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41.
42.
Syed Safdar Ali Khalid Mohammed Khan Hartmut Echner Wolfgang Voelter Mashooda Hasan Atta-ur-Rahman 《Advanced Synthesis \u0026amp; Catalysis》1995,337(1):12-17
Two new synthons, Fmoc-L-Arg(biphenyl-4-sulphonyl)-OH ( 8 ) and Fmoc-Arg(4-methoxy-3-t-butylbenzenesulphonyl)-OH ( 14 ), are prepared for the synthesis of arginine-containing peptides. These groups are cleaved by commonly employed trifluoroacetic acid and methanesulphonic acid. Kinetic studies reveal that extended bicyclic aromatic conjugation, as in biphenyl, slightly improves the acid lability compared to the electron-donating t-butyl group. 相似文献
43.
Industrialization has led to a number of environmental problems, such as release of toxic metals and other toxic organic and inorganic compounds to the environment. Among all, the rapid expansion of leather related industries in Pakistan have resulted in considerable environmental problems and effluents from processing of both domestic and imported hides and skins have increased pollution to alarming levels. Some tannery effluents of Peshawar area investigated in the present study showed high concentrations of Cr(Ⅵ) (2.7-12.6 mg/L), Cu(Ⅱ) (2.6-11.4 mg/L) and phenol (0.1-4.2 mg/L). These contaminants are very toxic and must be removed from effluents before releasing into water bodies. A new technique of gamma irradiation has been investigated to decrease the load of COD and concentrations of Cr(Ⅵ), Cu(Ⅱ) and phenol associated with tannery effluents to the permitted values. It was observed that concentration of Cr(Ⅵ) in the effluents can be brought to the permitted level by applying radiation dose of 3 kGy. A radiation dose of 2.5 kGy was required to remove more than 95% of Cu(Ⅱ) and 100 % degradation of phenol in tannery effluents could be achieved by only one kGy of radiation dose. 相似文献
44.
Hypocholesterolaemic effect of yoghurt containing Bifidobacterium pseudocatenulatum G4 or Bifidobacterium longum BB536 总被引:4,自引:0,他引:4
The effect of a yoghurt supplement containing Bifidobacterium pseudocatenulatum G4 or Bifidobacterium longum BB536 on plasma lipids, lipid peroxidation and the faecal excretion of bile acids was examined in rats fed a cholesterol-enriched diet. After 8 weeks, the rats in the positive control (PC) group who were fed the cholesterol-enriched diet showed significant increases in plasma total cholesterol (TC), low-density lipoprotein (LDL) cholesterol, and malondialdehyde (MDA). However, groups fed a cholesterol-enriched diet supplemented with yoghurt containing B. pseudocatenulatum G4 or B. longum BB536 had significantly lower plasma TC, LDL-C, very-low-density lipoprotein (VLDL) cholesterol, and MDA than had the PC group after 8 weeks of treatment. In addition, faecal excretion of bile acids was markedly increased in the rats fed the yoghurt containing B. pseudocatenulatum G4 or B. longum BB536 as compared to the PC and NC groups. 相似文献
45.
Bogdan M. Leu Hasan Yavaş Innokenty Kantor Vitali B. Prakapenka 《Journal of the American Oil Chemists' Society》2010,87(12):1517-1520
We measured the velocity of sound in olive oil under pressure with the Brillouin light scattering technique. Using the values
for the density and the thermal conductivity that have only recently been reported, we calculated the adiabatic compressibility
and the isobaric specific heat up to 356 MPa and the thermal diffusivity up to 200 MPa. The specific heat displays a maximum
at 124 MPa, suggesting a possible phase transition around this pressure. Apart from the theoretical and practical importance
of these results for the food industry and beyond, this work shows that Brillouin light scattering and macroscopic methods
are complementary and can be employed to measure thermophysical parameters of food liquids under pressure. 相似文献
46.
Hüseyin Çelikkan A. Elif Sanli Hasan Aydin M. Levent Aksu 《Journal of Applied Electrochemistry》2009,39(9):1525-1533
This study was carried out to investigate the electrochemical behavior of boron tribromide in dimethlyformamide. The reduction
of the compound was found to follow a CE mechanism. The kinetic parameters and the diffusion coefficient were calculated by
the use of ultramicrodisc electrodes and chronoamperometry. The number of electrons transferred was found to be 2 by rotating
disc and ultramicro disc electrodes and 3 by coulometry. These results are in good accordance with those obtained from molten
boron salts. This study is important in regard to electrochemical boronizing at low temperatures. 相似文献
47.
M. Schulz R. Moshammer M. Dürr A. Hasan M.F. Ciappina 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2009,267(2):187-191
Recent developments on kinematically complete experiments on basic atomic fragmentation processes are reviewed. Comparisons between theoretical and experimental fully differential cross sections for single ionization of light atoms by charged particle impact are analyzed. Furthermore, a method developed very recently, four-particle Dalitz plots, is discussed in context of double ionization. The extraordinary power of these plots is their capability to provide a comprehensive picture of the momentum exchange between all four final-state particles in a single spectrum. 相似文献
48.
Sobia Noreen Sara Hasan Shazia Akram Ghumman Syed Nasir Abbas Bukhari Bushra Ijaz Huma Hameed Huma Iqbal Afeefa Aslam Mervat Abdelaziz Mohamed Elsherif Shazia Noureen Hasan Ejaz 《International journal of molecular sciences》2022,23(5)
The rapid progression in biomaterial nanotechnology apprehends the potential of non-toxic and potent polysaccharide delivery modules to overcome oral chemotherapeutic challenges. The present study is aimed to design, fabricate and characterize polysaccharide nanoparticles for methotrexate (MTX) delivery. The nanoparticles (NPs) were prepared by Abelmoschus esculentus mucilage (AEM) and chitosan (CS) by the modified coacervation method, followed by ultra-sonification. The NPs showed much better pharmaceutical properties with a spherical shape and smooth surface of 213.4–254.2 nm with PDI ranging between 0.279–0.485 size with entrapment efficiency varying from 42.08 ± 1.2 to 72.23 ± 2.0. The results revealed NPs to possess positive zeta potential and a low polydispersity index (PDI). The in-vitro drug release showed a sustained release of the drug up to 32 h with pH-dependence. Blank AEM -CS NPs showed no in-vivo toxicity for a time duration of 14 days, accompanied by high cytotoxic effects of optimized MTX loaded NPs against MCF-7 and MD-MBA231 cells by MTT assay. In conclusion, the findings advocated the therapeutic potential of AEM/CS NPs as an efficacious tool, offering a new perspective for pH-responsive routing of anticancer drugs with tumor cells as a target. 相似文献
49.
Bemgba B.Nyakuma Aliyu Jauro Segun A.Akinyemi Hasan M.Faizal Mohammed B.Nasirudeen Muhammad Ariff H.M.Fuad Olagoke Oladokun 《国际煤炭科学技术学报(英文)》2021,8(4):697-716
In this study,the physicochemical,microstructural,mineralogical,thermal,and kinetic properties of three newly discovered coals from Akunza (AKZ),Ome (OME),and S... 相似文献
50.
This paper describes a new wind turbine simulator for dynamic conditions. The authors have developed an experimental platform to simulate the static and dynamic characteristics of real wind energy conversion system. This system consists of a 3 kW dc motor, which drives a synchronous generator. The converter is a 3 kW single-phase half-controlled converter. MATLAB/Simulink real time control software interfaced to I/O board and a converter controlled dc motor are used instead of a real wind turbine. A MATLAB/Simulink model is developed that obtains wind profiles and, by applying real wind turbine characteristics in dynamics and rotational speed of dc motor, calculates the command shaft torque of a real wind turbine. Based on the comparison between calculated torques with command one, the shaft torque of dc motor is regulated accordingly by controlling armature current demand of a single-phase half-controlled ac–dc converter. Simulation and experimental results confirm the effectiveness of proposed wind turbine simulator in emulating and therefore evaluating various turbines under a wide variety of wind conditions. 相似文献