阳离子交换树脂催化合成十三碳二元酸二乙酯

以强酸性阳离子交换树脂为催化剂,十三碳二元酸与乙醇为原料合成十三碳二元酸二乙酯,考察了影响反应的因素。结果表明:醇酸摩尔比为4∶1,催化剂用量为酸质量的2%,在3分子筛脱水的情况下反应7 h,酯化率达98.4%,并且催化剂可重复使用3次。     

论高校网络视频在思想政治教育中的作用

校园网络视频是高校开展思想政治工作的重要阵地,也是一种新型有效传播社会主义先进文化的重要载体,它具有发挥宣传和舆论导向、教书育人、素质教育等独特作用.     

基于L1输出反馈自适应方法的火箭姿态控制

针对运载火箭刚—弹耦合动力学模型,开展了基于L1输出反馈自适应方法的火箭姿态控制器设计.考虑到L1控制器低通滤波器环节可能在一定程度上减少弹性影响,分析了火箭不同低频模态对控制系统的影响情况.由于低通滤波器带宽与系统带宽存在相互制约关系,当无法通过低通滤波器设计消除低阶弹性影响时,结合校正网络设计L1输出反馈控制器.仿真结果表明,上述设计思路能够应对火箭低阶弹性问题,所设计的控制器控制效果良好,且在弹性频率变化时系统依然具有良好的暂态和稳态性能.     

Finite-time Containment Control of Nonlinear Delayed Fractional Multi-agent Systems

This article deals with finite-time containment control (FTCC) of nonlinear delayed fractional multi-agent systems (FMASs). Addressing fractional Razumikhin approach, properties of fractional calculus and analytical techniques, a quadratic Lyapunov function is constructed to derive sufficient conditions on FTCC by adopting a discontinuous control protocol, the employed method may overcome well the troubles arising from time delays and fractional derivatives. Numerical simulations further clarify the reliability and validity of our theoretical conclusions.

     

高速公路施工区车辆强制换道耗时生存模型

为研究高速公路施工区车辆强制换道行为及其影响因素,采用生存分析中的半参数分析方法建立强制换道耗时的乘法风险率模型.通过无人机拍摄采集高速公路施工区的车辆换道耗时及其影响因素数据,最终确立换道耗时Cox比例风险模型,对换道耗时数据进行Cox回归建模分析.结果表明:近77%的换道车辆在10 s内完成换道;小型车和中型车经养护施工区的换道耗时未发现显著性差别;对于相同的换道耗时,平峰期的累积生存率明显低于高峰期和过渡时期,而高峰期的累积生存率最高.建立的强制换道耗时生存模型可有效的定量分析车型和交通时段对高速公路施工区车辆换道行为的影响,可为高速公路施工区交通管理控制及车辆换道行为建模及仿真奠定一定的理论基础.     

中国犯罪防治的主流之路

我国目前犯罪预防体制存在较大漏洞,应从劳改释放人员和非劳改释放人员中的特定主体进行着重预防工作.问题解决应从国家机关、社会以及家庭等方面着手.心理预防是我国目前以至未来犯罪防治的主流之路.     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

论我国高职院校如何破解毕业生就业结构性矛盾

高等职业教育作为我国高等教育的重要组成部分,在现阶段经济社会发展中发挥越来越重要的作用。通过分析高职院校自身教学特点,提出教学体系构建和教改内容应加强与劳动力市场需求相对接,探讨破解毕业生就业结构性矛盾的措施,力求为社会培养高素质的技术技能型毕业生。     

Influence of static pre-loading on the dynamic bending strength of concrete with particle element modeling

Experimental tests show that static pre-loading has a significant effect on the dynamic strength of concrete.Based on meso-scale particle element model,numerical simulations of dynamic bending tests with pre-loading are performed.Complete stress–strain relationships are then obtained.Significant increase in dynamic strength is found when the pre-loadings are imposed within the elastic limit of concrete.However,when the imposition of pre-loadings reaches the plastic or softening range,dynamic strengths may gradually decrease along with the increase in pre-loadings.The distribution of energy components and the failure modes are discussed to explain the mechanisms of the phenomena.     

微创业:大学生创业实践教育的思考

大学生创业实践是高校创业教育的一个难题。当前国内高校创业教育普遍存在实践教育环节薄弱、效果不显著等问题,本研究同步社会经济发展,尝试以微创业视角思考高校创业实践教育,通过梳理微创业的概念及应用,从契合大学生需求角度分析微创业具有的时代性、低门槛、大众化、创新性等特点。并根据高校实际情况,从完善微创业环境、开设微创业课程、建立微创业实践基地、提供微创业网络平台服务等方面提出推动高校大学生微创业的路径建议。