甲缩醛空气氧化制甲醛催化剂的研制和工艺条件探讨

考察了铁钼催化剂对甲缩醛空气氧化制甲醛的催化性能。制备了多种不同钼铁比和第三、第四组分的催化剂,进行了活性评价和筛选,探讨了适宜的工艺条件范围。对于所选定的催化剂(钼铁比为1.82～1.88;铬铁比为0.1～0.38)在适宜的工艺条件(甲缩醛进料浓度4.5～5.5％;甲缩醛和氧气进料比1:2.0±0.2;空速12000～22000h~(-1);热点温度370～390℃)下,甲醛收率可达85％左右。     

浅谈信息技术教育在艺术设计专业中的应用

当今社会已进入信息化时代,作为美学和功能学相结合的艺术设计专业,与发展迅猛的信息技术相结合是顺应时代发展的必然现象,信息技术为艺术设计提供了新的技术支撑和思维模式,大大促进了教与学的优化与提升,更好的培养和提高了学生的信息素质,从而使艺术设计从业人员创作出更能符合受众者所需的艺术设计作品。     

不饱和聚醚醋酸酐酯化封端合成工艺的探讨

简单介绍了目前不饱和伯羟基聚醚封端的几种常用方法,讨论了最具可操性的工艺方案,即利用醋酸酐酯化封端工艺各因素对封端结果影响的问题,通过系列正交实验数据,得出最佳封端剂用量、反应温度及时间等工艺条件。     

CATALYTICALLY ACTIVE COMPONENTS OF Fe_2O_3-Sb_2O_4 MIXED OXIDE CATALYSTS AND THEIR ROLE IN AMMOXIDATION OF PROPYLENE

The catalytically active components of a series of Fe_2O_3-Sb_2O_4 mixed oxide catalysts with differentSb/Fe ratio,calcined at elevated temperature,as well as with or without support,have been investigated byX-ray diffraction analysis,Mossauer spectroscopy and XPS in order to elucidate their catalytic behavior inammoxidation of propylene.Correlations of acrylonitrile yield with Fe~2 and Fe~3 respectively showed that,FeSbO_4 seems to bethe basic active component of catalyst,upon which the formation of new phase containing Fe~3 is responsiblefor a good selective oxidation.     

Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated.The results revealed that Zn+implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure.Meanwhile,C:Zn solid solution was synthesized after Zn+ implantation.The turn-on field and threshold field were 0.80 and 1.31 V/μm,respectively for original...     

Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

2,4,6-三甲氧基脱氧安息香的合成新方法

以1,3,5-三甲氧基苯替代间苯三酚为原料和苯乙腈反应,用甲苯替代不易回收且安全性较差的乙醚为溶剂,通过Hoesch反应制备得到2,4,6-三甲氧基脱氧安息香,产品经HNMR和MS定性.因醚键的保护作用降低了羟基的反应活性,抑制了副反应,使得方法改进后,Hoesch反应的单步收率提高到81.3%.考察了原料配比、反应时间及ZnCl2用量对反应的影响,得到了较佳的反应条件为1,3,5-三甲氧基苯与苯乙腈的摩尔配比为1.2∶1,反应时间为28 h,ZnCl2与苯乙腈的摩尔配比为0.3∶1.     

6-PRRS并联机器人的动力学建模研究

为解决并联机器人动力学模型的计算复杂性与实时准确控制之间的矛盾,采用虚功原理建立6-PRRS并联机器人各构件随参数变化的完整动力学方程,对6-PRRS并联机器人动力学模型在各种工作情况下进行仿真分析,对机器人各部分质量和转动惯量对驱动力的影响进行研究,提出动力学模型简化策略,减小了动力学计算量,提高并联机器人动力学的计算速度,为并联机器人的控制和参数识别奠定了基础.     

弱酸性条件起始合成MUF树脂工艺研究

为了开发一种新的在"弱酸—弱碱—弱酸—弱碱"条件下合成三聚氰胺-尿素-甲醛树脂(MUF)的工艺,对弱酸性条件下起始合成MUF工艺进行研究.探讨了在不同酸性阶段加入的三聚氰胺对脲醛树脂性能的影响,找出最佳的三聚氰胺改性脲醛树脂的合成工艺.在最佳工艺基础上,评价三聚氰胺用量对MUF树脂性能的影响以及对胶合板性能的影响,并对MUF树脂和普通脲醛树脂进行红外分析.结果证明:三聚氰胺在甲醛与尿素一次缩聚之后加入,对脲醛树脂改性效果最好,其胶合板湿剪切强度与甲醛释放量之间达到较好平衡,胶合板甲醛释放量为0.63mg/L,湿剪切强度为1.03MPa.红外谱图分析表明:三聚氰胺分子以亚甲基与脲醛树脂分子链相连并有可能嵌入脲醛树脂分子链中,形成一定数量的醚键,使三聚氰胺在脲醛树脂中真正起到骨架作用.     

GM(1,1)模型在虚拟仪器测量过程控制中的应用

虚拟仪器的测量过程控制是保证测量数据有效的重要手段,利用灰色系统GM(1,1)模型对虚拟仪器的测量过程进行控制,由少量数据信息得到未来的预期测量结果,通过与核查标准的测量结果相比较来判别测量过程是否受控.论文给出了测量过程控制判别限、适用灰色系统GM(1,1)模型的条件以及模型精度检验判据.