Wcomet直接还原法渣铁分离影响因素研究

研究还原温度、渣相配料碱度和渣中CaF2、K2O、P2O5、S、FeO的含量等因素对2CaO·SiO2形成及其相变的影响规律。结果表明,在快速升温条件下,温度高于1300℃后2CaO·SiO2才大量生成;CaF2、S和FeO对2CaO·SiO2相变不产生影响,但K2O和P2O5对2CaO·SiO2相变具有明显抑制作用;渣相二元碱度R〈1．8时渣的自然粉化效果明显变差。     

Examining the use of Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> nanoparticles to enhance the NH<Subscript>3</Subscript> sensitivity of polypyrrole films

Summary Polypyrrole (PPy) composite films with different contents of Fe₃O₄ were prepared by in-situ polymerization of pyrrole in aqueous solutions. The dependence of dc current changes on the response of the samples exposure to NH₃ vapor has been investigated. The results shows the composite films are more stable than the pristine ones after being exposed to NH₃ vapor. Meanwhile, the response time was reduced with increasing the Fe₃O₄ content in the films. The results might be originated from the structural changes in the PPy films caused by the addition of Fe₃O₄.     

Novel polyurethane coating technology through glycidyl carbamate chemistry

Glycidyl carbamate chemistry combines the excellent properties of polyurethanes with the crosslinking chemistry of epoxy resins. Glycidyl carbamate functional oligomers were synthesized by the reaction of polyfunctional isocyanate oligomers and glycidol. The oligomers were formulated into coatings with several amine functional crosslinkers at varying stoichiometric ratios and cured at different temperatures. Properties such as solvent resistance, hardness, and impact resistance were dependent on the composition and cure conditions. Most coatings had an excellent combination of properties. Studies were carried out to determine the kinetics of the curing reaction of the glycidyl carbamate functional oligomers with multifunctional and model amines. Detailed kinetic analysis of the curing reactions was also undertaken. The results indicated that the glycidyl carbamate functional group is more reactive than a glycidyl ether group. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, on October 27–29, 2004, in Chicago, IL.     

油酸二聚甘油酯的合成及其柔软保湿纸的测试

以油酸缩水甘油酯和甘油为原料，在固体酸催化剂（活性炭负载硫酸）作用下，通过开环反应制得油酸二聚甘油酯。通过FTIR和1HNMR对产物结构进行表征，并将其用作柔软保湿剂涂覆到面巾纸上对纸张的柔软度、保湿性、抗张强度等性能进行测试。结果表明：油酸二聚甘油酯具有优异的柔软保湿性能，在油酸二聚甘油酯添加量为甘油水溶液质量的0.25%时，面巾纸的柔软度（49 mN）优于市面上有机硅柔软剂改性的面巾纸柔软度（68 mN），这是由于大分子柔软剂能够对纤维表面的缺陷进行修复，从而使纤维表面平整度的提升。且在温度为30 ℃，湿度为60%时，油酸二聚甘油酯型柔软保湿剂涂覆后的面巾纸的保水率（98.2%）也略高于有机硅柔软剂涂覆后的面巾纸的保水率（96.5%）。     

增粘树脂在SBS改性胶粘剂中的应用

研究了增粘树脂在SBS改性胶粘剂中的应用，其中包括增粘树脂品种、用量对胶粘剂剥离强度的影响，同时研究了该胶粘剂对各种鞋材的粘结性。结果表明，该胶对许多鞋材的初粘力和剥离强度都达到了制鞋业的要求。     

利用七宫格的遮挡车辆凹性检测与分割

目的:交通场景中车辆间的距离过近或相互遮挡容易造成识别上的粘连,增加了准确检测目标车辆的难度,因此需要建立有效、可靠的遮挡车辆分割机制。方法:首先在图像分块的基础上确定出车辆区域,根据车辆区域的长宽比和占空比进行多车判断;然后提出了一种基于“七宫格”的凹陷区域检测算法,用以找出车辆间的凹陷区域,通过匹配对应的凹陷区域得到遮挡区域;最后,将遮挡区域内检测出的车辆边缘轮廓作为分割曲线,从而分割遮挡车辆。结果:实验结果表明,在满足实时性的前提下算法具有较高的识别率,且能够按车辆的边缘轮廓准确分割多个相互遮挡的车辆。与其他算法相比,该算法提高了分割成功率和分割精度,查全率和查准率均可达到90%。结论:提出了一种新的遮挡车辆分割方法,有效解决了遮挡车辆不宜分割和分割不准确的问题,具有较强的适应性。     

网络控制系统随机延迟的预测控制

针对网络控制系统随机时延、时变等特性造成控制效果不理想的问题,提出一种改进的广义预测控制与递推最小二乘法相结合的预测控制策略.上述控制策略将传统的预测控制运用于网络控制系统中,针对网络随机时延的特性,采用改进的广义预测控制算法对随机时延进行补偿.结合分段可变遗忘因子递推最小二乘法对被控对象模型参数进行在线辨识,可以减少网络控制系统参数突变对系统造成的不利影响.仿真结果表明,所提出的预测控制策略可以有效解决网络控制系统随机时延问题,并且在参数突变的情况下也能够获得良好的控制效果.     

垂直姿态的非正交测量优化与校正

垂直小角度时,采用的非正交姿态测量方法旨在解决传感器输出信号极微弱和解算精度低等问题。描述了非正交坐标系的理论模型,对其进行了优化,确定了最佳偏置角度。利用补偿矩阵对因测斜仪安装问题引入的位置误差进行校正,通过井斜角和工具面角的解算结果验证校正效果。测试结果表明,在偏置角为45°时,姿态参数具有较高的解算精度;而数据校正能大幅度降低位置误差,进一步提高测量精度。     

Energetic surface heterogeneity of nanocrystalline TiO<Subscript>2</Subscript> films for dye-sensitized solar cells

Dye sensitized solar cells (DSSCs) have been receiving significant attention because they have many advantages compared to conventional organic solar cells. It has been known that the photovoltaic characteristics of DSSC are highly dependent on the adsorption properties of dyes on TiO₂ films. To analyze the surface heterogeneity of TiO₂ surfaces, single-phase anatase nanocrystallite titanium films were prepared by sol-gel method using the hydrolysis reaction of titanium tetraisopropoxide under acidic condition and characterized by XRD, FE-SEM and BET analysis. The adsorption energy distribution functions were calculated by the generalized nonlinear regularization method. It was found that the shape and the intensity of the adsorption energy distribution curve determined were highly related with the physical properties (i.e., geometrical heterogeneity) and chemical characteristics (i.e., energetic heterogeneity) of nanocrystalline TiO₂ for DSSC.     

基于计数排序的最小种子集贪心算法

网络最小种子集问题与网络影响最大化问题相关,研究的是对于具有节点阈值的网络,构造网络的最小节点子集,使得如果这个子集中的节点是活的,则在给定的影响传播模型下整个网络都受到影响。为此提出了新的贪心算法,以节点的度与阈值的差为关键值对网络节点进行计数排序,然后取值最小的节点进行处理。新算法在时间复杂度上改进了基于最小堆的种子点选取算法。在简单多数阈值模型上针对经典的无标度网络得到了所构造的种子集规模上界。实验在随机生成网络和一些实际网络数据集上进行,结果表明所提方法的有效性,特别在无标度网络上生成的种子集具有比相关算法更小的规模。