微机模拟处理pH络合滴定法研究——Ⅱ.终点确定方法和最佳实验条件模拟估计程序

本文利用简便的滴定过程模型,确立了微机模拟处理实验数据,方便、准确地求解络合滴定等当点的方法。设计了最佳实验条件模拟估计程序。该法测定Zn~(2+),Pb~(2+),Cu~(2+),Fe~(3+)结果的相对误差Δ<1％。pH=6-7时,测定Ca~(2+)的相对误差为-1.61％;σ<0.001mmol,(N=5)。     

预测控制算法的统一格式及其在电加热炉的应用

本文根据常用的两类预测控制算法推出一种新型预测控制算法。并将其应用于一双输入/双输出的力学持久机电加热炉的温度控制系统上,获得了满意的结果:控温精度为±1.5℃/300℃,且适用于非最小相位系统。     

利用增量矩阵辨识确定型ARMA模型的新算法

本文提出了一种无偏辨识确定型ARMA模型参数及阶次的新方法。和其他辨识算法不同的是在这里我们构造了关于系统开环阶跃响应的增量矩阵,并且通过分析该增量矩阵子矩阵的代数性质而得到了辨识系统阶次的一种简单方法。仿真的结果说明了本文理论的正确性。     

Efficiency improvement of near-ultraviolet InGaN LEDs using patterned sapphire substrates

The use of conventional and patterned sapphire substrates (PSSs) to fabricate InGaN-based near-ultraviolet (410 nm) light-emitting diodes (LEDs) was demonstrated. The PSS was prepared using a periodic hole pattern (diameter: 3 /spl mu/m; spacing: 3 /spl mu/m) on the (0001) sapphire with different etching depths. From transmission-electron-microscopy and etch-pit-density studies, the PSS with an optimum pattern depth (D/sub h/=1.5 /spl mu/m) was confirmed to be an efficient way to reduce the thread dislocations in the GaN microstructure. It was found that the output power increased from 8.6 to 10.4 mW, corresponding to about 29% increases in the external quantum efficiency. However, the internal quantum efficiency (@ 20 mA) was about 36% and 38% for the conventional and PSS LEDs, respectively. The achieved improvement of the output power is not only due to the improvement of the internal quantum efficiency upon decreasing the dislocation density, but also due to the enhancement of the extraction efficiency using the PSS. Finally, better long-time reliability of the PSS LED performance was observed.     

基于TMS320C6x实现多载波QPSK信号全数字化整体解调

提出并证明了一种群路FDMA/QPSK(频分多址/正交相移键控)信号全数字化整体解调的新方法,该方法根据信道构成特点和信号调制方式,将直接分路法和常规多相FFT(快速傅里叶变换)分离法相结合,构成了一种简化的等效多相FFT分路方法,再将输出的数字信号送到数字式解调器,实现了多载波信号的全数字化整体解调,其特点是软件和硬件结构简单、系统计算量小,且易于DSP实时实现,现已用该算法进行了32路FDMA/QPSK信号整体解调的计算机仿真实验,结果表明该方法是可行的.     

剂量率对聚四氟乙烯辐射裂解的影响

本文研究了在以电子加速器的电子射线为辐射源时,剂量率对PTFE辐射裂解的影响。在剂量相同的条件下,剂量率从1.44×10~4 rad/s增至5.75×10~4 rad/s,裂解效率提高3.3倍。剂量率和各断裂参数(单位剂量裂解度a_0,G(s)值等)均成线性关系。当裂解度一定时,剂量率与剂量成反变关系。     

冲击回波法检测隧洞混凝土衬砌厚度

冲击回波法是通过接收、分析在混凝土中传播的回波信号，判断结构混凝土厚度和内部质量的新型无损检测技术。室内试验和工程应用研究表明，该方法为隧洞混凝土衬砌厚度检测提供了一个有效的测试手段。     

Synthesis of Nearly Monodisperse Iron Oxide and Oxyhydroxide Nanocrystals

Uniform magnetite, hematite, and goethite nanocrystals were prepared through an attractive method based on an oleic acid/alcohol/water system. By adjusting the synthetic parameters (base concentration, alcohol content, categories of alcohols, etc.), the controlled synthesis of uniform magnetite, hematite, and goethite nanocrystals can be easily achieved. Detailed investigations on the effect of the experimental parameters on the morphology of the final products and the phase transitions among the magnetite, hematite, and goethite phases were carried out. Finally, a method of doping other metal ions into magnetite was developed and the magnetic properties of magnetite doped with different metal elements were studied.