A porous mixed-valent iron MOF exhibiting the acs net: Synthesis, characterization and sorption behavior of Fe3O(F4BDC)3(H2O)3·(DMF)3.5

A new mixed-valent iron MOF, formulated as Fe₃O(F₄BDC)₃(H₂O)₃·(DMF)_3.5 (1), has been synthesized by using a perfluorinated linear dicarboxylate to link trigonal prismatic Fe₃(μ³-O)(O₂C–)₆ clusters. The structure refinement based on single crystal X-ray diffraction data collected from 1 reveals the material exhibits the acs topology with large channels along the crystallographic c-axis. Due to the presence of fluorine atoms the organic link, 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate (F₄BDC), has a 63° torsion angle between the carboxylate and aromatic planes, resulting in larger channels compared to those in the isoreticular material MOF-235. While few iron-based MOFs have demonstrated porosity, nitrogen and hydrogen sorption experiments carried out at 77 K proved the porosity of outgassed 1, which has a Langmuir surface are of 635 m²/g and a gravimetric capacity of 0.9 wt% of hydrogen at 1 bar.     

有机硅含量对改性酚醛环氧树脂涂料性能的影响

利用自制的有机硅改性酚醛环氧树脂配制耐热防腐涂料，对其性能进行试验。不同有机硅树脂百分含量影响改性酚醛环氧树脂清漆的综合性能，并确定了有机硅的含量在40％-60％时改性涂料具有较好的综合性能；探讨了不同温度下涂膜附着力的变化及在不同酸碱溶液中不同有机硅含量的改性涂料的耐蚀性。     

IT capability and organizational performance: the roles of business process agility and environmental factors

The business value of information technology (IT) has been one of the top concerns of both practitioners and scholars for decades. Numerous studies have documented the positive effects of IT capability on organizational performance but our knowledge of the processes through which such gains are achieved remains limited due to a lack of focus on the business environment. Such a linkage therefore remains the subject of debate in the information systems literature. In this study, we fill this gap by investigating the mediating role of business process agility and the moderating roles of environmental factors. On the basis of matched survey data obtained from 214 IT and business executives from manufacturing firms in China, our analyses show that even though firm-wide IT capability presents the characteristics of rarity, appropriability, non-reproducibility, and non-substitutability, its impact on organizational performance is fully mediated by business process agility. Our results also show that the impact of the environment is multifaceted and nuanced. In particular, environmental hostility weakens the effect of IT capability on business process agility, while environmental complexity strengthens it. The theoretical and practical implications of this study, and its limitations, are also discussed.     

乙二醇与马来酸酐酯化反应的研究

优化了乙二醇与马来酸酐的酯化反应,得出了马来酸酐与乙二醇的最佳摩尔比为2.1：1,反应时间为1h,催化剂质量分数为1%,同时反应以丙酮为溶剂.     

基于奇偶树型交互学习机与遗传算法的密文优化系统

为使图像加密系统具备优化功能,并解决当前遗传算法无法实现全局最优、收敛速率慢等问题,提出奇偶树型交互学习机耦合全局离散遗传算法的密文优化系统。定义权值更新机制,耦合混沌映射,构造奇偶树型交互学习机及其互扰模型。将切断型轮盘赌择取机制引入均匀交叉算子中,以图像分块的相邻像素相关系数和密文信息熵为目标,根据权重理论设计加权适应度函数,提出一种全局离散遗传算法,最终形成"初始加密-密文优化"的加密结构。实验结果表明,与超混沌算法、离散遗传算法、元胞自动机相比,该系统的加密质量较好,并且具备全局优化功能,可优化所有迭代结果,使最终输出密文的信息熵最大,相关系数最小。     

级联No序列的三项式特性研究

利用有限域GF(2n)到其子域GF(2m)上的迹函数及其性质,研究一类非线性扩频序列的密码学性质,即级联No序列的三项式特性。给出级联No序列的三项生成多项式的形式,将级联No序列三项式特性的结论应用到二元No序列中,解决了二元No序列的三项式特性问题。分析结果表明,级联No序列不仅具有三项式对,而且具有正则三项式对。     

基于日志挖掘的移动应用用户访问模型建模技术研究

提出了一种基于监控日志挖掘的移动应用用户访问模型自动构造方法,该方法包括监控代码注入和界面访问模型构造两部分。首先,提出了一种监控代码自动注入方法,即通过对移动应用代码的静态分析,自动地在相应位置插入监控代码以支持在运行时动态地监控用户的访问行为。其次,提出了一种基于状态机的移动应用用户访问模型构造方法。访问模型中状态机的节点和节点间跳转上的附加属性描述了UI界面之间的跳转行为和界面内控件的使用情况。对移动应用进行的实验表明,这种基于监控日志挖掘的移动应用用户访问模型自动构造方法能够成功地自动注入移动应用的监控代码,并能够有效获得移动应用用户界面访问行为。     

基于自旋图和ICP算法的3D实体签名算法

针对已有的3D实体真实性认证方法中实体的标识不与实体自身绑定且难以验证的问题,提出了一种面向3D实体的签名算法。给出了3D实体签名算法的设计思想、签名产生算法以及签名验证算法。在粗配准和精匹配阶段分别通过自旋图(Spin Image)和ICP(Iterative Closest Point)算法对签名表面和待测表面进行匹配,从而提高了验证的准确率。对所设计的签名算法进行了实验仿真,所获得的迭代误差和匹配率表明该算法可以区分原始和伪造的签名表面,进而证明了算法的有效性。     

面向移动平台的新型身份认证方案设计

各种类型的移动平台如智能手机、平板电脑、嵌入式系统快速普及,并渗透到生活和工作的方方面面,但是移动平台在带给大家丰富多彩的应用和方便快捷的生活的同时,也带来了许多新的安全问题。身份认证和接入认证是保护移动平台的第一道屏障。结合多点触控技术、重力感应技术和图形密码,设计、开发了适用于移动平台的几种身份认证方案,包括绘制曲线认证方案、图像选择认证方案、多点指划认证方案和重力感应认证方案。所设计的方案较之单纯的口令式密码,设置口令和验证口令直观方便,通过简单的操作即可产生较大的密钥空间。经分析,所提方案操作方便,安全性较高。     

大力推进辽宁省石化工业结构优化升级

介绍了辽宁省石化工业中的结构性矛盾，提出了走新型工业化道路，推进石化产业结构优化升级的思路。