Increasing ethylene production as a high value hydrocarbon in Fischer-Tropsch (FT) reactor: A concept reactor for combining FT with oxidative coupling of methane

The paper proposes a concept configuration of reactors for coupling OCM and FTS, and presents systematic simulation results. FTS section is a combination of fixed bed and membrane fluidized bed reactor, and feed of the FT reactor is supplied by OCM. The reactor configuration is compared with the consecutive reactors of OCM and one fixed bed FT reactor. Effects of CH₄/O₂ ratio, percent of N₂ in the feed, contact time, and input temperature on the yield of ethylene and valuable hydrocarbons are studied. The results show that compared with one FTS reactor configuration, the dual FTS reactor configuration is more effective and thus gives much higher product yields. Furthermore, a main decrease is observed in the formation of CO₂ and CH₄.     

Monolayer film behavior of polymers and their mixtures

The monomolecular film behavior of polyvinyl acetate (PVAc), polyethyl acrylate (PEA) and mixtures of these ranging in concentration ratio of PEA to PVAc from 0.008 to 11.301 has been studied using a Langmuir-type filmbalance over an aqueous 0.01N HCl substrate. Hysteresis was observed in the compression–expansion cycle for PVAc. A discussion of polymer–polymer interaction in a mixed monomolecular film at an interface is presented. The extent of this interaction for films comprising PVAc and PEA has been determined in terms of deviations of the film area from the ideal behavior. The data on the film areas of PVAc and PEA are discussed in terms of the molecular orientation of these polymers on the surface. A simple equilibrium thermodynamic treatment is applied to the data on mixed monolayer films. The implications resulting from this study are discussed.     

Quantitative monitoring of terbium ion by a Tb3+ selective electrode based on a new Schiff's base

Solution study showed N,N′-bis(5-nitrosalicylidene)-2-aminobenzylamin (L) trends toward Tb³⁺ ion. Then, it was used as a suitable ionophore in construction of terbium ion selective electrode. The electrode with composition of 30% PVC, 65% solvent mediator (NB), 3% ionophore (L) and 2% anionic additive (NaTPB) shows the best potentiometric response characteristics. It displays a Nernstian behavior (20.1 mV decade^?1) over the concentration range 1.0 × 10^? 6 to 1.0 × 10^? 2 mol L^?1. The detection limit of the electrode is 6.3 × 10^? 7 mol L^?1. It has a very short response time (~ 10 s) and a useful working pH range of 2.6–9.4 for at least 2 months. The proposed membrane sensor shows excellent discriminating ability towards Tb³⁺ ions with regard to several alkali, alkaline earth, transition and heavy metal ions. To investigate the analytical applicability of the sensor, it was successfully applied to the determination of terbium in certified reference material.     

蔷薇红景天色素的提取及稳定性的研究

本文对蔷薇红景天色素的提取方法和色素的基本性质进行了研究。通过研究发现,红景天色素提取时95％(pH=3)的乙醇水溶液提取效果最佳,色素的最大吸收峰在314nm处;日光,温度和大多数金属离子Ca^2 ,Mg^2 ,Mn^2 ,Zn^2 等对红景天色素的稳定性影响不大,但是Na^ ,Fe^2 ,K^ 对红景天色素有增色的趋势。这种色素不仅耐光性好,而它的耐糖性也很好。虽然在碱性环境下,红景天色素pH稳定性较差,但在酸性条件下,其pH稳定性较好。通过初步研究发现该色素具有一定的开发利用价值。     

红枣色素的提取及稳定性的研究

本文对红枣色素的提取方法和色素的基本性质进行了研究。通过研究发现,所选用的16种不同的提取溶液当中,红枣色素在以50％（pH3）的乙醇水溶液提取时,效果最好,色素的最大吸收峰在320nm处;日光、温度、和大多数金属离予,对这种色素的稳定性无太大的影响,这种色素的耐糖性和耐光性很好。红枣色素的pH稳定性无论在酸性或在碱性条件下都很稳定。红枣色素稳定性不受人体所需的微量元素Ca^2＋、Na^＋、Fe^2＋、K^＋、Mg^2＋、Mn^2＋、Zn^2＋和Fe^3＋的影响。温度变化（20～100℃）也对色素稳定性几乎无影响。根据研究结果可以初步确定,红枣色素具备了作为天然色素使用的最基本的性能,可开发利用。     

Modeling the electronic band-structure of strained long-wavelength Type-II superlattices using the scattering matrix method

This study introduces a comprehensive theoretical framework for accurately calculating the electronic band-structure of strained long-wavelength InAs/GaSb type-II superlattices. Utilizing an eight-band Hamiltonian in conjunction with a scattering matrix method, the model effectively incorporates quantum confinement, strain effects, and interface states. This robust and numerically stable approach achieves exceptional agreement with experimental data, offering a reliable tool for analyzing and engineering the band structure of complex multilayer systems.     

Bimetal cup hydroforming of Al/St and Cu/St composites: Adaptive finite element analysis and experimental study

Journal of Mechanical Science and Technology - An adaptive Finite element analysis (FEA) was proposed in this paper for the industrial design of bimetal conical-cylindrical cup hydroforming....