基于需求侧博弈的区域综合能源服务商最优运营策略

为了提高综合能源服务商运营服务的高效性、清洁性和经济性,提出了一种基于需求侧博弈的综合能源服务商最优运营策略。通过对综合能源服务商模型的分析,以用户能源消耗量确定系统碳排放量,建立了区域综合能源服务商碳排放模型,确定了园区的碳排放量。在此基础上,考虑了用户对用能成本波动的可承受能力和服务商应对用户用能变化的风险成本,分别以综合能源服务商全天利润最大、用户用能成本最小为目标函数,建立了综合能源服务商-多用户博弈优化模型。采用迭代搜索法得到纳什均衡解,从而确定服务商最优运营策略。最后以典型工业园区为例对所提策略进行仿真验证。结果表明,所研究的服务商运营策略有效降低了系统碳排放量,提高了综合能源服务商的经济效益和用户满意度。     

A multi-energy inertia-based power support strategy with gas network constraints

An integrated energy system with multiple types of energy can support power shortages caused by the uncertainty of renewable energy. With full consideration of gas network constraints, this paper proposes a multi-energy inertia-based power support strategy. The definition and modelling of gas inertia are given first to demonstrate its ability to mitigate power fluctuations. Since partial utilization of gas inertia can influence overall gas network parameters, the gas network is modelled with an analysis of network dynamic changes. A multi-energy inertia-based power support model and strategy are then proposed for fully using gas-thermal inertia resources in integrated energy systems. The influence of gas network constraints on strategy, economy and power outputs is analyzed. Special circumstances where the gas network can be simplified are introduced. This improves the response speed and application value. The feasibility and effectiveness of the proposed strategy are assessed using a real scenario.     

Promote Intratumoral Drug Release and Penetration to Counteract Docetaxel-Induced Metastasis by Photosensitizer-Modified Red Blood Cell Membrane-Coated Nanoparticle

The red blood cell membrane (RBCm) provides tight protection, lowers the immunogenicity, and prolongs the circulation time of drugs in vivo when acting as the coating of drug delivery systems. However, the cellular uptake and release of drugs are hindered by RBCm. Docetaxel (DTX) is the first-line medicine for treating triple-negative breast cancer (TNBC), but it induces tumor metastasis. To solve these dilemmas, in this study, the photosensitizer 1,1-dioctadecyl-3,3,3,3-tetramethylindotricarbocyanine iodide (DiR)-modified RBCm (DM) is prepared, which is coated onto a hybrid micelle consisting of the prodrugs of DTX and the anti-metastasis agent calcitriol (CTL), obtaining a nanoparticle, named HDC-DM. In a 4T1 tumor-bearing mouse model, after injecting HDC-DM, the intratumoral DTX and CTL concentrations are increased by 1.7 and 2.5 times compared with the free drug groups. After irradiating tumors with near-infrared laser, DiR elicits the photothermal effect, triggering the rupture of RBCm and drug release, promoting drug penetration in tumors, and inducing immunogenic cell death. The tumor growth inhibition rate is 77%, and the formation of lung metastases is reduced by 82%, with good biocompatibility. It is suggested that the combination of phototherapy, chemotherapy, and anti-metastatic therapy using HDC-DM is expected to be a powerful strategy for treating TNBC.     

Challenges and Opportunities of Implantable Neural Interfaces: From Material,Electrochemical and Biological Perspectives

The desirable implantable neural interfaces can accurately record bioelectrical signals from neurons and regulate neural activities with high spatial/time resolution, facilitating the understanding of neuronal functions and dynamics. However, the electrochemical performance (impedance, charge storage/injection capacity) is limited with the miniaturization and integration of neural electrodes. The “crosstalk” caused by the uneven distribution of elctric field leads to lower electrical stimulation/recording efficiency. The mismatch between stiff electrodes and soft tissues exacerbates the inflammatory responses, thus weakening the transmission of signals. Though remarkable breakthroughs have been made through the incorporation of optimizing electrode design and functionalized nanomaterials, the chronic stability, and long-term activity in vivo of the neural electrodes still need further development. In this review, the neural interface challenges mainly on electrochemistry and biology are discussed, followed by summarizing typical electrode optimization technologies and exploring recent advances in the application of nanomaterials, based on traditional metallic materials, emerging 2D materials, conducting polymer hydrogels, etc., for enhancing neural interfaces. The strategies for improving the durability including enhanced adhesion and minimized inflammatory response, are also summarized. The promising directions are finally presented to provide enlightenment for high-performance neural interfaces in future, which will promote profound progress in neuroscience research.     

基于用户行为的社交网络人格特质识别方法

社交网络已成为人们获取和发布信息的一个重要平台,也是黑客发起网络诈骗的主要场地。大多数黑客在发起网络诈骗之前,首先会判别目标用户的主要人格特点,然后根据主要人格特点制定与其接触的策略。因此,面向社交网络用户的人格特质识别方法的研究对提高用户识别社交网络诈骗能力具有重要意义。提出基于用户的人格特质识别方法。通过构建面向社交网络的人格特质词典提取用户发表或转发文本信息中能反映用户主要人格特质类型的观测值,采用5个具有不同参数值的隐半马尔可夫模型刻画用户在社交网络上发表或转发文本信息的行为过程。在人格特质识别阶段,通过计算每个用户在发表或转发文本信息过程中产生的观测序列相对于模型的平均对数似然概率,以识别用户所属的人格特质类型。在采集的新浪微博数据集上进行实验,结果表明,当假正率为10%时,该方法的总真正率为93.18%,能准确识别用户的人格特质类型。     

结合感知损失与双重对抗网络的低剂量CT图像去噪

低剂量计算机断层扫描（LDCT）成像技术在医学诊断中得到广泛应用,但其斑纹噪声和非平稳条纹伪影复杂,目前多数算法仅依靠推断条件后验概率来实现图像去噪,无法应对LDCT图像噪声复杂、数据量少、先验知识缺乏的问题。提出一种结合感知损失的双重对抗网络去噪算法,以实现LDCT图像复原。该算法包含一个去噪器和一个生成器,分别从图像去噪和噪声生成2个角度来建模干净-噪声图像对的联合分布,通过联合学习使得去噪器和生成器相互指导,从而充分学习数据中的噪声信息和清晰图像信息,且学习到的去噪器可以直接用于LDCT图像修复。考虑到通过感知损失学习语义特征差异可以使去噪结果保留更多的细节和边缘信息,提出一种掩膜自监督方法,针对CT图像域训练一个语义特征提取网络用于计算感知损失。实验结果表明,与BM3D、RED-CNN、WGAN-VGG等主流去噪算法相比,该算法可以有效抑制噪声并去除伪影,最大程度地保留边缘轮廓和纹理细节,产生更符合人眼视觉特性的去噪效果,与当下LDCT图像去噪性能较好的SACNN算法相比,所提算法的PSNR和SSIM指标分别提升1.26 dB和1.8%。     

Hydrofluoric Acid-Removable Additive Optimizing Electrode Electrolyte Interphases with Li+ Conductive Moieties for 4.5 V Lithium Metal Batteries

High-voltage lithium metal batteries (LMBs) are capable to achieve the increasing energy density. However, their cycling life is seriously affected by unstable electrolyte/electrode interfaces and capacity instability at high voltage. Herein, a hydrofluoric acid (HF)-removable additive is proposed to optimize electrode electrolyte interphases for addressing the above issues. N, N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) aniline (DMPATMB) is used as the electrolyte additive to induce PF₆⁻ decomposition to form a dense and robust LiF-rich solid electrolyte interphase (SEI) for suppressing Li dendrite growth. Moreover, DMPATMB can help to form highly Li⁺ conductive Li₃N and LiBO₂, which can boost the Li⁺ transport across SEI and cathode electrolyte interphase (CEI). In addition, DMPATMB can scavenge traced HF in the electrolyte to protect both SEI and CEI from the corrosion. As expected, 4.5 V Li|| LiNi_0.6Co_0.2Mn_0.2O₂ batteries with such electrolyte deliver 145 mAh g⁻¹ after 140 cycles at 200 mA g⁻¹. This work provides a novel insight into high-voltage electrolyte additives for LMBs.     

Grafted MXenes Based Electrolytes for 5V-Class Solid-State Batteries

Polymer blends based solid polymer electrolytes (SPEs), combining the advantages of multiple polymers, are promising for the utilization of 5 V-class cathodes (e.g., LiCoMnO₄ (LCMO)) with enhanced safety. However, severe macro-phase separation with defects and voids in polymer blends restrict the electrochemical stability and ionic migration of SPEs. Herein, inorganic compatibilizer polyacrylonitrile grafted MXene (MXene-g-PAN) is exploited to improve the miscibility of the poly(vinylidene fluoride-co-hexafluoropropylene) (PVHF)/PAN blends and suppress the consolidation of phase particles. The resulting SPE exhibits a high anodic stability with an ionic conductivity of 2.17 × 10⁻⁴ S cm⁻¹, enabling a stable and reversible Li platting/stripping (over 2500 h). The fabricated solid Li‖LCMO cell delivers a 5.1 V discharge voltage with a decent capacity (131 mAh g⁻¹) and cycling performance. Subsequently, the solid all-in-one graphite‖LCMO battery is also constructed to extend the application of MXene based SPEs in flexible batteries. Benefiting from the interface-less design, outstanding mechanical flexibility and stability is achieved in the battery, which can endure various deformations with a low-capacity loss (< ≈10%). This study signifies a significant development on solid flexible lithium ion batteries with enhanced performance, stability, and reliability by investigating the miscibility of polymer blends, benefiting for the design of high-performance SPEs.     

High-Performing Quasi-2D Perovskite Photodetectors with Efficient Charge Transport Network Built from Vertically Orientated and Evenly Distributed 3D-Like Phases

Quasi-two-dimensional (Q-2D) perovskites are emerging as one of the most promising materials for photodetectors. However, a significant challenge to Q-2D perovskites for photodetection is their insufficient charge transport ability, which is mainly attributed to their hybrid low-dimensional n-phase structure. This study demonstrates that evenly-distributed 3D-like phases with vertical orientation throughout the film can greatly facilitate charge transport and suppress charge recombination, outperforming the prevalent phase structure with a vertical dimension gradient. Based on such a phase structure, a Q-2D Ruddlesden−Popper perovskite self-powered photodetector achieving a combination of exceptional figures-of-merit is realized, including a responsivity of 0.45 AW⁻¹, a peak specific detectivity of 2.3 × 10¹³ Jones, a 156 dB linear dynamic range, and a rise/fall time of 2.89 µs/1.93 µs. The desired phase structure is obtained by utilizing a double-hole transport layer (HTL), combining hydrophobic PTAA and hydrophilic PEDOT: PSS. Besides, the dependence of the hybrid low-dimensional phase structure is also identified on the surface energy of the buried HTL substrate. This study gives insight into the correlation between Q-2D perovskites’ phase structure and performance, providing a valuable design guide for Q-2D perovskite-based photodetectors.     

A Polymer Defect Passivator for Efficient Hole-Conductor-Free Printable Mesoscopic Perovskite Solar Cells

Due to the low cost and excellent potential for mass production, printable mesoscopic perovskite solar cells (p-MPSCs) have drawn a lot of attention among other device structures. However, the low open-circuit voltage (V_OC) of such devices restricts their power conversion efficiency (PCE). This limitation is brought by the high defect density at perovskite grain boundaries in the mesoporous scaffold, which results in severe nonradiative recombination and is detrimental to the V_OC. To improve the perovskite crystallization process, passivate the perovskite defects, and enhance the PCE, additive engineering is an effective way. Herein, a polymeric Lewis base polysuccinimide (PSI) is added to the perovskite precursor solution as an additive. It improves the perovskite crystallinity and its carbonyl groups strongly coordinate with Pb²⁺, which can effectively passivate defects. Additionally, compared with its monomer, succinimide (SI), PSI serves as a better defect passivator because the long-chained macromolecule can be firmly anchored on those defect sites and form a stronger interaction with perovskite grains. As a result, the champion device has a PCE of 18.84%, and the V_OC rises from 973 to 1030 mV. This study offers a new strategy for fabricating efficient p-MPSCs.