一种高效过滤亚微米级细颗粒的新液固过滤技术——表层过滤

论述一种新的可高效过滤液体中亚微米级细颗粒的表层过滤技术,分析了表层过滤技术的特点、过滤模式、表层过滤基本条件和设计计算中所必需的数学模型。介绍了表层过滤技术在我国工业生产上推广应用的概况。     

润滑油糠醛精制装置优化运行措施

对糠醛抽提装置生产中存在的问题进行原因分析,提出具体的解决方法,实施后效果较明显.     

TPU/ATH复合材料热老化性能研究

热塑性聚氨酯弹性体(TPU)具有较广泛的应用,并且在有机领域获得了较高的评价。但由于TPU自身的不足,经常导致一些事故的发生。人们发现一些无机粒子其化学性质稳定,并且受热分解时吸热脱水过程可以延缓聚合物的燃烧。故以热塑性聚氨酯弹性体(TPU)和氢氧化铝(ATH)为主要原料,采用溶液共混法制备TPU/ATH复合材料,着重研究了TPU/ATH复合材料老化后的力学性能和热性能。结果表明,从力学性能上看,随着老化时间的推移,TPU/ATH复合材料的力学性能逐渐降低。红外图谱分析,老化时间168h之内,老化导致的TPU大分子链的断裂引起力学性能的下降。老化时间0~24h之内,由于分子链断裂导致复合材料结晶度减小,老化时间为24h的复合材料的结晶度低于老化前复合材料的结晶度。采用XRD计算复合材料的结晶度与DSC的计算结果基本符合。     

高密度聚乙烯装置旋液分离器堵塞原因及对策分析

30万吨/年高密度聚乙烯装置旋液分离器D3001A/B在生产的过程中容易堵塞。从旋液分离器顶部密度增加、反应器的内部固体含量(Solids-in)增加及淤浆加热器的热负荷增加等现象可以判断D3001A/B堵塞。根据不同反应模式和生产牌号,从反应器正常运行的参数和堵塞时的参数进行分析,并提出有效的优化措施,如降低顶部回流量,减小底部固体浓度和保证旋液分离器内壁光滑度等。     

吸附器的工程设计

详细介绍了实现变压吸附气体分离技术的关键设备—吸附器的设计,及其制造检验相关的要求。     

Synthesis and characterization of LTA zeolite with uniform intracrystal mesopores directed by bridged polysilsesquioxane monomer

An ordered mesoporous LTA zeolites (MLTA) have been synthesized in presence of the bridged polysilsesquioxane monomer (BS-1) as mesoporogen. The relatively well-defined small-angle X-ray diffraction peaks and nitrogen sorption isotherms with narrow pore size distribution centered at around 2.2 nm both indicated the presence of uniformly mesopores in MLTA samples. The scanning electron microscopy and transmission electron microscopy observations further confirmed that the uniform and partially interconnected intracrystal mesopores were randomly distributed throughout the globular particles with rugged surfaces. Interestingly, removal of the BS-1 resulted in uniform mesopore diameters that are nearly consistent with the molecular size of BS-1 (1.8 nm). ²⁹Si MAS NMR revealed that the BS-1 was linked to MLTA zeolite crystal surface through 2 Si–O bonds and 3 Si–O bonds before calcinations. Nitrogen sorption analysis showed that the mesoporosity in MLTA samples could be adjusted by adding different amounts of BS-1 in starting gels. Relative to conventional mesoporous materials, one obvious feature of MLTA is that the resultant mesopores were structured by the bridged polysilsesquioxane monomer instead of commercial polymers or micelles, which broad the routes in synthesizing of various mesoporous materials with controllable pore size distribution, adjustable mesopore volume, and large surface area.     

Performance evaluation of asphalt containing layered double hydroxides with different zinc ratio in the host layer

The effects of five layered double hydroxides (LDHs) with different zinc ratio on the physical and rheological properties, chemical components, and anti-UV aging performance of asphalt were evaluated. Results show that LDHs improve the deformation resistance of asphalt at high temperature. After UV aging, LDH-modified asphalts show the smaller changes of physical and rheological properties and chemical components in comparison with asphalt, indicating the improved UV aging resistance. By comparison, the LDHs with higher ratio of zinc in the layers have the more outstanding UV reflection ability, leading to a beneficial effect in improving UV aging resistance of asphalt.     

Visible Light‐Initiated C(sp3)?Br/C(sp3)?H Functionalization of α‐Carbonyl Alkyl Bromides through Hydride Radical Shift

A new visible light‐initiated 1,5‐hydride radical shift strategy has been developed to enable the one‐step functionalization of both a C(sp³) Br bond and a C(sp³) H bond adjacent to the same carbon atom. This visible light photoredox catalysis offers a mild and straightforward access to diverse five‐membered carbocyclic ring‐fused polycyclic hydrocarbons with high turnover numbers (TONs; up to 4.93×10³) and broad substrate scope.

     

Synthesis of Polymer Nanospheres Conjugated Ce (IV) Complexes for Constructing Double Antibacterial Centers

Journal of Inorganic and Organometallic Polymers and Materials - The antimicrobial materials are rapidly emerging as a primary component in mitigation of bacterial pathogens, and functional...     

Numerical Modeling and Experimental Study of Laser Assisted Machining of Fused Silica

Silicon - Fused silica is a kind of high-strength optical material, which is widely used in industry. It is slow and inefficient to process hard and brittle materials by conventional machining (CM)...