Room-Temperature Solid-State Lithium Metal Batteries Using Metal Organic Framework Composited Comb-Like Methoxy Poly(ethylene glycol) Acrylate Solid Polymer Electrolytes

Solid polymer electrolyte with good thermal stability and flexibility is an excellent candidate for solid-state lithium metal batteries, while its low ionic conductivity caused by high crystallinity limits its application at ambient temperature. Here a metal organic framework (zeolitic imidazolate framework-8, ZIF-8) composited comb-like methoxy poly(ethylene glycol) acrylate polymer electrolyte (MCPE) with high ionic conductivity (9.96 × 10⁻⁵ S cm⁻¹ at 30 °C) is prepared by an in situ UV polymerization method. The as-prepared MCPE exhibits improved mechanical property due to the introduction of porous ZIF-8 nanofillers, which is beneficial to suppress the growth of lithium dendrites. Consequently, the LiFePO₄||MCPE||Li cells show a high capacity of 116 mAh g⁻¹ at 30 °C and 0.5 C, and maintain 89.4% of initial capacity after 150 cycles with the average Coulombic efficiency of 99.9%. These results demonstrate that the MCPE shows great potential in solid-state lithium metal batteries near room temperature.     

Degradable Superhydrophilic Iron-Pillared Bentonite Doped with Polybutylene Adipate/Terephthalate Open-Cell Foam: Its Application in Dye Degradation,Removal of Heavy Metal Ions,and Oil–Water Separation

Development of industrialization has brought convenience to people's lives; however, it has also brought serious harm to the environment, where, water pollution is the most obvious. Here, a polybutylene adipate terephthalate (PBAT) open-cell foam doped with iron-pillared bentonite (IPB) is prepared by using sugar as a pore-forming agent and solution phase separation, and then combined with a solution dipping method to coat the foam surface with a polyacrylamide/SiO₂, which makes the PBAT foam superhydrophilic. The static adsorption effect of superhydrophilic IPB-doped PBAT open-cell foam on methylene blue (MB) and Cu²⁺ is studied. The adsorption isotherm fitting shows that the adsorption conforms to the Langmuir model and it has biased toward monolayer adsorption. The adsorption kinetics fitting confirms that the adsorption process is in line with the pseudo-second-order adsorption model, which is dominated by chemical adsorption. The modified PBAT open-cell foam has an adsorption effect on Cu²⁺; however, it has weak cyclic adsorption capacity. It shows a good cyclic adsorption ability for the cationic dye MB and it has >95% photodegradation efficiency of the MB after five time's cyclic adsorption. The superhydrophilicity makes the foam to have better applications in oil–water separation.     

Facile Modification of Biochar Derived from Agricultural Straw Waste with Effective Adsorption and Removal of Phosphorus from Domestic Sewage

Journal of Inorganic and Organometallic Polymers and Materials - In recent decades, straw waste is the major byproduct around agriculture that has become one of the factors of environmental...     

First-Principles Investigation of the Interfacial Stability,Precipitate Formation,and Mechanical Behavior of Al3Li/Al3Zr/Al Interfaces

Metallurgical and Materials Transactions A - Precipitates including Al3Li, Al3Zr and core–shell structured Al3Li (Al3Zr) produce significant strengthening effects in Al-Li alloys by means of...     

水质稳定剂HPDP缓蚀阻垢性能评定

用静态阻垢，旋转挂片失得法实验研究了ＨＰＤＰ对ＣａＣＯ３，Ｃａ３（ＰＯ４）２等的阻垢性能以及对Ｑ２３５碳钢的缓蚀性能等。试验证明，ＨＰＤＰ是一种优良的阻垢缓蚀剂，适用于高温，高碱，高ＰＨ，高浓缩倍数的循环冷却水处理，具有广阔的应用前景。     

中国蠕墨铸铁40年

含有蠕虫状石墨的铸铁作为正式的工程材料来研究和应用，我国与国外同期开始，而投入工业应用则早于国外。早在20世纪60-80年代，我国对它就作了广泛深入的试验研究。据不完全了解，迄今，我国在不同场合已发表了600多篇文献，其中研究过十种生产方法，并研究了三十余种蠕化剂，提出了获得蠕虫状石墨的蠕化剂临界加入量计算式和蠕化处理后的“浮渣”形成机理；在铸造性能、金相组织、机械-物理性能和某些使用性能、铸件加工的工艺特性以及它们之间相互关系等方面的研究趋于基本完善，并制订了蠕铁金相和牌号的部级标准；在蠕铁一次结晶理论方面的研究仍处于百花齐放状态；蠕铁通过各种热处理和合金化可进一步提高性能，扩大其应用范围；在交通运输及内燃机零件、矿山和冶金用品以及在交变热载荷下工作的铸件、机械制造及液压件类铸件、轻工及纺织机械铸件、军工产品等等领域内生产或试生产着数百种蠕铁件，单件重量最大达38t，最小约1kg，年产量约有20万t，其中绝大多数采用冲天炉熔炼的不经预处理的铁液来制取，少数采用电炉、冲天炉-电炉或高炉-电炉双联熔炼：列举了蠕铁的典型应用实例；但在蠕铁炉前快速检验和蠕铁件显微组织无损检验的较精确的手段方面仍是薄弱环节；提出了今后应加强的工作；总的看来，我国蠕铁的研究、生产和应用水平不亚于国外，一些方面还处于领先地位。正文共约43000字．参考文献329篇，表5个。     

ON THE WETTABILITY OF CARBON ELECTRODES BY MOLTEN CRYOLITE-ALUMINA ELECTROLYTE

<正> 在冰晶石-氧化铝熔盐电解中,电解质向阴极渗透以及在阳极上发生阳极效应,这些过程都和电解质对炭电极的湿润性有关系。将近二十年前Жемчужина和Беляев曾在电极极化条件下研究NaF-AlF_3,Na_3AlF_6-Al_2O_3系以及含有盐类添加物的冰晶石熔液在炭板上的湿润角,但试验用电流强度较小(0.01—0.3A)。我们在实验室用微型电解槽,采取较大的电流强度(0.1—5.0A,其中包括与工业上铝电解槽阳极电流密度值     

稀有金属杂多化合物的脱硫脱硝性能研究

对稀有金属钨、钼的典型杂多化合物HCP(Heteropoly Compound Comprising)进行了同时脱硫脱硝性能对比研究.发现磷钼酸钠对SO2,NOx具有较高的去除效率.在此基础上,以磷钼酸钠为对象,考察了温度、吸收剂浓度、pH值、气流中氧含量等多种因素对体系性能的影响.实验结果表明:磷钼酸钠溶液对SO2,NOx的脱除率分别可达92%与55%;体系的同时脱硫脱硝效率随温度升高而有所降低,适宜温度为室温;提高吸收剂浓度、增加溶液pH值,均能显著增强体系的脱硫脱硝性能;气流中氧含量的提高,对NOx的脱除有显著的促进作用,但却在一定程度上削弱了体系的脱硫效果.对比发现:磷钼酸钠体系对SO2和NOx的脱除率均高于Fe-EDTA体系.     

微型飞行器的研究与发展

微型飞行器是90年代中期出现的新生事物，它正以日新月异的速度蓬勃向前发展。它的出现引起了世界各国的极大关注和高度重视。本文介绍了微型飞行器的概念和应用前景，重点综述国内外研究现状，总结出研究的关键问题，并提出了未来微型飞行器研究发展的趋势。     

Stage-efficiency of centrifugal extractor used in nuclear industry

1　INTRODUCTIONComparedwithamixer settlerorpulsedcolumnusedinthenuclearfuelreprocessingextraction pro cesses,ashort residence timecentrifugalextractorcatchesresearcher seyesbecauseofthe goodphaseseparationandasmallhold upvolume .Itshowsthefollowingadvantagesinthenuclearindustry[1] :1)Reducingsolventdegradationduetoradiation ;2 )Reducinginventoryofaqueousandorganicphases ,whichgivesrapidstart upandshut down ;3)Com pactdesignthatcontributestothereductionofplantcost .Manydifferenttypesofcen…