钠基膨润土胶质价测试方法的改进

以两种人工钠化膨润土为研究对象,探讨了文献胶质价测试方法的不合理性、取土量和MgO量这两个关键因素。实验结果表明:用常规100 mL量筒测胶质价时,取土量和MgO量影响较大,有必要针对具体试样做条件试验,最佳条件是1#钠土为取3.00 g土、0.2 g MgO,2#钠土为取5.00 g土、0.33 g MgO。     

Assembly of Enantioenriched cis‐3a,8a‐Hexahydropyrrolo[2,3‐b]indole Scaffolds by Silver(I)‐Catalyzed Asymmetric Domino Reaction of Isocyanoacetates in the Presence of Cinchona‐Derived Chiral Phosphorus Ligands

By using Cinchona‐derived chiral phosphines as catalytic ligands, enantioenriched cis‐3a,8a‐hexahydropyrrolo[2,3‐b]indoles (ent‐HPIs), which are core scaffolds in a large array of biologically active natural products, can be convergently assembled under mild conditions through the silver(I)‐catalyzed asymmetric domino reaction of readily available isocyanoacetates and 2‐(2‐aminophenyl)acrylates. Various functionalities can be tolerated in the reaction, affording enantioenriched HPIs in high overall yields and good enantioselectivities (up to 92% ees).

     

Dearomatization of Indole Derivatives via Palladium‐Catalyzed C?H Bond Functionalization of Pyrroles: Convenient Construction of Spiroindolenines

An intramolecular palladium(II)‐catalyzed dearomative arylation reaction of indoles via C H bond functionalization was developed, providing access to structurally novel spiroindolenines with moderate to good yields. A one‐pot process for the synthesis of spiroindoline derivatives was also realized.

     

Fabrication of shish-kebab-structured carbon nanotube/poly(ε-caprolactone) composite nanofibers for potential tissue engineering applications

The electrospinning process was applied to fabricate the nanofibers of biodegradable poly(ε-caprolactone)(PCL) in which different contents of multiwalled carbon nanotubes(MWCNTs) were embedded. Afterward,the electrospun nanofibers were successfully decorated with shish-kebab structure via a self-induced crystallization technique. The topographical features and the mechanical properties of the composite scaffolds were characterized,and the biocompatibility of the material was assessed by using human osteogenic sarcoma osteoblasts(MG-63 cells). The carbon nanotube(CNT) concentration is found to affect the fiber diameter and mechanical properties of electrospun nanofibers and the periodic distance of the shish-kebab architecture. Cellular attachment and proliferation assays reveal that 0.5 wt% CNT-embedded PCL scaffold shows enhanced biocompatibility with MG-63 cells than their counterparts made of neat PCL, and the collagen-like nanotopology provided by the shish-kebab structure further facilitates the cell adhesion and proliferation. The superior interactions between cells and scaffolds demonstrate that the shish-kebab-structured CNTs/PCL nanofibers may be promising candidate for tissue engineering scaffold application.     

环氧型水性自泳漆的研制

采用"己二酸与环氧树脂酯化反应+氨水中和+相反转"工艺制备高稳定性的水性环氧乳液,加入活化剂、颜料浆、去离子水等,制备了环氧型水性自泳漆。样板实验结果表明:漆膜表面光滑平整、有光泽,耐盐雾实验时间为360h,达到汽车车身底漆I级防腐标准,具有较好的市场应用潜力。     

Quench Sensitivity of AA7N01 Alloy Used for High-Speed Train Body Structure

JOM - The quench sensitivity of AA7N01 aluminum alloy used for high-speed train body structure was investigated by end-quenching test, time–temperature-transformation curves simulation,...     

园林景观标准化探讨

近年来,我国房地产经历了爆发式的发展,园林建设也处于高速的发展中。标准化是企业做大做强的途径之一,也是增强企业规模的重要手段。本文将主要探讨园林企业竞争的发展方向,即景观标准化,为未来园林企业的发展提供一点参考意见。     

锻造成形有限元数值模拟技术

数值模拟是目前塑性成形分析最有效的方法.通过有限元数值模拟,可以预测金属流动规律,获得应力场、应变场及温度场等场量分布及变化,进而揭示出复杂的变形机理.介绍锻造成形有限元法以及模拟中的关键技术,并以基于DEFORM软件的热-力耦合模拟实验为例,探讨了数值模拟技术在工程实际中的指导意义.     

设备闸门提升与导向装置运行特性仿真分析

对核电厂设备闸门提升与导向装置在设备闸门封头开启与关闭过程中的运动特性进行了分析研究,该研究借助动力学仿真软件ADAMS展开,分别对提升与导向装置可能出现的同步提升操作和不同步提升操作两种工况进行了仿真分析。分析结果表明:在同步提升操作工况下,设备闸门封头两侧导向箱位移一致,提升与导向装置不会产生卡滞;在不同步提升操作工况下,设备闸门封头两侧导向箱最大允许高度差为54 mm,否则提升与导向装置将产生卡滞。     

In-situ diagnostic of femtosecond laser probe pulses for high resolution ultrafast imaging

Ultrafast imaging is essential in physics and chemistry to investigate the femtosecond dynamics of nonuniform samples or of phenomena with strong spatial variat...