Viscoelastic properties of polyarylene ether nitriles/thermotropic liquid crystalline polymer blend

Polyarylene ether nitriles (PEN)/thermotropic liquid crystalline polymer (TLCP) blend was prepared via melt mixing. The immiscible phase morphologies, linear and nonlinear, as well as transient viscoelastic properties of the blend were studied using SEM, rheometer, and DMA. The linear dynamic viscoelastic behavior of the blend shows temperature dependence due to further evolution of the immiscible morphology and, as a result, the principle of time‐temperature superposition (TTS) is invalid. In the steady shear flow, the discrete TLCP phase is difficult to be broken up because of the high viscosity ratio of the blend systems, while is easy to be coarsened and followed by elongation, and finally, to form fibrous morphology at high TLCP content and high shear level. During this morphological evolution process, the transient stress response presents step increase and nonzero residual relaxation behavior, leading to increase of the dynamic viscoelastic responses after steady preshear. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Modeling the effect of pigment morphology on the dynamic compression of coating layers using DEM

In the present paper, discrete element method (DEM) was employed to investigate the effect of pigment morphology on packing dynamics and compressive behavior of paper coating layers in calendering process. Spherical, platy, and needle-like particles, representing GCC, delaminated clay, and aragonite PCC pigments, were considered in this study. For each particle shape, the compression of coating structures formed by mono-sized and poly-dispersed pigments were modeled. Stress–strain behavior of the coating layers and in-plane and out-of-plane movements of the pigment particles during the compression were computed under the same maximum compressive stress. Simulation results revealed that the in-plane movements of the pigment particles during compression in the calender nip were small in magnitude (<0.35 μm). These findings help to better understand the smoothening phenomena of coating structures during the calendering process.     

港口起重机风灾事故的防范

介绍了港口起重机所受风害的种类及其设防情况,分析了起重机结构形式与风作用的关系。介绍了上海国际港务(集团)有限公司几种常用的大型起重机防风装置的原理、功效及检测情况。     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

管内覆丝网强化对流换热及阻力特性的实验研究

通过实验对管内覆丝网管进行了强迫对流换热和阻力特性研究。结果表明：管内覆丝网使换热明显增强，阻力也相应增长。菱形丝网对角线距离与平行边距离之比对换热效果有决定作用，丝网厚度对换热的影响比较小，而丝网网格的大小对换热几乎没有影响，在相同的泵功率和几何条件下，换热系数最大增加２１％。     

空泡溃灭水锤的VOF计算方法

空泡溃灭水锤是核电厂冷却循环系统中较常出现的一种严重的水锤事故。空泡的形成和溃灭是复杂的两相、瞬态过程，对于这一现象的分析是相当困难的。作者尝试着把蒸汽泡的边界看成是冷水流动的自由面，在自由面上考虑蒸汽的凝结。对于自由面的ＶＯＦ算法用了ＶＯＦ算法，取得了令人满意的结果，不仅形象地描绘了空泡的形成和溃灭的过程，而且得到了与实验相符的空泡溃灭高压和弥合速度，因此可为管道设计提供理论基础。     

平均不等式有趣应用几例

介绍了平均不等式在数学证明中的几例有趣应用。     

JDZ-1型固态存储雨量器降水量误差成因分析

对JDZ-1型固态存储雨量器与虹吸自记雨量计平行观测资料进行了系统分析,分析了两者存在误差的影响因素。对JDZ-1型固态存储雨量器在北方地区使用过程中存在的问题提出了解决方法,以保证和提高JDZ-1型固态存储雨量器资料质量。     

温度,压力对漂移室气体增益的影响

研究了温度及气体压力对漂移室（工作于正比区）气体放大倍数的影响，温度和气体压力的变化范围分别是５￣４０℃及９０￣１０５ｋＰａ。用实验数据拟合得到了函数关系并测量了几种饱和度下函数中的参数值。