Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

硝硫混酸与Ag、Cu反应的动力学

用失重法探讨了硝硫混酸此例、浸出温度和时间等因素对银的溶解和铜的钝化的影响。结果表明:在一定的[HNO_3]范周内,较高温度时,银的溶解符合一级反应规律;求得银的溶解量与时间、HNO_3起始浓度等的关系式和相应的反应活化能;铜在此条件时是钝化的。本实验再一次证实了银的溶解和铜的钝化机理的正确性,也为银、铜的分离提供了实验依据。     

移动定位技术的现状与发展趋势

基于位置服务为人们的日常生活带来了极大的方便,同时也推动了移动定位技术行业的快速发展。针对移动定位技术发展状况,分析目前主流定位技术的优劣,并对取得的突破作简单的总结归纳。     

基于云基础设施的服务部署优化问题建模

目前典型的云基础设施提供商所提供的虚拟机资源都是有限的规格类型,当同一个服务部署在不同配置的虚拟机上时,会体现出不同的性能。通过对基于云基础设施的SaaS层服务部署情况进行研究和分析,提出对服务部署策略进行优化的必要性,并将该服务部署优化问题抽象为多目标组合优化问题,对其进行数学建模;然后利用排队论,得出优化指标的计算方法,并进行实验验证。     

车辆仪表检校方法研究

针对常用仪表的检校需求,提出了一种利用激励电路代替传感器输出的方法,校准仪表指示器。设计了阻值激励电路、电压激励电路、电流激励电路及脉冲激励电路,能够实现车辆仪表快速原位检校。     

公交车的远卡自动收费系统设计

在对公交收费系统的发展和无线射频识别技术进行研究的基础上,分析了现行公交收费系统的优缺点与局限性,并提出了一种公交车远卡自动收费系统的设计思路.主要使用ARM核芯片STM32、射频芯片nRF24LE1等器件,完成了硬件设计.在软件设计上实现了自动计算票价的扣费机制.该系统创新性地将远距离射频技术应用在公交收费系统中,不仅方便了乘客,而且大大提高了乘客上下车的效率.     

Efficient identity-based signature over NTRU lattice

Identity-based signature has become an important technique for lightweight authentication as soon as it was proposed in 1984. Thereafter, identity-based signature schemes based on the integer factorization problem and discrete logarithm problem were proposed one after another. Nevertheless, the rapid development of quantum computers makes them insecure. Recently, many efforts have been made to construct identity-based signatures over lattice assumptions against attacks in the quantum era. However, their efficiency is not very satisfactory. In this study, an efficient identity-based signature scheme is presented over the number theory research unit (NTRU) lattice assumption. The new scheme is more efficient than other lattice- and identity-based signature schemes. The new scheme proves to be unforgeable against the adaptively chosen message attack in the random oracle model under the hardness of the γ-shortest vector problem on the NTRU lattice.