大型压力容器现场热处理技术

以大连石化350万t/a催化裂化装置再生器为例,研究开发大型炼油化工设备现场新型热处理工艺。通过设置必要的热气流导向装置,采用微正压内燃工艺,配备新型大功率燃油喷嘴、用DCS集散控制系统调节油风比例和烟囱热量排放张合度,对超厚壁板适当增加电加热辅助热处理,解决了大容积、变截面、不等壁厚、超重设备施工现场热处理温度调整难度大、不均衡等技术问题。实践证明,应用该技术进行热处理,具有工期短、效果好、经济效益明显等特点。     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

我国电力工业和发电技术未来发展趋势

传统工业化走的是通过高消耗追求经济数量增长和先污染后治理的道路。介绍在传统工业化面临严重危机的背景下,可持续发展战略和新型工业化的兴起和特点,充分体现了未来发展的要求。在分析、总结世界能源发展的经验和规律的同时,对未来世界能源发展进行了宏观预测。以科学发展观为指导,采用未来学的方法,结合我国国情、发展现状和近中期发展目标,对本世纪特别是21世纪前20a我国电力工业和发电技术趋势进行了初步探讨,对国家能源安全等问题进行讨论。     

In Google We Trust: Users' Decisions on Rank, Position, and Relevance

An eye tracking experiment revealed that college student users have substantial trust in Google's ability to rank results by their true relevance to the query. When the participants selected a link to follow from Google's result pages, their decisions were strongly biased towards links higher in position even if the abstracts themselves were less relevant. While the participants reacted to artificially reduced retrieval quality by greater scrutiny, they failed to achieve the same success rate. This demonstrated trust in Google has implications for the search engine's tremendous potential influence on culture, society, and user traffic on the Web.     

Effects of three crosslinkers on colored pH‐responsive core–shell latexes

Environmentally responsive hydrogels have become attractive research subjects for many applications. In this work, a series of pH‐sensitive and color‐changing nanoparticles (nanogels) with core–shell structures were synthesized. The cores were blue latex particles synthesized by a miniemulsion technique with styrene and methacrylic acid as monomers and Neozapon Blue 807 as a dye. The shell was a pH‐sensitive polymer that was precipitation‐polymerized onto the core from 2‐(diethylamino) ethyl methacrylate with N,N′‐methylenebisacrylamide, poly(propylene glycol) diacrylate, and divinylbenzene as crosslinking agents. In the resultant latexes, the color was observed to change from deep blue to pale blue as the pH of the system was changed from a high of 10 to a low of 3. The synthesized latexes and particles (gels) were then characterized with an ultraviolet–visible spectrometer, dynamic light scattering, Fourier transform infrared, and nuclear magnetic resonance. Atomic force microscopy was also used to investigate the different morphologies of the particles after the synthesized latexes were dried at different pH values. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Preparation and characterization of metal-complex imprinted PVDF hollow fiber membranes

Using nickel-2,2′-dipyridyl complex as a template, N-vinyl-2-pyrrolidone as the metal coordination functional monomer, and ethylene glycol dimethacrylate as the crosslinker, polyvinylidene fluoride (PVDF) hollow fiber ultrafiltration membrane as the supported membrane, metal complex imprinted polymeric membranes were prepared. The association constant of template-monomer interaction in the prepolymerization solution was estimated to be 4.38 × 10⁴ (L/mol)² by spectrophotometric titration analysis. The attenuated total reflection Fourier transform infrared spectroscopy and scanning electron micrograph characterization indicated that the surface of the support PVDF membrane was completely coated by the imprinted polymer layer after modification. The imprinted membranes exhibited the selective permeability for the template in certain nickel acetate solution. The molecularly imprinted membranes gave higher permeation separation factors at about pH 6, whereas increasing pressure would lower the separation ability. The effects of ion concentration, cations and counterions, ligand selectivity, pH, and trans-membrane pressure were investigated and the permeation performances of the imprinted membranes could be regarded as facilitated transport mechanism. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

国产新型铜带冷轧机

铜带冷轧机是铜带材生产的关键设备。20多年来，通过铜带冷轧机研制开发领域的广大科技人员的共同努力，国产铜带冷轧机获得了长足的发展。本文重点介绍几种主要机型，并分析其优缺点，同时指出今后国产铜带冷轧机的发展方向。     

原料磨同步机励磁装置的改造

分析原料磨同步机所使用的KGLF型励磁装置在实际运行中存在的问题，介绍采用LZK-3型微机励磁装置的改造实践。     

In-Situ Wet Chemical Composition of Multicomponent Precursors to Blue Emitting Sr2CeO4 Phosphors

Hybrid precursors were assembled with cerium coordination polymers, polyethyl glycohol (PEG), SrCO3 and other functional components using a modified in-situ chemical polymeric gel technology. The hybrid precursors were calcinated to achieve the Sr2CeO4 phosphors, whose particle sizes were in the range of micrometer by XRD and SEM. The photoluminescence spectra indicate that the phosphors present a strong blue emission.