二元稀土系AB5型贮氢电极合金的放电容量与晶胞体积和4f电子浓度的关系

制备了6个系列通式为AαA‘1-αB5的RE(NiCoMnTi)5贮氢电极合金(其中,AαA‘1-α为La,Ce,Pr,Nd4个元素中任意2个的组合),测定了它们在100次循环中的最大放电容量Cmax及部分合金的晶胞体积Vcell．结果表明：Cmax主要由Vcell决定,Cmax先随Vcell的增大而增加,在Vcell≈85．66x10^-^3。nm^3时达到一极大值,然后又随Vcell的增大而减小;同时,Cmax还与4f电子浓度ne4f／naRE有关,A侧具有相同4f电子浓度的合金其Cmax随4f电子浓度的变化趋势相似．     

Electrochemical properties of AB5 type hydrogen storage alloy as anode electrocatalyst of PEMFC

1　INTRODUCTIONIn recent years, the application of the roomtemperature type ( < 100 ℃) polymer electrolytemembrane fuel cells(PEMFCs) as a primary powersource in electric vehicles and portable equipmentsetc has received increasing attention[1 4]. Usuallyin a PEMFC system, platinum is chosen as the e lectrode electrocatalyst, however, it results in ahigh cost PEMFC system for commercialization be cause Pt is a high cost, source limit metal. So,looking fo…     

Electrochemical properties of CeMg_(11)Ni+x% Ni composites (x=0,50, 100 and 200) prepared by ball-milling

1　INTRODUCTIONMagnesium and magnesium based alloys arepromising hydrogen storage materials because oftheir absorbability of hydrogen in large quantities,low specific gravity, rich mineral resources, lowmaterial cost and so on. Nevertheless, their hy drides are too stable to be used at room tempera ture[1]. It seems impossible for application of crys talline Mg based alloys in nickel hydrogen batter ies.It is well known that amorphous alloys havemany advanta…     

Electrochemical properties of CeMgu Ni＋x% Ni composites （x=0, 50, 100 and 200） prepared by ball-milling

The electrochemical properties of the as-cast CeMg11 Ni and ball-milled CeMg11 Ni x%Ni(x=0, 50,100 and 200, mass fraction) composites were investigated. The results show that homogeneous amorphous phase of CeMg11 Ni x% Ni composite can be obtained by ball-milling, and discharge capacity of the ball-milled CeMg11 Ni x% Ni composites differs greatly depending on the amount of Ni introduced during milling. The CeMg11 Ni 200% Ni composite after 90 h ball-milling was found to exhibit a large discharge capacity of about 1 012 mAh/g at 303 K,and it also shows better charge-discharge cycling stability than those with lower Ni content. This remarkable improvement in electrochemical properties of the ball-milled composites seems to be attributed to the formation of an amorphous composite as well as the improvement of the surface state of the ball-milled particles.     

动力换挡变速器挡位故障的排除

以TY220型推土机为例,挡位故障一般有4种. 1.缺挡 缺挡是指某一挡或某几挡没有,而其他挡是正常的.如缺Ⅰ挡,即是前进Ⅰ挡和后退Ⅰ挡都没有,而其他挡位正常;若缺前进挡,则是前进各挡都没有,而后退各挡都正常;若缺Ⅱ挡,则是前进和后退Ⅱ挡都没有,而其他各挡都是正常的等等.     

环己酮废碱焚烧运行成本模拟方法及应用

通过反平衡法计算废碱焚烧炉热效率、产汽量及可变成本,建立了废碱焚烧运行成本模型,并计算分析了可变成本与燃料类型、组成、投碱量、尾气含氧量等因素的关联性。结果表明:随着混合燃料中干气比例提高,可变成本下降;仅使用辅助燃料渣油时,随着渣油量增加,可变成本不断增加,并出现加速拐点,急速增加;仅使用干气作辅助燃料时,随着干气量增加,投碱量减少,可变成本不断降低,并出现加速拐点,急速下降;随着尾气含氧量增加,锅炉的燃烧效率不断下降,可变成本不断增高;针对干气充足、干气不充足以及全部使用燃料油时,提出了相应的经济运行模式,并将其应用于指导生产,经济效益明显。     

万吨级可发性聚苯乙烯开发的研讨

从国内外EPS工艺对比出发,提出了改造我国二步法现行工艺的六项建仪,并对万吨级EPS一步法的开发,展开了工艺、工程等方面的论证。     

RFI用改性双马树脂膜的黏度特性

采用热塑性树脂改性双马来酰亚胺树脂,获得了适用于RFI成型的改性双马来酰亚胺树脂膜。采用DSC方法和黏度测试研究了该树脂的固化特性和黏度特性,并根据黏度特性建立了Arrhenius模型。结果表明,改性双马来酰亚胺树脂膜的黏度特性能够满足RFI工艺的要求,建立的Arrhenius模型能够较好地预测黏度特性,可为RFI工艺参数的制定提供理论指导。     

快速凝固MlNi4．0 Al 0．3 Si 0．1 Fe0．6无Co贮氢电极合金的微结构和电化学性能

研究了单辊快淬快速凝固处理对无Co贮氢电极合金MlNi4．0Al0．3Si0．1Fe0．6的微结构和电化学性能的影响。XRD分析表明，快凝合金仍为单相CaCu5型结构，但合金相的成分和结构均匀性得到明显改善。金相观察和能谱分析显示，铸态合金为比较粗大的树枝晶结构并存在明显的成分偏析，而快凝合金呈细小的胞状晶结构，合金中元素的分布趋于均匀化。电化学测试表明，快速凝固处理后合金的活化性能不变，循环稳定性得到显著改善，但其放电容量和高倍率放电性能有所降低。研究发现，快凝合金电极的交换电流密度Io以及氢在合金中的扩散系数D较铸态合金有所减小是导致其高倍率放电性能降低的主要原因。快速凝固处理导致无Co合金电化学性能的变化与合金的微结构的改变有关。     

稳定变应力下疲劳强度的可靠性设计

本文根据可靠性设计理论，对疲劳强度的可靠性设计计算方法进行了分析，并给出了设计实例。