interest in recent energy conversion technologies. Herein, a novel heteroelectrocatalyst of molecular iron complex (Fe_MC)-carbide MXene (Mo₂TiC₂T_x) uniformly embedded in a 3D graphene-based hierarchical network (GrH) is rationally designed. The coexistence of Fe_MC and MXene with their unique interactions triggers optimum electronic properties, rich multiple active sites, and favorite free adsorption energy for excellent trifunctional catalytic activities. Meanwhile, the highly porous GrH effectively promotes a multichannel architecture for charge transfer and gas/ion diffusion to improve stability. Therefore, the Fe_MC–MXene/GrH results in superb performances towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The practical tests indicate that Zn/Al–air batteries derived from Fe_MC–MXene/GrH cathodic electrodes produce high power densities of 165.6 and 172.7 mW cm⁻², respectively. Impressively, the liquid-state Zn–air battery delivers excellent cycling stability of over 1100 h. In addition, the alkaline water electrolyzer induces a low cell voltage of 1.55 V at 10 mA cm⁻² and 1.86 V at 0.4 A cm⁻² in 30 wt.% KOH at 80 °C, surpassing recent reports. The achievements suggest an exciting multifunctional electrocatalyst for electrochemical energy applications.     

Research and Implementation of Parallel Artificial Fish Swarm Algorithm Based on Ternary Optical Computer

Mobile Networks and Applications - Artificial fish swarm algorithm (AFS) is used in the field of function optimization problems widely. The traditional AFS algorithm has some problems such as long...     

Friendly spectrum jamming against MIMO eavesdropping

Wireless Networks - Friendly spectrum jamming is a flexible scheme to establish secure communications among heterogeneous wireless devices without the need of encryption. Previous works have...     

Social-path embedding-based transformer for graduation development prediction

As the education of students attracts more and more attention, the task of graduation development prediction has gradually become a hot topic in academia and industry. The task of graduation development prediction aims to predict the employment category of students in advance via academic achievement data, which can help administrators understand students’ learning status and set up a reasonable learning plan. However, existing research ignores the potential impact of social relationships on students’ graduation development choices. To fully explore social relationships among students, we propose a Social-path Embedding-based Transformer Neural Network (SPE-TNN) for the task of graduation development prediction in this paper. Specifically, SPE-TNN is divided into the Social-path selection layer, the Social-path embedding layer, the Transformer layer, and the Multi-layer projection layer. Firstly, the Social-path selection layer is designed to find social relationships that impact graduation development and embed them into the student’s performance features through the Social-path embedding layer. Secondly, the Transformer layer is adopted to balance the weights of the students’ features. Finally, the Multi-layer projection layer is used to achieve the student graduation development prediction. Experimental results on the real-world datasets show that SPE-TNN outperforms the existing popular approaches.

     

基于多通道脑电信号的因果网络情绪识别

情绪是由大脑内多个通道共同作用产生的,格兰杰因果检验作为情绪识别的主流方法,在计算任意2个通道之间的因果关系时容易忽略其他通道的影响。面向多通道脑电信号,提出一种基于条件格兰杰因果检验（CGC）的因果网络情绪识别方法。利用CGC算法计算不同情绪下大脑全通道的因果关系,据此构建因果网络,并通过分析各通道的入/出度和介数拓扑属性找到关键通道,得到简化的因果网络进行情绪识别。将节点之间的因果连接关系作为特征分别输入SVM和KNN分类器进行分类训练,实验结果表明,简化网络的识别率分别为75.3%和78.4%,验证了所提方法的有效性。     

关键词最优路径查询的分段拓展算法

关键词最优路径查询（KOR）查找在满足关键词全覆盖和路径长度约束条件下,时间开销最小的路线常用于旅行规划。现有优化算法虽然采用各种剪枝策略缩小搜索规模,但是本质上是广度优先搜索,在查找长路径时,搜索规模依然过大,执行时间长。针对该问题,提出一种关键词最优路径查询的分段拓展算法（SE-KOR）。SE-KOR算法根据关键词倒排索引表构建关键词顶点路径,将路径划分为多段分别拓展,降低搜索规模,从而缩短执行时间。该算法在路径拓展时给出路径走向,而现有剪枝策略不控制路径拓展方向,因此提出局部代价阈值剪枝,控制路径的走向沿关键词顶点路径拓展,并综合运用近似支配、可行解目标值剪枝和全局优先拓展策略加速拓展。实验结果表明,在不损失精度的情况下,该算法执行时间分别在不同关键词个数、代价阈值与查询图规模下至少缩短8.0%、61.0%和57.7%。     

Bioinspired yeast microcapsules loaded with self-assembled nanotherapies for targeted treatment of cardiovascular disease

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