A novel method for determining effects of fire damage on the safety of the Type I pressure hydrogen storage tanks

Consumption of the fossil fuels causes greenhouse gas effect and environmental pollution, which are two basic problems of our age. As a result of this problem, clean and renewable alternative energy sources are beginning to replace fossil fuels. Nowadays, the use of hydrogen energy, which is one of the clean energy, is increasing in transportation and industrial areas. Increasing of hydrogen energy usage, scientists are attempting to solve the many safety problems (such as fire, burst, impact and hydrogen embrittlement) that can occur during the storage and consumption of hydrogen energy. In this study, during the event of fire, the safety of metallic Type I pressure hydrogen storage tanks is investigated by using a novel approach. In this new approach, the mechanical strength drops of the tank materials that is related with temperature rising are added to the safety calculations. In the study, 6061 T6 aluminum and SS 316L stainless steel alloys were used as hydrogen tank material. The safety of hydrogen tanks modelled using these alloys was investigated under different temperature conditions (22, 100, 200 and 300 °C) and internal pressure (15, 20 and 25 MPa).     

Experimental study on drying of pear slices in a convective dryer

The experiments were conducted on pear slices with thickness of 5 mm at temperatures of 50, 57, 64 and 71 °C with an air velocity of 2.0 m s^?1. Prior to drying, pear slices were pretreated with citric acid solution (0.5% w/w, 1 min, 20 °C) or blanched in hot water (1 min, 85 °C). Also, the untreated samples were dried as control. The shortest drying time of pear slices was obtained with pretreatment with citric acid solution. It was observed that whole drying process of pear slices took place in a falling rate period. Four mathematical models were tested to fit drying data of pear slices. According to the statistical criteria (R², χ² and RMSE), the Midilli et al. model was found to be the best model to describe the drying behaviour of pear slices. The effective diffusivity of moisture transfer during drying process varied between 8.56 × 10^?11 and 2.25 × 10^?10 m² s^?1, while the activation energy of moisture diffusion in pear slices was found to be 34.95–41.00 kJ mol^?1.     

UV curable lens production using molecular weight controlled PEEK based acrylic oligomer (Ac-PEEK)

We produced UV curable lenses with properties blocking short wave UV light. In the UV-curable formulations, we used an oligomer (Ac-PEEK) with another urethan oligomer (Mw = 2000). Radically active, molecular weight controlled Ac-PEEK was obtained by reacting 2-hydroxyl ethyl methacrylate with molecular- weight- controlled and isocyanate terminated PEEK (Mn = 4500). We characterized all synthesized monomer, oligomer and optical materials with UV/Vis spectrophotometer with interferogram, elemental analyser, mass spectrophotometer, proton nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermal gravimetric analyzer, differential scanning calorimeter, scanning electron microscopy and gas chromatography. Results suggested that newly synthesized oligomer with the structure of PEEK absorbs short wave UV-light. Ageing tests [ISO 11979-5, Ophthalmic implants—intraocular lenses (IOL)—Part 5: Biocompatibility] performed on the IOL materials were successful. High contact angle of the obtained lenses suggests that all lenses were hydrophobic and SEM results revealed that lenses are morphologically homogeneous. Based on all positive properties just mentioned, we safely conclude that the lenses produced in this study are very promising for IOL production.     

A Study on Glutaric Acid Extraction by Tridodecylamine: Equilibria and Models

The extraction of glutaric acid was studied using tridodecyl amine (TDA) with respect to the functional groups of the diluent. The diluents studied were 1‐octanol (alcohol), methyl isobuthyl ketone, MIBK (ketone), and toluene (aromatic hydrocarbon) and these were used to dilute the TDA. The experimental results of batch extraction experiments are reported as distribution coefficients, D_C, loading factors, Z, and extraction efficiency, E. All measurements were carried out at 298.15 K. The results of the liquid‐liquid equilibrium measurements are correlated by a linear solvation energy relationship (LSER) model that takes into account physical interactions and modified Freundlich and Langmuir equations. The experimental results are compared with model results.     

Investigation of current‐voltage characteristics and current conduction mechanisms in composites of polyvinyl alcohol and bismuth oxide

Temperature dependent current‐voltage (I–V) measurements of Au/Polyvinyl Alcohol + Bi₂O₃/n‐Si structure were conducted between 100 and 350 K for investigating the temperature dependence of I–V characteristics and current conduction mechanisms in the structure. Series resistance of the structure is calculated using Ohm's law and Cheungs' method. Ideality factor (n) and zero‐bias barrier height (Φ_Bo) were obtained considering thermionic emission theory. From 100 to 350 K, n changed from 32.1 to 3.54, and Φ_Bo changed from 0.27 to 0.99 eV. Obtained temperature dependent values of n and Φ_Bo suggested that thermionic emission is not the dominant current conduction mechanism. Therefore, Ln(I)–Ln(V) curves of the studied structure were plotted for investigating current conduction mechanisms in the structure and current flow is explained considering space charge limited current. Moreover, density of interface states (D_it) in the structure were calculated and its temperature dependence was investigated such that D_it values are reduced to the order of ～10¹³ eV^?1 cm^?2 from ～10¹⁴ eV^?1 cm^?2 with increasing temperature. POLYM. ENG. SCI., 54:1811–1816, 2014. © 2013 Society of Plastics Engineers     

A Review of Dehydration of Various Industrial Sludges

Wastewater characteristics and sludge generation potential of point source categories are reviewed critically. Novel industry-specific sludge dewatering/drying solutions necessary to establish a sustainable model are examined through a detailed literature survey. Knowledge of sludge properties is one of the most critical issues needed to design dewatering/drying equipment. This study focuses on industrial wastewater/sludge characterization. In addition, a comprehensive review of current drying models and technologies is also presented. A summary of the results derived from a novel thin-film-based photonic sludge dewatering/drying study is outlined as an alternative approach for industrial sludge control. Sludge was dried in a tubular quartz reactor (TQR), the inner surface of which was coated with a TiO₂ thin film. The TQR was irradiated with UV A, UV B, and UV C lamps. The consumed and generated energy fluxes through endergonic and exergonic reactions driven by photolysis and photocatalysis were investigated. In addition, the variations in sludge dewatering/drying characteristics were also examined and compared with conventional methods to evaluate the energy requirements.     

Poly(azomethine-imide)s containing siloxane moities: Optical,thermal, mechanical,and morphological properties

A new series of poly(azomethine-imide)s having siloxane moities in backbone was prepared using different dianhydrides.Thermal, optical, and morphological properties of these polymers were clarified. Also, bulky  CO and  CF₃ group effects and meta or para-substituted aldeyhde effects on the mentioned properties were evaluated. The structural characterization of poly(azomethine-imide)s was carried out using a FT-IR spectroscopy. The optical properties of the polymers were performed via an UV–Vis spectrophotometer. Optical band gap of the poly(imide)s containing azomethine was calculated between 2.20 and 2.33 eV. Thermal behavior of poly(azomethine-imide)s was also studied using TG-DTA, DSC, and DMA techniques. The onset degradation temperature and percentage char values of the polyimides were found in the range from 429 to 545 °C and 22 to 35%, respectively. Thermal stability results demonstrated that benzophenone bearing poly(azomethine-imide)s have higher onset temperature, percentage char, and the glass transition temperature than poly(azomethine-imide)s derived from hexafluoroisopropylidene. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48364.     

The Effects of Heat Treatment on Some Mechanical Properties of Juvenile Wood and Mature Wood of Eucalyptus grandis

Heat treatment is a well-known method for modifying wood that is applied in different ways, and treatment schedules change from tree to tree. This treatment improves the physical properties of wood but, in general, it reduces the mechanical properties of wood. The effects of heat treatment on the mechanical properties of juvenile and mature wood of the same tree species have not been well-defined. Therefore, we focused our study on the differences in the mechanical properties of juvenile wood and mature wood of Eucalyptus grandis after both were subjected to heat treatment. Wood samples were treated at temperatures of 120, 150, and 180°C for 4, 6, and 8 h. The test results showed that decreases in the mechanical properties of juvenile wood (e.g., modulus of elasticity (MOE), modulus of rupture (MOR), compression strength (CS), and impact bending (IB)) were greater than the decreases that occurred in mature wood that was heat treated at the same conditions.     

Competitive adsorption of uranyl ions in the presence of Pb(II) and Cd(II) ions by poly(glycidyl methacrylate) microbeads carrying amidoxime groups and polarographic determination

The adsorption capacity of UO in the presence of Pb(II) and Cd(II) ions was investigated with amidoximated poly(glycidyl methacrylate) (PGMA) microbeads with an average size of 135 μm packed in a glass column (0.5‐cm i.d. and 20‐cm length, flow rate = 3 mL/min) under competitive conditions. A differential pulse polarography technique was used for the determination of trace quantities of uptaken elements by the measurement of the reduction peak currents at ?200/?950, ?400, and ?600 mV (vs a saturated calomel electrode) for UO, Pb(II), and Cd(II) ions, respectively. When only UO was found in the eluate, its adsorption was 85.3% from a 50 μM initial solution. However, when there was UO with binary systems of Pb(II) or Cd(II), it was 78.2 and 76.3%, respectively. On the other hand, in a ternary mixture of UO with Pb(II) and Cd(II), the adsorption was found to be 75.2% with the same initial concentration. According to the results, the competitive adsorption studies showed that these amidoximated PGMA microbeads had good adsorption selectivity for UO with the coexistence of Pb(II) and Cd(II) ions. The ionic strength of the solution also influenced the UO adsorption capacity of the amidoximated PGMA microbeads. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 4168–4172, 2007