Upconversion Emission in Er^3＋ Doped Novel Bismuthate Glass

Novel Er3 -doped bismuth lead strontiam glass was fabricated and characterized, and the absorption spectrum and upconversion spectrum of the glass were studied. The Judd-Ofelt intensity parameters Ωt (t=2, 4, 6) were found to be Ω2＝3.27×10-20 cm2, Ω4＝1.15×10-20 cm2, and Ω6＝0.38×10-20 cm2. The oscillator strength, the spontaneous transition probabilities, the fluorescence branching ratios, and excited state lifetimes were also measured and calculated. The upconversion emission intensity varies with the power of infrared excitation intensity. A plot of log Iup vs log IIR yields a straight line with slope 1.86, 1.88 and 1.85, corresponding to 525, 546, and 657 nm emission bands, respectively, which indicates that a two-photon process for the red and green emission.     

P2O5-BaO-Nb2O5三元系统玻璃的形成及性能的研究

研究P     

单光束扫描法测量掺染料硫堇(Thionine)有机改性凝胶材料的光学非线性折射率

用溶胶凝胶法制备了掺染料硫堇（Ｔｈｉｏｎｉｎｅ）的有机改性凝胶材料，利用单光束扫描法（Ｚ－ｓｃａｎ）测试样品的光学非线性折射率，获得的ｎ２值约为４×１０－７ｅｓｕ，对实验结果的分析表明，材料的非线性折射来源于有机染料的离域π电子效应     

Tm3+-Yb3+共掺氧氟硅酸盐玻璃热学性能和上转换发光特性研究

稀土掺杂氧氟玻璃是一种优良的上转换发光材料,制备了组分为35SiO2-15AlO1.5-(45-x)PbF2-xCdF2-0.1TMF3 -1.5YbF3 (x = 0,10,20,30)的氧氟硅酸盐玻璃,系统研究了CdF2含量对其热学性能和光学性能的影响.研究表明用CdF2部分替代PbF2可以提高玻璃的热稳定性、使紫外吸收截至边向短波方向移动;随着CdF2含量的增加,开始TM3+蓝光和红光上转换发光增强缓慢,而后迅速增强,而近红外上转换发射先显著增强后增强放缓;由于蓝光和近红外发光强度远大于红光发光强度,所以该氧氟玻璃更适合于蓝光和近红外发光材料.最后,探讨了TM3+的上转换发光机理.     

脉冲氙灯用新型复合石英玻璃管性能的研究

为了研制出满足大功率脉冲氙灯技术要求的管壁材料,使用石英玻璃管二步法制备工艺,采用分层制砣技术,把纯石英玻璃和掺铈石英玻璃密切熔合,研制出新型的复合石英玻璃管.研制了几种不同复合比例的复合石英玻璃管,并对其光谱性能和机械性能进行了测试.通过对比实验表明,当纯石英玻璃层和掺铈石英玻璃层的比例合适时,复合石英玻璃管不仅具有吸收小于320 nm波长的紫外辐射的性能,而且具有比掺铈石英玻璃管更高的机械强度和抗冲击性能,满足了大功率脉冲氙灯对管壁材料的特定要求.采用复合石英玻璃管制备的大功率脉冲氙灯具有优良的抗冲击性能、高的负载能量和与钕玻璃匹配的辐射光谱特性,能很好地满足大型激光器对脉冲氙灯的要求.     

用于WDM系统的掺稀土玻璃光纤

作为新的光纤放大器增益介质，掺稀土玻璃光纤近年来在WDM传输系统中发展迅速。在介绍了玻璃光纤用作光纤放大器增益媒质优点的基础上，综述了目前掺稀土玻璃光纤研究的要点、种类、性能及其应用实例。     

铒镱共掺磷酸盐玻璃的激光性质

制备了镱铒共掺的磷酸盐玻璃并研究了室温下LD泵浦的连续激光输出性质.在泵浦功率为496 mW时实现了最大输出功率77 mW.讨论了在不同玻璃样品厚度和谐振腔长度时的斜率效率的变化以及在不同玻璃样品厚度,泵浦功率和谐振腔长度时的不同激光模式竞争的动力学行为.结果表明:激光光谱受到光学增益和光学损耗相对大小的限制.     

掺钕材料激光终态能级寿命测量

介绍了目前测量掺钕材料激光终态能级寿命的三种方法,通过对三种测量方法比较,采用间接法测量激光终态能级寿命相对简单易行。     

高分子基体的固体染料激光器的制备和研究

制备了用于固体染料激光器的高分子共聚物基体 ,研究了两种激光染料 Rhodamine- B(Rh-B)和 Pyrromethene597(PM- 597)在高分子基质中的光谱性质。以调 Q的 Nd:YAG激光器的倍频光为抽运光源 ,在无外加谐振腔的条件下 Rh- B和 PM- 597掺杂的高分子基体中获得了高转换效率和大能量激光输出 ,可为固体染料激光器的实用化提供关键工作物质     

Energy transfer between Gd^3＋ and Tb^3＋ in phosphate glass

The phosphate glass doped with Gd3+,Tb3+ and Gd3+/Tb3+ were prepared by high temperature melting.The photo-luminescence behavior of Gd3+ and Tb3+ in phosphate glass were investigated by absorption,excitation,and emission spectroscopy.Energy transfer between Gd3+ and Tb3+ in phosphate glass was studied,and it was found that there were two energy transfer mechanisms between Gd3+ and Tb3+ in phosphate glass: one was from 4f7 level of Gd3+ to the 4f8 level of Tb3+,and the other was from 5d level of Tb3+ to 4f7 level of Gd3+.The new findings would be beneficial for the study of Tb3+-doped scintillating phosphate glass.