高阻相对La2／3Ca1／3MnO3低场磁电阻效应的影响

实验研究了La2／3Ca1/3MnO3系统晶界上掺杂(YSZ)对其输运性能和磁电阻效应(MR)的影响。样品是由溶胶．凝胶法制成的。通过对样品的电输运特性的测量表明,在掺杂量(x)低于2％时,掺杂引起电阻的增大并降低了金属．绝缘体转变温度;当掺杂量高于2％时电阻逐渐减小,且转变温度增加。而低场磁电阻效应随掺杂量增加,在x=1％时达到最大。     

Fe76.5Cu1Si13.5B9非晶合金晶化过程的X射线衍射研究

Fe_(76.5)Cu_1Si_(13.5)B_9非晶合金在晶化过程中析山的α-Fe固溶体(α相)的X射线衍射峰存在不对称性并随退火温度而变化,对α相衍射峰进行分峰拟合证实,Cu原子可以促进α相形核并固溶其中,合金晶化与原始态中残存晶核无关,α相晶粒中Cu含量的不同导致衍射峰的不对称性,键合能准化学近似计算结果表明,Cu原子降低了周围原子的迁移势垒,导致合金的晶化首先在含Cu量较高的区域开始,使晶化温度降低。     

冷轧取向硅钢片的织构与磁感应强度的定量关系

一、前言冷轧取向硅钢片有两个主要性能参数,即磁感应强度和铁损。测量磁感强度一般采用艾布斯坦方圈,这种方法在工业生产中被广泛采用。然而测得的磁感应强度实际上是一个平均值,与某块样品的实际情况可能有差距。精确的测定方法是采用单片或双片测磁,但是这种设备在很多单位不一定具有。在研究冷轧取向硅钢片成品织构时,由于晶粒粗大,一般采用X射线劳埃法或腐蚀坑法,逐个测出每个晶粒的取向。在研究织构之后,有时还需要知道其磁感应强度。本     

板材轧制问题中的变形与应力

根据全息干涉法对板材轧制成形中的变形进行分析，假设三种典型轧制板的截面形状模型，计算了纵向非均匀应变分布，给出了其所产生的残余应力及其失稳起皱时的临界参数计算公式。与实测结果比较，变形的最大误差为11％。     

NdFeB磁体的二次化学镀耐蚀性能

研究了NdFeB磁体表面超声波化学镀和二次化学镀Ni- P合金的耐腐蚀性，用扫描电子显微镜和X射线衍射仪分析了镀层的组织结构，结果表明，该工艺制备的镀层明显地提高了NdFeB磁体的耐蚀性能.     

干混合对硬质合金组织结构的影响

采用扫描电镜,通过对WC原料粉末、脱蜡压坯断口与表面、合金抗弯强度样品断口与合金烧结体表面微观形貌以及合金金相组织的观察,研究了干混合对硬质合金组织结构的影响。结果表明,干混合只对压坯成形过程中粉末颗粒的压制行为与烧结过程中合金的致密化行为产生影响,不会对烧结过程中的合金化行为产生影响。压坯中的大孔洞与未压好等压制缺陷以及显著的元素分布不均匀现象难以通过液相烧结得到有效消除,会继续保留至合金中。采用干混合工艺制备合金,合金晶粒均匀、粗大,接近原料粉末的电镜观测粒度。     

热带粗轧机组立轧稳定轧制变形规律的实验研究和有限元分析

本文采用铅作为模拟材料，对热带粗轧机组平辊立轧变形规律进行了实验研究，得到了表征立轧稳定轧制阶段时轧件断面特征的四个参量与侧压量、立辊直径、板坯来料厚度及宽度之间的关系。并首次提出用超薄单元近似处理奇异点的新方法，采用全三维刚塑性可压缩有限元法对立轧稳态过程进行了理论解析，所得结果和实验结果符合较好。     

XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue

During bio-oxidation of sulfides, the chemical state change of sulfur is a complex and key factor. It is not only an indicator of the extent and intensity of the bio-oxidation, but also controls the property of bio-leaching medium and the period of oxidation. The chemical state of sulfur in sulfides oxidized by leaching bacteria was studied with XPS. Sulfide minerals in the arsenic-bearing gold concentrate consist of pyrite, arsenopyrite, chalcopyrite, galena, sphalerite and so on. In order to probe the pattern of the chemical state change of sulfur in the bio-oxidation residue of arsenic-bearing gold concentrate, the structure of the grains, and the surface nature of the residue, XPS test was carried out through different sputtering duration. The study of XPS clearly shows that: sulfides is progressively oxidized from the surface of minerals to the core by leaching bacteria; the chemical valence of sulfur changes from S^2- or [S2]^2- to [SO4]^2- ; sulfur in the core is in a reduction state, S^2- or [S2]^2- , but exists in an oxidation state S^6 on the surface; due to the chemical state change of sulfur, mineral phase of the bio-oxidation residue is also changed(sulfides inside, while sulfates outside); the layered structure is found in the grains of the bio-oxidation residue.     

Friction welding of TiAI intermetallics and structural steel by applying Inconel 718 as interlayer

Inconel 718 with thickness ranged from 0. 1 - 1.7 mm was chosen as interlayer to promote weldability in friction welding of TiAl intermetallics and structural steel such as AIS14140, in which the welded joint presents single fin showing less welding deformation on TiAl side. The correlations between tensile strength and the interlayer thickness were analyzed and fitted to a model. It indicates an optimum interlayer thickness ranged from 0.9 - 1.1 mm where the tensile strength reaches as high as 360 MPa. Otherwise, while the interlayer thickness decreases to 0. 1 mm, brittle compounds of TiC, Al2Ti4C2 and MTC3 are formed in the welded zone so that the tensile strength decays. Thicker interlayer should be also avoided as double joints may occur at TiAl -lnconel 718 and lnconel 718 -AISI 4140, respectively, which lowers the tensile strength to some extent.     

热带粗轧机组立轧变形规律研究

以铅为模拟材料，对热带粗轧机组平辊立轧变形规律进行了实验研究，分析了稳定轧制阶段表征立轧时轧件断面特征的４个参量，及非稳定轧制阶段头、尾部最大狗骨高度非稳定行为，失宽行为，鱼尾长度与立辊直径、侧压量、板坯来料厚度及宽度之间的关系，并建立了新的数学模型．