对叔丁基苄胺的合成研究

摘要选择Delepine反应法的路线合成对叔丁基苄胺，并对反应投料比、反应温度及酸化后的反应时间进行了优化试验，得到了较好的反应条件：反应温度为40℃，对叔丁基苄氯与乌洛托品投料比为1：1；加入酸和醇后的保温时间为2h，从而使反应收率稳定在90％以上，含量达到95％。     

Effect of fretting amplitudes on fretting wear behavior of steel wires in coal mines

Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes ranging from 5 to 180 μm. We observed morphologies of fretted steel wire surfaces on an S-3000N scanning electron microscope in order to analyze fretting wear mecha-nisms. The results show that the fretting regime of steel wires transforms from partial slip regime into mixed fretting regime and gross slip regime with an increase in fretting amplitudes under a given contact load. In partial slip regime, the friction coefficient has a relatively low value. Four stages can be defined in mixed fretting and gross slip regimes. The fretting wear of steel wires in-creases obviously with increases in fretting amplitudes. Fretting scars present a typical morphology of annularity, showing slight damage in partial slip regime. However, wear clearly increases in mixed fretting regime where wear mechanism is a combination of plastic deformation, abrasive wear and oxidative wear. In gross slip regime, more severe degradation is present than in the other regimes. The main fretting wear mechanisms of steel wires are abrasive wear, surface fatigue and friction oxidation.     

Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

基于模块化模型的自适应预失真技术

系统地比较和分析了OFDM传输系统里高功率放大器（HPA）预失真方法的优缺点,提出一种基于模块化模型的有记忆高功率放大器自适应数字预失真方法,该方法分别基于Wiener、Hammerstein和Wiener-Hammerstein模型各自构成一个有记忆HPA的自适应预失真器。从而避免了因分别估计Wiener-Hammerstein模型各个环节特性参数所带来的复杂性。使得有记忆高功率放大器的预失真设计变得简单了。     

交通运输业节能减排国际管理手段及启示

交通运输业的能源消费在许多国家中都占有较高比例,经济发展较快的国家更是如此。介绍了能源消费大国英国、美国、欧盟以及日本交通运输业节能减排采取的主要管理手段,包括健全的法律体系、节能技术创新、有效的税费政策等。借鉴其先进经验,为我国交通运输业节能减排管理工作提供启示。     

因子分析法和熵值法在高校科技创新评价中的应用

在已有研究的基础上总结出了一套科学合理并具有可行性的高校科技创新评价指标体系,并把因子分析法和熵值法应用于高校科技创新评价.首先对高校科技创新评价体系的5个一级指标分别进行因子分析,然后运用熵值法对其确定权重.分析结果表明两种方法的结合使用能够简化分析对象的结构,使评价结果更具科学性、客观性.     

电子商务配送速度与客户退单的关联建模仿真

在电子商务中,产品的配送速度与客户的退单率之间存在着较为复杂的关联性,这种关联性受到所在地域、购买时间、运输能力、订单处理能力、人为因素等多方因素的影响十分复杂.传统的建模方法只能利用多个简单的线性关系进行描述,加入了更多的复杂约束过程的描述,模型复杂,无法准确反映两者关系.为解决上述问题,提出基于PLS_SEM算法的电子商务中产品的配送速度与客户退单的关系建模方法.根据PLS_SEM算法的构建复杂模型特有的优势,建立电子商务客户退单评价模型,并利用退单校验因子定量分析了电子商务中不同的变量对于客户退单的影响,可以较好地解决模型中存在的过多约束问题,保证建模准确性.仿真结果表明,利用PLS_SEM算法能够实现对电子商务中产品配送速度与客户退单的关系进行准确分析,效果令人满意.     

红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.     

燃煤发电机组锅炉节油技术

介绍浙能长兴发电有限公司300MW燃煤机组锅炉在节约燃油方面所采取的措施.     

Effects of gold plating on the resistance to high temperature discoloration of the cavity for ceramic packages

The effects of thickness and types of gold plating on the resistance to high temperature discoloration of gold plating on cavity surface of ceramic package were investigated. It was found that the thicker gold plating, the less discoloration degree for ceramic packages. Non-cyanide gold plating performed better resistance to high-temperature aging than cyanide gold plating. The relationship between the gold plating thickness and the amount of diffused Ni to the gold plating of ceramic packages with Au/Ni and Au/Ni-Co platings after heating at 420℃for 15 min was also studied. When the gold plating thickness reach 2.0 μm and 1.6 μm for Au/Ni and Au/Ni-Co plating systems, respectively, no discoloration was observed on the gold plating surface of cavity, and the corresponding diffused Ni amounts (mass fraction) are 1.0% and 0.4%, while the diffused Co to the gold plating is 0.04%.