Effects of Na, Cu, Ni and Co Modifications on the Activity and Characteristics of Rh/Al2O3 Catalysts for NO Reduction

This study used different metals to modify Rh/Al₂O₃ catalysts for NO reduction in a simulated waste incineration flue gas containing 6% O₂. The characteristics of the modified catalysts were analyzed using BET, TEM and XRD. The results of the experiment reveal that Na addition can significantly affect the properties of Rh/Al₂O₃ catalysts on the BET surface area and Rh metal dispersion. Furthermore, Na addition was found to significantly enhance the NO conversion of Rh/Al₂O₃ at 250–350 °C. On the contrary, Cu, Ni, and Co addition was found to have slight suppression effects.     

Asymmetric Regulation System Fit for Chinese Telecom Market

After the new round of restructuring of Chinese telecom sector,it's pressing to formulate and implement asymmetric regulation policies so as to shape an effectively competitive market structure in a relatively short term.This paper reviewed the asymmetric regulation policies and practices carried out in foreign telecom market,and then according to the specific situations of Chinese telecom market,proposed the principles and corresponding policies for establishing an asymmetric regulation system fit for Chin...     

Onset of buoyancy-driven convection in melting from below

When a horizontal homogeneous solid is melted from below, convection can be induced in a thermally unstable melt layer. In this study the onset of buoyancy-driven convection during time-dependent melting is investigated by using similarly transformed disturbance equations. The critical Rayleigh numbers based on the melt-layer thickness are found numerically for various conditions. For small superheats, the present predictions approach the well known results of classical Rayleigh-Bénard problems, that is, critical Rayleigh numbers are located between 1,296 and 1,708, regardless of the Prandtl number. However, for high superheats the critical Rayleigh number increases with an increase in phase change rate but with decrease in Prandtl number.     

箍筋末端135度弯钩二次就位法讨论

随着人们对建筑安全的日益重视 ,对建筑抗震要求的提高 ,国内外有关规范都对箍筋末端的设置作了明确规定 ,要求做成 135度弯钩。而在工程实践中 ,由于施工上的技术困难 ,很多工程都只设置成 90度弯钩。笔者提出的箍筋末端 135度弯钩二次就位法在基本不增加 90度弯钩施工难度与费用的基础上实现了 135度弯钩的施工 ,其法是可行的     

基于显微视觉的宏/微双重驱动微动台的自动标定

提出了基于压电技术的微操作系统的自动标定方法,采用混合式步进电机直接驱动的宏动平台,实现系统大行程宏动定位,安装在宏动平台上的压电陶瓷驱动的微动平台和精密光栅,实现亚微米级的分辨率和定位精度,通过以上两部分实现定位机构的全闭环反馈控制,采用显微视觉反馈获取微动台操作器在图像中的位置信息进行标定。实验结果表明:系统的动态和稳定性能良好,自动标定运算速度快,运行速度达到11 frame/s,实现了对系统的精确标定,标定精度达到0.1μm。     

Catalytic oxidation of naphthalene using a Pt/Al2O3 catalyst

Polycylic aromatic hydrocarbons (PAHs) are listed as carcinogenic and mutagenic priority pollutants, belonging to the environmental endocrine disrupters. Most PAHs in the environment stem from the atmospheric deposition and diesel emission. Consequently, the elimination of PAHs in the off-gases is one of the priority and emerging challenges. Catalytic oxidation has been widely used in the destruction of organic compounds due to its high efficiency (or conversion of reactants), its economic benefits and good applicability.

This study investigates the application of the catalytic oxidation using Pt/γ-Al₂O₃ catalysts to decompose PAHs and taking naphthalene (the simplest and least toxic PAH) as a target compound. It studies the relationships between conversion, operating parameters and relevant factors such as treatment temperatures, catalyst sizes and space velocities. Also, a related reaction kinetic expression is proposed to provide a simplified expression of the relevant kinetic parameters.

The results indicate that the Pt/γ-Al₂O₃ catalyst used accelerates the reaction rate of the decomposition of naphthalene and decreases the reaction temperature. A high conversion (over 95%) can be achieved at a moderate reaction temperature of 480 K and space velocity below 35,000 h⁻¹. Non-catalytic (thermal) oxidation achieves the same conversion at a temperature beyond 1000 K. The results also indicate that Rideal–Eley mechanism and Arrhenius equation can be reasonably applied to describe the data by using the pseudo-first-order reaction kinetic equation with activation energy of 149.97 kJ/mol and frequency factor equal to 3.26 × 10¹⁷ s⁻¹.     

Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Addition-Fragmentation Chain Transfer Polymerization

A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA) group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers. The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE as the RAFT agent. Number-average molecular weight (M_n,GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow (PDI< 1.50). The results of chain-extension reaction, ¹H NMR spectra and UV/Vis spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine (TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated.     

基于Lab VIEW的小型汽油机磁电机点火提前角的测量

本文介绍了磁电机点火系统的点火提前角测量原理。对点火系统的点火信号和触发信号进行采集、调理，再用单片机进行处理，最后用LabVIEW进行点火提前角数据存储和显示。     

试论QC小组活动与企业文化建设相结合

本文分析了QC小组活动与企业文化的特点与共同点,提出开展QC小组活动与企业文化建设是互相促进,互相补充的,两者可以互相结合。     

Investigation on Single-Mode–Multimode– Single-Mode Fiber Structure

This paper presents an investigation on a single-mode-multimode-single-mode fiber structure. A one-way guided-mode propagation analysis for the circular symmetry waveguide is employed to model the light propagation and the approximated formulations are derived and evaluated concerning the accuracy. Phase conjunction of the multimode interference within the fiber structure is revealed. A simple way to predict and analyze the spectral response of the structure is presented through the space to wavelength mapping with the derived approximated formulations. The prediction of spectral response is verified numerically and experimentally.