Efficient Catalyst for Both Suzuki and Heck Cross‐Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry‐ Constrained Iminopyridylpalladium Chlorides

A series of geometry‐constrained iminopyridyl‐palladium chlorides were synthesized and characterized. These phosphine‐free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross‐coupling reactions, achieving turnover numbers as high as 10⁶ towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities.

     

Catalyst-Controlled Selectivity in Oxidation of Olefins: Highly Facile Success to Functionalized Aldehydes and Ketones

Catalysis Letters - The attractive challenge in green chemistry is exploring novel heterogeneous catalyst system for catalyst-controlled product selectivity for oxidation of olefins. Hence, we...     

Novel Fast-switching LIGBT with Single-Step Low-k Dielectric Layer and Assistant-Depletion Trench

Silicon - A novel low-loss and good-robustness silicon-on-insulator lateral insulated gate bipolar transistor (LIGBT) is proposed and investigated by simulation for the first time. The device is...     

Photovoltaic Study of Photoelectrochemical Biofuel Cells Sensitized by Porphyrin Derivatives with Different Substituents

Two porphyrin derivatives with different substituents were investigated as dyes for the titanium dioxide (TiO₂) film electrode to construct new two-compartment photoelectrochemical biofuel cells (PEBFCs). The two porphyrin derivatives were tetrakis(4-carboxyphenyl)porphyrin (TCPP) and meso-tetra(p-hydroxyphenyl)porphine (THPP). To determine how cell performance was affected by the dye with different substituents, we analyzed the photochemical and photoelectrochemical properties of the two dyes by physical characterization and photoelectrochemical experiments. The UV–Vis absorption spectra and X-ray photoelectron spectra indicated that the interactions between the dye and TiO₂ decreased in the order of TCPP > THPP, which was also in accord with the results of Fourier transform infrared. In addition, TCPP and THPP were calculated using the density functional theory and the time-dependent density functional theory, and the calculation result exhibited that the radiative lifetime decreased in the order of TCPP > THPP. Compared with THPP, TCPP with longer excited-state was expected to enhance the performance of a PEBFC. We measured and compared the incident photon-to-collected electron conversion efficiency and the light-to-electrical conversion efficiency (η) of the porphyrin-sensitized photoelectrochemical biofuel cell. The photovoltaic characteristics showed the TCPP was more effective compared to the THPP, which obviously showed that the experimental results were consistent with theoretical expectation. These results revealed that the kind of the substituent for the porphyrin influenced the photovoltaic properties of the PEBFC.     

基于包容性的城市慢行交通综合导视交互设计研究

针对城市慢行交通系统的导视进行了研究,提出了基于包容性理念的综合导视系统的设计概念,设计过程包括了原型测试、行人动线研究、互动导视系统的设计等内容。     

基于BIM理念的绿色建筑新思维

通过BIM精细化设计, 使用统一的数据源, 保持整个设计过程数据的可持续性, 对设计各阶段进行优化, 使设计作品达到绿色建筑设计的要求。此外, 使用数字模拟软件Ecotect、Fluent、Abaqus、Pathfinder等对光照、风环境、荷载、人员疏散进行模拟分析, 并通过模拟结果来优化建筑开窗、建筑遮阳、建筑抗震、建筑疏散以及可再生能源的利用, 提升设计质量, 保证设计的安全性、节能性、环保性和可持续性, 使图书馆具有更适合学习和生活的室内外环境, 达到“人-建筑-自然”三者和谐共生。     

A simple analytical model to predict liquid unloading in the horizontal gas well

An accurate prediction of the critical gas velocity for the liquid loading is of great importance for operators to select the tubing diameter for the newly dril...     

Blockchain and MEC-Assisted Reliable Billing Data Transmission over Electric Vehicular Network:An Actor–Critic RL Approach

Recently, electric vehicles (EVs) have been widely used under the call of green travel and environ-mental protection, and diverse requirements for charg-ing are...     

新型二氧化硫传感器的制备

制成一种新型无参比电极、由NASICON和YSZ2种固体电解质及Na₂SO₄辅助电极构成的二氧化硫传感器。实验结果表明,该传感器对二氧化硫产生Nernst响应。由于这种传感器采用了平面结构,参比电极和工作电极处于相同气氛中,消除了氧气的影响和密封问题,这种结构有利于传感器的微型化和多组元复合传感。     

板形板厚综合系统的解耦神经网络预测控制方法

给出了板形板厚综合控制模型,提出了基于TH神经网络的动态矩阵设计方法并分析了其收敛特性.使用不变性原理对板形板厚综系统进行了解耦设计,并对板形板厚解耦神经网络预测控制系统,进行了仿真研究.结果表明神经网络可在儿百ns的时间内达到稳定状态,不仅满足了轧钢过程的快速性要求,而且控制精度也得到了提高.