餐饮废油生物柴油低温流动性的改进研究

使用气-质联用仪测定餐饮废油生物柴油(WCME)和-10号柴油(-10PD)的组成,使用冷滤点试验器和运动黏度试验器测定WCME的低温流动性,同时使用调合、添加低温流动性改进剂的方法改进WCME的低温流动性。实验结果表明,WCME主要由饱和脂肪酸甲酯和不饱和脂肪酸甲酯组成,质量分数分别为27.63%和71.81%;WCME冷滤点为0℃,运动黏度(40℃)为4.41mm2/s;WCME与-10PD调合后,冷滤点降低,其中B20的冷滤点最低,为-13℃,运动黏度随着WCME的体积分数的减少,逐渐接近-10PD的运动黏度。通过添加低温流动性改进剂,WCME,B10,B20的冷滤点分别从0,-8,-13℃降至-4,-26,-25℃。     

Enhance cycling performance of LiMn2O4 cathode by Sr2+ and Cr3+ doping

Spinel LiSr_0·1Cr_0·1Mn_1·8O₄ was synthesised by high temperature solid state method in order to enhance the electrochemical performance. The LiSr_0·1Cr_0·1Mn_1·8O₄ (LSCMO) materials were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical tests. The XRD and SEM studies confirm that LSCMO had spinel crystal structure with a space group of Fd3m, and the particle of LSCMO shows irregular shape. The cyclic voltammetry data illustrated that the heavy current charge–discharge performance of LMO was improved by Sr²⁺ and Cr³⁺ doping. The galvanostatic charge–discharge of LSCMO cathode materials was measured at 1, 5, 10 and 20 C. The results indicated that LSCMO improved the capacity retention.     

Ni-Foam Structured Ni-Phyllosilicate Ensemble as an Efficient Monolithic Catalyst for CO2 Methanation

This work proposed a new path to synthesize Ni-phyllosilicate through the reaction of nickel hydroxide and silica sol on the surface of Ni-foam to form the monolithic Ni-phyllosilicate/Ni-foam catalyst. Ni-phyllosilicate could reprint the morphology of nickel hydroxid and firmly anchor on the framework of Ni-foam, which obtained fine Ni particles of 2.8 nm after reduction in H₂ at 650 °C, resulting in high catalytic activity for CO₂ methanation. In addition, the Ni-phyllosilicate/Ni-foam catalyst showed high long-term stability in a 100 h-lifetime test owing to the combined effects of surface confinement of Ni-phyllosilicate, firm anchoring between Ni-phyllosilicate and Ni-foam, as well as the high heat transfer property of Ni-foam.

Graphical Abstract

     

基于Web的3D模型浏览与交互系统的研究与实现

设计了基于Web的3D模型浏览与交互系统，主要采用基于WebGL的第三方库Three.js来实现。该系统的建立主要包括场景的构建、场景的交互控制和模型的云存储。模型是场景构建的前提，用户可从外部导入所需模型或利用系统自带的简单模型进行模型的构建。场景交互技术主要包括模型的平移、旋转、缩放、拾取、剖切、3D动画模型的播放以及信息的显示等。模型的云存储是指用户可以通过登录账户将3D模型存储到服务器，日后需要时直接从服务器中加载即可。     

Decorative near-infrared transmission filters featuring high-efficiency and angular-insensitivity employing 1D photonic crystals

We present a new scheme for visibly-opaque but near-infrared-transmitting filters involving 7 layers based on one-dimensional ternary photonic crystals, with capabilities in reaching nearly 100% transmission efficiency in the near-infrared region. Different decorative reflection colors can be created by adding additional three layers while maintaining the near-infrared transmission performance. In addition, our proposed structural colors show great angular insensitivity up to ±60° for both transverse electric and transverse magnetic polarizations, which are highly desired in various fields. The facile strategy described here involves a simple deposition method for the fabrication, thereby having great potential in diverse applications such as image sensors, anti-counterfeit tag, and optical measurement systems.

     

裂缝性孔隙介质频变AVAZ反演方法研究进展

由于尺度的限制,利用地震方法进行裂缝参数定量表征一直是地球科学的难题。基于裂缝性孔隙介质动态等效理论的频变AVAZ反演方法给出了研究思路。首先介绍了裂缝性孔隙介质的等效介质理论研究进展,分析比较了各种裂缝性储层岩石静态等效介质模型和动态等效介质模型;然后给出了基于Chapman模型的裂缝参数和渗透率定量表征的正问题数学模型以及反演问题求解的方法和策略,以及基于模型数据的数值计算结果;最后讨论了频变AVAZ反演方法目前存在的问题和进一步研究方向。