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51.
Muhammad S. Akram Muhammad R. Usman 《Theoretical Foundations of Chemical Engineering》2021,55(3):545-561
Theoretical Foundations of Chemical Engineering - Increase in CO2 emissions from fossil fuels has threatened the future security of human race. The addition of a renewable and environment friendly... 相似文献
52.
Usman Abdulfatai Adamu Uzairu Sani Uba Gideon Adamu Shallangwa 《Egyptian Journal of Petroleum》2019,28(2):241-245
Quantitative structure-properties relationship (QSPR) method was used to design some novel antioxidant lubricant additives, while molecular dynamics simulations were used to calculate their dynamic binding energies on steel and to hydrogen-containing DLC (a-C: H) crystal surfaces. 29 synthesized antioxidant lubricant additives were collected from literature and geometrically optimized by Spartan’14 version 1.1.2 software while Genetic Function Algorithm (GFA) method of the material studio version 8.0 software was used to build the predictive QSPR model. Four novel antioxidant lubricant additives were successfully designed out of which E)-3-(4-((3-amino-4-methylphenyl)diazenyl)-5-hydroxy-4H-pyrazol-3-yl)-2-argio-6,7-difluoroquinazolin-4(3H)-one with excellent property of 3.531295 (KOH/g) was found to be better than the one reported by other researchers. The dynamic binding energy results revealed that one of the designed additives was excellently bound to steel (?1120.11 kcal/mol) and to hydrogen-containing DLC (a-C: H) crystals surface (7814.156 kcal/mol) surfaces than its co-additives. This investigation shows that the entire studied antioxidant lubricant additive was found to be better bound to the steel surface than hydrogen-containing DLC (a-C: H) crystals surface. This study will help in synthesizing novel anti-oxidant lubricant additives with better additive properties that will slow the tendency of oil to oxidize and will not possess a threat to the environment as the structures do not contain zinc and phosphorus that could limit the operation of the catalytic converter in the exhaust pipe. 相似文献
53.
54.
M. Imran Saira Riaz Ifra Sanaullah Usman Khan Anjum N. Sabri Shahzad Naseem 《Ceramics International》2019,45(8):10106-10113
Composites play important role in dental filling by controlling shrinkage along with correction in teeth's shape and position. Rehabilitation of severely worn dentition can be achieved using mechanically strong composites. This study aims to synthesize zirconia-based composites to be used as dental fillers. Effect of microwave powers (100–900?W) along with Fe3O4 doping are studied on the structural, mechanical and magnetic properties of stabilized zirconia. SEM and TEM reveal formation of spherical nanoparticles with diameter of ~30?nm. XRD results shows phase pure tetragonal zirconia (t-ZrO2) at microwave power of 500?W without any post heat treatment. Crystallite size calculated from XRD data (~23?nm) matches well with the previously reported value for stabilization of t-ZrO2. Microwave energy dissipation results in stresses causing volume shrinkage leading to monoclinic to tetragonal phase transformation with higher X-ray density and hardness of ~1347HV. VSM results show ferromagnetic response with low coercivity (600Oe) value and saturation magnetization (~2emu/g). It is worth mentioning here that this is one of its kind study reporting synthesis of room temperature stabilized Fe3O4 doped zirconia composites at microwave power of 500?W. Antibacterial studies reveal inhibition zone of ~32?mm against bacillus bacteria suggesting their potential use as dental filler. 相似文献
55.
Azeem Irshad Shehzad Ashraf Chaudhry Muhammad Shafiq Muhammad Usman Muhammad Asif Anwar Ghani 《International Journal of Communication Systems》2019,32(14)
The mobile cloud computing (MCC) has enriched the quality of services that the clients access from remote cloud‐based servers. The growth in the number of wireless users for MCC has further augmented the requirement for a robust and efficient authenticated key agreement mechanism. Formerly, the users would access cloud services from various cloud‐based service providers and authenticate one another only after communicating with the trusted third party (TTP). This requirement for the clients to access the TTP during each mutual authentication session, in earlier schemes, contributes to the redundant latency overheads for the protocol. Recently, Tsai et al have presented a bilinear pairing based multi‐server authentication (MSA) protocol, to bypass the TTP, at least during mutual authentication. The scheme construction works fine, as far as the elimination of TTP involvement for authentication has been concerned. However, Tsai et al scheme has been found vulnerable to server spoofing attack and desynchronization attack, and lacks smart card‐based user verification, which renders the protocol inapt for practical implementation in different access networks. Hence, we have proposed an improved model designed with bilinear pairing operations, countering the identified threats as posed to Tsai scheme. Additionally, the proposed scheme is backed up by performance evaluation and formal security analysis. 相似文献
56.
Jan Syed Rooh Ullah Jan Mian Ahmad Khan Rahim Ullah Hakeem Alam Muhammad Usman Muhammad 《Mobile Networks and Applications》2019,24(4):1295-1305
Mobile Networks and Applications - In Wireless Sensor Networks (WSNs), a dense deployment of sensor nodes produce data that contain intra-temporal and inter-spatial correlation. To reduce the... 相似文献
57.
Kunjie Yuan Jinming Shi Waseem Aftab Mulin Qin Ali Usman Fang Zhou Yang Lv Shan Gao Ruqiang Zou 《Advanced functional materials》2020,30(8)
Thermal energy storage technologies based on phase‐change materials (PCMs) have received tremendous attention in recent years. These materials are capable of reversibly storing large amounts of thermal energy during the isothermal phase transition and offer enormous potential in the development of state‐of‐the‐art renewable energy infrastructure. Thermal conductivity plays a vital role in regulating the thermal charging and discharging rate of PCMs and improving the heat‐utilization efficiency. The strategies for tuning the thermal conductivity of PCMs and their potential energy applications, such as thermal energy harvesting and storage, thermal management of batteries, thermal diodes, and other forms of energy utilization, are summarized systematically. Furthermore, a research perspective is given to highlight emerging research directions of engineering advanced functional PCMs for energy applications. 相似文献
58.
Reservoirs play a strategic role in the rapid monetary growth of the world by providing numerous benefits. However, the reduction in appropriate sites along with environmental and social apprehensions has resulted in curtailment of new reservoirs around the world in twenty-first century. There is a potential of benefits available from existing reservoirs which can be best capitalized through their optimized operation. Reservoirs Operation Optimization considering Sediment Evacuation (RESOOSE), recently developed model which combines multiple reservoirs operation and sediment evacuation with Genetic Algorithm based optimization module, has been used in the study. The objective of the study was to optimize the irrigation deficit through cascade reservoirs with consideration to hydropower, sediment evacuation and flood damages reduction benefits. The RESOOSE model was applied to optimize the irrigation deficits of Tarbela and Diamer Basha Reservoirs in Pakistan using developed objective function. The article computed and compared the benefits of optimized and existing rule curves. The hydropower benefits of 36.92 Billion Kw, sediment evacuation benefits of 21.534 Million m3 and flood damages of 616.19 Million US$ due to existing rule curves were considered as minimum benefits for achieving the optimized rule curves to minimize irrigation deficits. The developed optimized rule curves reduced the irrigation shortages of case study reservoirs from 6.9 to 5.8 Billion m3 (16% enhancement) annually as compared to existing rule curves. The optimized rule curves minimized the irrigation deficits by maintaining the existing benefits and without lowering the minimum operating levels of case study reservoirs. The study suggests change in existing rule curves of Tarbela and Diamer Basha Reservoirs due to less irrigation shortages. The RESOOSE model can be applied to other cascade reservoirs for optimizing the rule curves. 相似文献
59.
Jock Asanja Alexander Abdulsalam Surajudeen El-Nafaty Usman Aliyu Aroke Umar Omeiza 《Particulate Science and Technology》2018,36(5):569-577
Multicomponent adsorption of lead(II), cadmium(II) and manganese(II) by Nigerian Dijah-Monkin bentonite clay was investigated. The clay samples were characterized for elemental composition, cation exchange capacity and textural properties. Natural bentonite exhibits cation exchange capacity of 47.7?meq/100?g and specific surface area of 23.5?m2/g. Manganese(II) displays higher values of rate constant than lead(II) in multimetals adsorption. However, lead(II) is favorably adsorbed onto bentonite adsorbents at different concentrations studied. The multimetals adsorption onto bentonite clay samples is site selective and site specific. The pseudo-second-order kinetics model gave a better fit to the adsorption data, suggesting ion exchange and/or complex formation. The adsorption mechanism could be described by intraparticle diffusion with some restriction of metals diffusion due to film or boundary layer. Also, the multicomponent adsorption is endothermic and becomes more spontaneous as temperature increased from 303 to 338?K. Nigerian bentonite clay in its natural form is a promising adsorbent for multimetals removal in aqueous solution. 相似文献
60.
Yi Zhang Tariq Usman Xiang-Ming Tao Ming-Qiu Tan 《Journal of Superconductivity and Novel Magnetism》2018,31(6):1707-1714
In this paper, we performed a density functional theory calculation study on the newly discovered superconductor Re6Hf containing anti-symmetric spin-orbit coupling (ASOC) properties. The calculated densities of electronic states demonstrate that the d–d interaction of Re6Hf is much stronger than that in Re6Zr. A fully relativistic DFT study shows a special performance of densities of states for the spin-up and spin-down electrons. Band structure calculations indicate that the lifting at several high symmetric k points and plenty of splits in band structures yield significant topological transitions in the Fermi surfaces of Re6Hf. The energy splitting of bands caused by ASOC are estimated to be 34 and 44 meV, respectively. The de Hass-van Alphen effect simulation is demonstrated and analyzed. 相似文献