剪切变形方向特征对高纯铝箔轧制织构的影响

运用取向分布函数(ODF)研究了每个轧制道次的剪切变形特征对高纯铝箔轧制织构的影响.提出用中性角的相对大小来量化轧制剪切变形作用方向改变的位置,运用Taylor晶体塑性变形理论模拟计算了中性角的相对大小对轧制织构演变的影响.实测与模拟的轧制织构特征表明:中性角靠近轧制变形区的中心位置有利于形成{001}<110>剪切织构,从而证实了除剪切变形的程度外,剪切变形方向改变的位置也是影响高纯铝箔轧制织构的重要因素.     

Hot-compression behavior of Al-1Mn-1Mg alloy

The hot-compression of Al-1Mn-1Mg (mass fraction, %) alloy sample was carried out on a Gleeble-1500 thermo-simulator at deformation temperatures from 320 to 400 ℃ and strain rates from 0.1 to 10 s-1 by total strain of 1.4. Microstructure and texture evolution of the hot-compressed alloy were investigated by optical microscopy and X-ray diffraction analysis, respectively. The results show that the relationship among flow stress σ, deformation temperature T and strain rate ε can be expressed in the form of βσ...     

Corrosion resistance of cerium conversion film electrodeposited on Mg-Gd-Y-Zr magnesium alloy

The cerium conversion film was applied to improving the corrosion resistance of Mg-Gd-Y-Zr magnesium alloy. The film was electrodeposited on the surface of the Mg-RE alloy in cerium nitrate solution. The compositions and morphologies were analyzed by X-ray diffraction(XRD), scanning election microscopy (SEM). The corrosion behaviors of the film were investigated electrochemical impedance spectroscopy (EIS), potentiodynamic polarization tests and immersion tests. The results show that the optimum parameters for electrochemical deposition are as follows: pH 10.0, time 30 min, 50 mmol/L Na₂CO₃ and temperature 25 °C by the designed experiments according to the orthogonal table L(9, 3⁴). The corrosion protection efficiency is dependent on the deposition parameters. The cerium conversion film shows better corrosion protection behavior than chromate conversion film on Mg-Gd-Y-Zr magnesium alloy. Foundation item: Project (5133001E) supported by the Major State Basic Research and Development Program of China     

微量Zr对Al-5.8Cu-0.3Mn合金焊接接头组织与性能的影响

采用4047焊丝对Al-5．8Cu-0．3Mn铝合金进行熔化极惰性气体保护焊，利用金相显微镜、透射电镜、显微硬度等检测分析手段研究了Zr对Al-5．8Cu-0．3Mn母材及焊接接头的力学性能和显微组织的影响。结果表明，Al-5．8Cu-0．3Mn合金中添加适量Zr元素可使母材强度提高30MPa，焊接接头强度提高50MPa，同时，细化了母材的再结晶组织和焊缝组织。焊接接头的强度低于母材强度，焊缝区是合金的薄弱处，热影响区强度降低是θ‘相粒子受热粗化所致。     

深冲铝板中的再结晶织构与选择生长

利用电子显微分析（TE）和ODF织均分析，研究了纵横轧制铝板再结晶退火前后的织构和再结晶过程．直接观察到再结晶过程中的选择长大，经电子衍射分析了新晶粒的取向，并通过极图分析了各织构组分＜111＞间的关系结果表明，纵横轧制铝板再结晶过程中存在选择生长现象，并最终决定再结晶织构；面心立方金属中这种取向关系约为40°＜111＞     

BK992萃取除铜净化硫酸镍钴溶液

以BK992为萃取剂,从废镍合金硫酸溶液中萃取分离铜,研究了pH值、相比(O/A)、BK992浓度和萃取时间对萃取的影响,确定了BK992萃取铜的优化条件.结果表明:BK992的萃铜速度很快,随着pH值升高,铜萃取率增大,但当pH大于4.0时,镍钴损失较大;相比越大,萃取分离效果越好;BK992浓度的影响也较大,随着BK992浓度增加,铜分配比增大.室温下BK992萃取铜的最佳工艺条件:BK992浓度为20%,相比O/A为1:2,水相初始pH为3.0,萃取时间为10 min.在优化条件下,待处理液的一级萃取率达93.06%,20%BK992萃铜的饱和容量为17.30 g/L;一级反萃率达91.79%,铜净传递量为15.88 g/L.     

Mechanism of strengthening of cube texture for high purity aluminum foils by additional-annealing

1　INTRODUCTIONHighpurityaluminumfoilsareusedastheanodematerialofhighvoltageelectrolyticcapacitorswhichneedstrongcubetexture { 0 0 1}〈10 0〉forlargeeffec tivesurfacefromchanneletching[1] .Becauseofitstechnicalimportance ,alotofeffortshavebeenmadetodevelopstrongcubetextureinhigh purityalu minumfoils[2 8] .Itwasfoundthatthecubetextureinthefoilscanbestrengthenedviaanannealingpro cessfollowedbyalowcoldrolling[7,8] ,andsuchanannealingiscalledadditional annealinginthispaper .Buttherewerefewinv…     

铁含量及退火对高纯铝箔再结晶织构的影响

采用晶体取向分布函数 (ODF)、TEM研究了铁含量及退火对高纯铝箔再结晶织构的影响。结果表明 ,铁含量越高 ,立方织构越少 ,R织构越多。铁含量较少时 ,在成品退火的低温阶段 ,形成回复亚晶组织 ;高温退火时 ,在晶内析出含铁化合物 ,形成强烈的再结晶立方织构 ,R织构取向密度很小 ;铁含量较多时 ,无论采用何种退火工艺 ,再结晶织构中立方取向都较弱 ,而R取向都较强     

基于模糊综合评判的模具拉深工艺研究

研究模糊数学在模具设计中的应用,重点分析模糊数学中模糊综合评判原理应用于模具的拉深工艺,以筒形件为例分析影响筒形件拉深的主要因素--极限拉深系数,提出影响极限拉深系数的模糊可调因素和不可调因素,分析每个可调因素的原理和模糊划分的根据,总结和改进了前人研究的一些经验和技术并作出相应的变化,并且此过程能够通过CAPP程序实现.     

Synthesis and characterization of LiNi0.45Co0.10Mn0.45O2 cathode for lithium ion batteries

1INTRODUCTIONAdvanced rechargeable lithium ion batteriesare attractive for use in consumer electronic andelectric vehicle(EV)application because of a fa-vorable combination of voltage,energy density,cycling performance,and have been developed rap-idly worldwide during the past decade[1,2].LiCoO2has been widely used as a cathode material in com-mercial lithiumion battery because it is reasonableeasy to synthesize and shows a stable discharge ca-pacity[3].But due to its high cost and toxic…