多类型源储协调互动的配电网分布鲁棒优化调度

分布式光伏、风电等可再生能源出力具有较强的随机性和不确定性,其大量并网给配电网的运行带来了极大的挑战。本文提出了一种多类型源储协调互动的配电网分布鲁棒优化调度方法,基于分布鲁棒优化理论,对配电网中传统离散设备、可再生能源以及储能决策进行协调优化,提高配电网运行的经济性和安全性,实现了配电网运行决策保守性与鲁棒性的有效平衡。首先,考虑多类型源储资源的协调互动,建立配电网优化调度模型,并将其转化为混合整数二阶锥规划的形式;其次,利用可再生能源出力场景集进行不确定性刻画,建立分布鲁棒优化模型,并通过列和约束生成算法进行求解;最后,在PG&E69节点系统上进行算例分析,验证了所提方法的可行性与准确性。     

基于SWT的GIS电压互感器二次侧干扰分析

特快速暂态过电压（VFTO）是气体绝缘变电站（GIS）中切换隔离开关时产生的特殊电磁暂态现象。VFTO会以传导和辐射方式影响二次设备的正常运行。为探究VFTO对二次设备的干扰特性,文中采用自制的二次侧干扰测量装置对某1 000 kV GIS的电压互感器（PT）二次侧共模干扰进行现场实测。接着,对比了5种时频分析方法的性能,采用其中性能较优的同步压缩小波变换（SWT）对实测波形进行了时频分析。实测结果表明：PT二次侧的共模干扰电压峰峰值最高可达9.65 kV。微脉冲的时频分析结果表明：7.8 MHz频率分量幅值高,且贯穿波形的始终,是PT二次侧干扰的主导频率分量。该分析结果可为GIS中二次设备的电磁抗扰度测试和电磁防护设计提供参考。     

基于三维特征向量的非侵入式电热负荷细分算法

非侵入式负荷监测分解（NILMD）技术是当前居民用能服务深化提升和电力供需互动的重要数据获取手段,然而当前工程上应用广泛的事件驱动型NILMD技术一直无法准确细化分解电热负荷。针对这一问题,文中提出了一种基于三维特征向量的典型电热负荷细化分解算法。首先,基于有功、无功功率和电流谐波等电气负荷特征采用事件检测方法提取电热事件,在有功功率的基础上,引入运行时长、频繁启停次数等非电气负荷特征共同构建三维特征向量电器模型。然后,采用序贯覆盖法设计典型电热负荷细化分解命题学习规则和细化分解算法。最后,基于实证实验数据进行分解验证,发现4种典型电热负荷的细化分解准确率超过85%。实验结果表明,文中所提典型电热负荷细化分解算法有效地提高了4种典型电热负荷分解的准确率。     

Facile Fabrication of Poly(vinyl alcohol)/Polyquaternium-10 (PVA/PQ-10) Anion Exchange Membrane with Semi-Interpenetrating Network

Anion exchange membranes (AEMs) are one of the core components of AEM fuel cells. A series of poly(vinyl alcohol)/polyquaternium-10 (PVA/PQ-10) AEMs with semi-interpenetrating networks (s-IPNs) are prepared by a simple solution-casting method using glutaraldehyde (GA) as a cross-linking agent. Subsequently, the prepared PVA/PQ-10 cross-linked membranes are characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, mechanical analysis, water uptake and swelling ratio tests, ion exchange capacity (IEC) tests, ionic conductivity measurements, and oxidative/alkaline stability tests. The effects of the mass ratio of PVA and PQ-10 and the amount of cross-linking agent GA on the performance of the PVA/PQ-10 cross-linked membranes are systematically explored. The results show that the cross-linked PVA/PQ-10 AEMs have high IEC and low water uptake and swelling ratio, and its maximum ionic conductivity can reach 79.37 mS cm^–1 at 80 °C. In addition, the PVA/PQ-10 cross-linked membrane has good oxidative and alkaline stability under optimal preparation conditions. These results may provide valuable insights toward more effective scheme designs and new, simple preparation methods for AEMs with s-IPN structures.     

Highly Uniform and Stable Transparent Electromagnetic Interference Shielding Film Based on Silver Nanowire–PEDOT:PSS Composite for High Power Microwave Shielding

Electromagnetic interference (EMI) shielding materials, especially ones with excellent shielding effectiveness (SE), high optical transmittance, long-term stability as well as high uniformity, are urgently desired to meet the requirements of many applications. Herein, an extremely transparent, stable and uniform silver nanowire (Ag NW)–poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) composite film as an EMI shielding material is prepared, which possess excellent shielding capability to both small signal and high power microwaves (HPM). The composite film exhibits SE of 30.5 dB in the frequency range of 1–12 GHz (small signal) and simultaneously has an optical transmittance of 91.0%. The SE continuously increases to 41.4 dB, while the optical transmittance still maintains at 81.1%. The composite film is very uniform, and its SE is almost unchanged even when exposed in air for a year. The SE of this composite film under the excitation of HPM is also thoroughly investigated. The HPM SE is much larger than that of small signal. As the power density of HPM is increased, the SE firstly remains unchanged, then continuously increases, and finally saturates. The SE exceeds 50 dB with the excitation power density of 40 W. More interestingly, the SE is saturated at a fixed HPM power density.     

PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High-Efficiency Protective Masks

Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min⁻¹, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material.     

钙基材料的制备及其CO2静态吸附应用

烟道气脱碳一直是降低碳排放的重点,由于现行技术的不完备与工艺的复杂性,烟道气脱碳效果与经济性还不是很理想.利用固体废弃物鸡蛋壳制备了钙基吸附材料的前驱体,通过吸附实验发现其有一定的吸附性能,且煅烧后的产品吸附性能明显提高.同时利用单因素实验考察了吸附温度、吸附时间以及循环次数对二氧化碳吸附的影响.结果表明:在600℃条件下,吸附反应30 min可达到理想吸附效果,循环使用5次仍具有较好的吸附性能.     

高镍三元正极材料表面碱性物质研究进展

高镍三元正极材料表面形成的碱性物质容易导致电池容量衰减加快、寿命缩短,因而调控三元材料表面碱性物质对于提高锂离子二次电池的功能和安全性至关重要。综述了高镍锂离子电池三元正极材料表面碱性物质的形成机理及处理手段,从不同角度阐述了环境中的水、二氧化碳对表面碱性物质形成的影响。探讨了表面碱性物质形成过程中,由于锂离子和过渡金属的迁移与固化引发的表面结构的相变现象,造成了三元正极材料的加工储存性能的恶化。还对降碱工艺中的洗涤、干燥、低温烧结等过程进行了重点说明,阐述了洗涤工艺对三元材料表面碱性物质降低及对材料性质的影响,指出需选择合适的洗涤、干燥条件,减小材料表面发生的变异。最后结合目前降碱工艺对后续研究方向提出了建议。     

碳酸锂在水和NaCl-KCl溶液体系中溶解度的在线测定

碳酸锂溶解度在工业结晶生产中是十分重要的基础数据。采用浸入式红外探头和拉曼探头在线监测溶液体系中CO₃^2-和碳酸锂的特征峰峰强的变化,依据Lambert-Beer定律得出溶液体系中实时在线测定碳酸锂的溶解度。通过在线测定,测得碳酸锂在氯化钠-氯化钾溶液（c_NaCl=0.446 6 mol/L,c_KCl=0.015 8 mol/L）中的溶解度高于在水中的溶解度值。实验测试出的水中碳酸锂的溶解度数据还能与Van′t Hoff方程较好地关联,进一步测算碳酸锂在其他温度下水中的溶解度值。此外,该方法测定的碳酸锂在水中的溶解度数据比文献值中采用重量分析法测试出的溶解度数据偏小,是因为测试装置不同造成的。     

基于储能型柔性多状态开关的直流微电网与交流配电网柔性互联策略

柔性多状态开关大多采用"刚性"的变流控制策略,导致其端口惯性与阻尼不足,直流微电网通过其接入时难以与交流配电网进行柔性互联,无法响应交流配电网调频调压.为此,提出一种基于储能型柔性多状态开关的直流微电网与交流配电网柔性互联策略,交直流端口统一采用虚拟电机控制,通过模拟电机的惯性和阻尼特性使交直流端口呈现柔性特性,同时针对馈线负荷不均衡问题提出一种考虑直流微电网功率交互的负荷均衡策略.仿真结果表明,所提策略能够降低直流微电网波动对交流配电网的冲击,增强直流母线电压的稳定性,主动响应交流配电网调频调压,实现了馈线负荷均衡,提升了柔性多状态开关的调控灵活性.