全文获取类型
收费全文 | 234871篇 |
免费 | 24625篇 |
国内免费 | 14586篇 |
专业分类
电工技术 | 20068篇 |
技术理论 | 12篇 |
综合类 | 19791篇 |
化学工业 | 32973篇 |
金属工艺 | 14782篇 |
机械仪表 | 15681篇 |
建筑科学 | 19858篇 |
矿业工程 | 7931篇 |
能源动力 | 7155篇 |
轻工业 | 16766篇 |
水利工程 | 5796篇 |
石油天然气 | 11465篇 |
武器工业 | 2769篇 |
无线电 | 27964篇 |
一般工业技术 | 24023篇 |
冶金工业 | 9370篇 |
原子能技术 | 2819篇 |
自动化技术 | 34859篇 |
出版年
2024年 | 1015篇 |
2023年 | 3712篇 |
2022年 | 7807篇 |
2021年 | 10841篇 |
2020年 | 8020篇 |
2019年 | 6174篇 |
2018年 | 6965篇 |
2017年 | 7918篇 |
2016年 | 7084篇 |
2015年 | 10604篇 |
2014年 | 13179篇 |
2013年 | 15600篇 |
2012年 | 18130篇 |
2011年 | 20065篇 |
2010年 | 17529篇 |
2009年 | 16363篇 |
2008年 | 16008篇 |
2007年 | 15169篇 |
2006年 | 13743篇 |
2005年 | 11059篇 |
2004年 | 8747篇 |
2003年 | 6628篇 |
2002年 | 6208篇 |
2001年 | 5275篇 |
2000年 | 4301篇 |
1999年 | 3599篇 |
1998年 | 2384篇 |
1997年 | 1959篇 |
1996年 | 1836篇 |
1995年 | 1482篇 |
1994年 | 1213篇 |
1993年 | 772篇 |
1992年 | 633篇 |
1991年 | 431篇 |
1990年 | 353篇 |
1989年 | 294篇 |
1988年 | 222篇 |
1987年 | 142篇 |
1986年 | 120篇 |
1985年 | 62篇 |
1984年 | 51篇 |
1983年 | 35篇 |
1982年 | 46篇 |
1981年 | 49篇 |
1980年 | 51篇 |
1979年 | 32篇 |
1977年 | 12篇 |
1976年 | 19篇 |
1959年 | 19篇 |
1951年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 782 毫秒
91.
92.
在伯克氏菌Bth264野生株产新型抗癌药物Thailandepsin A以及调节基因tdp R正向调控Thailandepsin A生物合成的基础上,利用基因工程菌Bth264/p BMTL3-tdp R发酵生产Thailandepsin A,以提高产量。以0.5%乳糖为诱导剂,确定最佳诱导条件:发酵15 h添加乳糖,诱导时间6 h;通过单因素实验,确定葡萄糖和胰蛋白胨作为碳氮源、装液量65/250 m L以及接种量1%;同时结合优化发酵培养基进行发酵,Thailandepsin A产量达到252.14 mg·L-1,比优化前的产量提高56%;另外在发酵过程中,添加大孔树脂HP-20原位吸附产物,Thailandepsin A产量可达283.75 mg·L-1,比不加树脂提高13.8%;最后,基于RT-PCR和比较Ct值法,基因工程菌和野生菌相比,Thailandepsin A生物合成基因tdp B、tdp C1的转录水平分别提高11.4倍和6.0倍,对应的产量增加4.6倍,从而在很大程度上说明调节基因tdp R的过表达促进生物合成基因转录水平的提高以及产量的增加。 相似文献
93.
94.
Yafei Liu Zhilong Fu Xingyu Chen Yaxin Wei Bo Zhang Aimin Chang 《Journal of the American Ceramic Society》2021,104(5):2134-2142
Rare-earth ions doped Ca0.9R0.1CeNbMoO8 (R = Y, Sm, Nd, La) ceramics have been successfully prepared by solid-state method, and their modifications to the microstructure and electrical properties are also investigated. The rare-earth ions doped ceramics exhibit the scheelite structure. With the increase in the radius of rare-earth ions, the lattice distortion and bond interaction will be enhanced, and the consistency of grain size will be reduced. The ceramics exhibit negative temperature coefficient (NTC) thermistor characteristics in the temperature range of 473 K-1273 K, and the activation energy decreases with the increase of the radius of rare-earth ions. Rare-earth ions doping can increase the content of Ce3+ ions and promote the conductivity of ceramics. Except for Sm3+-doped ceramics, the high-temperature aging rate of other ceramics is less than 2%. The existence of some metastable Sm2+ ions in Sm3+-doped ceramics not only increases the activation energy, but also reduces the high-temperature stability of the ceramics. 相似文献
96.
Donghai Xu Peng Feng Yang Wang Wanpeng Yang Yu Wang Shaoyan Sun 《American Institute of Chemical Engineers》2022,68(2):e17472
Corrosion and salt deposition problems severely restrict the industrialization of supercritical water oxidation. Transpiring wall reactor can effectively weaken these two problems by a protective water film. In this work, methanol was selected as organic matter, and the influences of vital structural parameters on water film properties and organic matter removal were studied via numerical simulation. The results indicate that higher than 99% of methanol conversion could be obtained and hardly affected by transpiration water layer, transpiring wall porosity and inner diameter. Increasing layer and porosity reduced reactor center temperature, but inner diameter's influence was lower relatively. Water film temperature reduced but coverage rate raised as layer, porosity, and inner diameter increased. Notably, the whole reactor was in supercritical state and coverage rate was only approximately 85% in the case of one layer. Increasing reactor length affected slightly the volume of the upper supercritical zone but enlarged the subcritical zone. 相似文献
97.
Gang Zheng Xiaoxuan Yu Haizuo Zhou Xinyu Yang Wei Guo Pengbo Yang 《Geotextiles and Geomembranes》2021,49(1):180-187
Incompressible dipping substrata are commonly encountered in engineering practice. Compared to horizontal underlying strata, the inclined underlying stratum increase the risk of collapse of embankments reinforced with columns because it weakens the restraint of the column base. The objective of this study is to investigate the effectiveness of geosynthetics on improving the embankment stability when the underlying stratum is inclined. The influence of geosynthetic tensile stiffness on the ultimate surcharge and failure mechanism is studied. A deep-seated failure with column tilting occurs when the geosynthetic tensile stiffness is low, whereas a lateral sliding occurs when the geosynthetic tensile stiffness is high. To illustrate the contribution of geosynthetics, the distribution of the lateral pressures acting on the columns is analyzed. 相似文献
98.
The capture of particles by charged droplets was simulated by considering the electrostatic interactions of droplet-droplet and droplet-particle. The results indicate that the electrostatic repulsion between droplets leads to a dynamic accumulation mode of particles. However, the droplet spacing has an insignificant effect on the capture efficiency when the electrostatic deposition predominates. The increase of droplet charge remarkably improves the capture efficiency, in which the capture of fine particles accounts for the largest proportion. Compared to the droplet charge, the droplet size shows a limited improvement in the capture efficiency. Reducing the droplet velocity prolongs the capture time instead of enhancing the capture capacity per unit time, thereby improving capture efficiency. 相似文献
99.
Wei Lai Lihong Ge Huaming Li Yilin Deng Bin Xu Bo Ouyang Erjun Kan 《International Journal of Hydrogen Energy》2021,46(53):26861-26872
The electrochemical water splitting to produce H2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)2 heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H2-evolving current density of 10 mA/cm2 and 153 mV at 100 mA/cm2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance. 相似文献
100.
Crystallographic characteristics and microwave dielectric properties of Ni-modified MgTa2O6 ceramics
Liang Shi Xueying Wang Rui Peng Gang Wang Cheng Liu Xiaolei Shi Dainan Zhang Huaiwu Zhang 《Ceramics International》2021,47(16):22514-22521
Ni2+ modified MgTa2O6 ceramics with a trirutile phase and space group P42/mnm were obtained. The correlations between crystallographic characteristics and microwave dielectric performance of MgTa2O6 ceramics were systematically studied based on the chemistry bond theory (PVL theory) for the first time. The results indicate that the introduction of Ni2+ causes a change in polarizability and the Mg–O bond ionicity, which contributes to the variation of dielectric constant. Moreover, the lattice energy, and packing fraction, full width at half maximum of the Raman peak of Ta–O bond, as the quantitative characterization of crystallographic parameters, regulate the dielectric loss of MgTa2O6 ceramics in GHz frequency band. In addition, the study of sintering behavior shows that the densification and micromorphology are the crucial factors affecting the microwave dielectric performance. Typically, Ni2+ doping on the A-site of MgTa2O6 can effectively promote the Q × f values to 173,000 GHz (at 7.43 GHz), which ensures its applicability in 5G communication technology. 相似文献