The pyrolysis of a Wyoming coal in different nonreactive atmospheres

This study investigated how differing nonreactive atmospheres affected the properties of chars produced by coal pyrolysis. Samples of a Wyoming subbituminous coal were first heated at 586°C in helium for 6 hr. They were then heated for another 6 hr at 300°C higher in helium, argon or nitrogen. Weight losses in the chars during the second step were apparently unaffected by the choice of inert environment. Surface characteristics, pore structures, and reactivities of the resulting chars were, however, significantly different as shown by the results of scanning electron microscopy, nitrogen adsorption, carbon dioxide adsorption, and reactivity of the chars in carbon dioxide. Smoothness of the surface, adsorption capacities, N₂ and CO₂ surface areas, and reactivity during gasification all decreased in the direction (in order of inert atmospheres employed) He >Ar >N₂. In addition, there were strong indications that trace contaminants in the inert gases could alter the characteristics of the resulting char markedly.     

SEMI-ACTIVE CONTROL OF VEHICLE SUSPENSION WITH MAGNETO- RHEOLOGICAL DAMPERS: PART Ⅰ-CONTROLLER SYNTHESIS AND EVALUATION

A modified skyhook-based semi-active controller is proposed for implementing an asymmetric control suspension design with symmetric magneto-rheological (MR) dampers. The controller is formulated in current form, which is modulated by integrating a continuous modulation and an asymmetric damping force generation algorithms, so as to effectively minimize switching and hysteretic effects from the MR-damper. The proposed controller is implemented with a quarter-vehicle MR-suspension model, and its relative response characteristics are thus evaluated in terms of defined performance measures under varying amplitude harmonic, rounded pulse and random excitations. The sensitivity of the semi-active suspension performance to variations in controller parameters is thoroughly evaluated. The results illustrate that the proposed skyhook-based asymmetric semi-active MR-suspension controller has superior robustness on the system parameter variations, and can achieve desirable multi-objective suspension performance.     

Formulae for determining heterodyne system spurious frequencies that coincide with desired output frequency

In this paper, formulae to determine the lowest order and other higher order spurious frequencies that coincide with desired output signal frequencies of mixers have been derived. The proposed formulae give general expressions that are suitable for any order of heterodyne mixing. The formulae have been verified using a suitable example and compared with the simulation results obtained through the radio frequency simulation software of Advanced Design System. The formulae directly reveal the order of the troublesome spurious frequencies that the designers would encounter in heterodyne systems. In comparison with these direct formulae, the results of existing spurious analysis software are based on the maximum order of simulation carried out. Based on these simulations, the coinciding spurious components have to be manually sorted out. Proposed formulae are quick tools used by the microwave system and circuit designers for choosing and finalizing heterodyne frequencies in their designs without the need for any simulations.     

Enzymatic membrane reactors: the determining factors in two separate phase operations

A two separate phase‐enzymatic membrane reactor is an attractive process since it has a large interfacial area and exchange surfaces, simultaneous reaction and separation and other benefits. Many factors influence its successful operation, and these include characteristics of the enzyme, membrane, circulating fluids and reactor operations. Although the operating conditions are the main factor, other factors must be considered before, during or after its application. At the initial stage of reactor development, the solubility of substrates and products, type of operation, membrane material and size, enzyme preparation and loading procedure, and cleanliness of the recirculated fluids should be specified. The immobilization site, reactor arrangement, dissolved or no‐solvent operation, classic or emulsion operation and immobilized or suspended enzyme(s) are determined later. Some factors still need further studies. Utilization of the technology is described for use from multigram‐ to plant‐scale capacity to process racemic and achiral compounds. The racemates were resolved primarily by kinetic resolution, but dynamic kinetic resolution has been exploited. The technology focused on hydrolytic reactions, but esterification processes were also exploited. Copyright © 2011 Society of Chemical Industry     

Analysis of a Localized Fire in a 3-D Tunnel Using a Hybrid Solver: Lattice Boltzmann Method,Finite-Volume Method,and Fully Explicit Upwind Scheme

A localized fire in a 3-D tunnel is analyzed by solving a combined-mode natural-convection and radiation problem. Nonlocal thermal equilibrium between air and smoke is considered. Separate energy equations are used for the two species. The density and temperature fields required for the solution of the energy equation are computed using the lattice Boltzmann method. The finite-volume method is used to compute radiative information. The energy equations are solved using the fully explicit upwind scheme. The Boussinesq approximation is used to account for the buoyancy effect. Effects of the scattering albedo, the convection-radiation parameter, and the wall emissivities on temperature profiles in the tunnel have been studied.     

TRANSIENT CONDUCTION AND RADIATION HEAT TRANSFER WITH HEAT GENERATION IN A PARTICIPATING MEDIUM USING THE COLLAPSED DIMENSION METHOD

In order to study the mechanisms of heat and mass transfer at the gas–liquid interface, flows inside and around a rising inert bubble are considered and calculated using the numerical algorithm developed in a companion article. Studies of heat and mass transfer are carried out while special attention is paid to the effects of wake vortices. Recoveries of the Sherwood and Nusselt numbers are observed in the wake zone behind bubbles, and a physical explanation is proposed.     

The constitutive behavior of refractory metals as a function of strain rate

The constitutive response and deformation mechanisms in refractory metals with a hexagonal close packed (hcp) crystal structure are reviewed. The research focuses on the high-strain-rate stress-strain response under uniaxial compressive loading and the associated microstructural deformation mechanisms. Some aspects relating to dynamic failure such as adiabatic shear banding in refractory metals and subsequent failure processes are also discussed.     

Red emitting MTiO3 (M = Ca or Sr) phosphors doped with Eu3+ or Pr3+ with some cations as co-dopants

Ca (or Sr)TiO₃:Eu³⁺, M (Li⁺ or Na⁺ or K⁺) and CaTiO₃:Pr³⁺, M (Li⁺ or Na⁺ or Ag⁺ or K⁺ or Gd³⁺ or La³⁺) powders were prepared by combustion synthesis method and the samples were further heated to ～1000 °C to improve the crystallinity. The structure and morphology of materials were examined by X-ray diffraction (XRD) and a scanning electron microscopy (SEM). The morphologies of SrTiO₃:Eu³⁺, CaTiO₃:Eu³⁺ or CaTiO₃:Pr³⁺ powders co-doped with other metal ions were very similar. Small and coagulated particles of nearly cubical shapes with small size distribution having smooth and regular surface were formed. Photo-luminescence spectra of CaTiO₃:Pr³⁺ and co-doped either with Li⁺, Na⁺, K⁺, Ag⁺, La³⁺ or Gd³⁺ ions showed red emissions at 613 nm due to the ¹D₂ → ³H₄ transition of Pr³⁺. The variation of intensity of emission peak with different co-doping follows the order: K⁺ > Ag⁺ > Na⁺ > Li⁺ > La³⁺ > Gd³⁺. The characteristic emissions of CaTiO₃:Eu³⁺ lattices had strong emission at 614 and 620 nm for ⁵D₀ → ⁷F₂ with other weak transitions observed at 580, 592, 654, 705 nm for ⁵D₀ → ⁷F_n transitions where n = 0, 1, 3, 4 respectively in all host lattices. Photoluminescence intensity in SrTiO₃:Eu³⁺ is more than CaTiO₃:Eu³⁺ lattices. A remarkable increase of photoluminescence intensity (in ⁵D₀ → ⁷F₂ transition) was observed if co-doped with Li⁺ ions in CaTiO₃:Eu³⁺ and SrTiO3:Eu³⁺.