Adsorptive performance of penta-bismuth hepta-oxide nitrate, Bi?O?NO?, for removal of methyl orange dye

The adsorption of methyl orange dye from aqueous solution onto penta-bismuth hepta-oxide nitrate, Bi(5)O(7)NO(3), synthesized by precipitation method, was studied in a batch adsorption system. The effects of operation parameters such as adsorbent dose, initial dye concentration, pH and temperature were investigated. The adsorption equilibrium and mechanism of adsorption was evaluated by Langmuir and Freundlich isotherm and different kinetic models, respectively. The results indicate that adsorption is highly dependent on all operation parameters. At optimum conditions, the adsorption capacity was found to be 18.9 mg/g. The adsorption data fits well with the Langmuir isotherm model indicating monolayer coverage of adsorbate molecules on the surface of Bi(5)O(7)NO(3). The kinetic studies show that the adsorption process is a second-order kinetic reaction. Although intra-particle diffusion limits the rate of adsorption, the multi-linearity plot of intra-particle model shows the importance of both film and intra-particle diffusion as the rate-limiting steps of the dye removal. Thermodynamic parameters show that the adsorption process is endothermic, spontaneous and favourable at high temperature.     

Location allocation modeling for healthcare facility planning in Malaysia

Malaysia has seen tremendous growth in the standard of living and household per capita income. The demand for a more systematic and efficient planning has become increasingly more important, one of the keys to achieving a high standard in healthcare. In this paper, a Maximal Covering Location Problem (MCLP) is used to study the healthcare facilities of one of the districts in Malaysia. We address the limited capacity of the facilities and the problem is formulated as Capacitated MCLP (CMCLP). We propose a new solution approach based on genetic algorithm to examine the percentage of coverage of the existing facilities within the allowable distance specified/targeted by Malaysian government. The algorithm was shown to generate good results when compared to results obtained using CPLEX version 12.2 on a medium size problem consisting of 179 nodes network. The algorithm was extended to solve larger network consisting of 809 nodes where CPLEX failed to produce non-trivial solutions. We show that the proposed solution approach produces significant results in determining good locations for the facility such that the population coverage is maximized.     

纳米In2O3／TiO2介孔复合体的制备及其光致发光性能研究

本论文利用尿素水解均匀沉淀法制备锐钛矿型纳米TiO2介孔粉体，然后在硫酸铟溶液中浸泡一周，并在650℃下退火处理5h，制得纳米In2O3／TiO2介孔复合体。采用X射线衍射（XRD）和光致发光（PL）谱表征In2O3／TiO2介孔复合体的组成结构和发光性能，并对相同温度退火处理下的介孔TiO2粉体进行比较，结果表明：经过650℃退火后，在激发波长380nm，发射波长570nm附近，纳米In2O3／TiO2介孔复合体产生荧光增强效应。     

DDFWS:一种新型分布式动态防火墙系统的研究与实现

文中对传统防火墙进行了深入的分析并指出了它们存在的问题和局限，在此基础上，提出了一种新型的分布式动态防火墙原型系统，并给出了系统的设计和实现，该原型系统具有广泛的适用性。     

基于多Agent的混合智能学习算法及

本文提出了基于多Agent的混合智能学习算法，将个体学习和群体学习有效地结合起来，并给出了该算法在RoboCup足球机器人仿真系统中的具体应用．实验结果表明了算法的可行性与有效性．     

集成型空间数据库技术探讨与应用实例

集成型空间数据库的构建过程中,常涉及到空间数据的非结构化特征问题。总结了目前克服此问题的两种技术,即面向对象技术与中间件技术,并对商业化中间件中的空间数据引擎作了标准性、存储结构与图层管理三方面分析。给出了采用空间数据引擎的应用实例,提出了急需解决的问题。
     

力矩电机自动调节的大量程数显卡卷尺测长技术

本文在数字显示卡尺技术和力矩电机技术的基础上，把卡尺量程扩大到20米做成卡卷尺，运用力矩电机作为卡卷尺的卷紧机构和保证光栅编码器标尺光栅平直度的施力元件，发展了力矩电机自动调节的大量程数字显示卡卷尺测长技术，同时为力矩电机设计了线性自动调节电流源，并在实际应用中检测了其测量精确度。     

常温磷化液的研制

常规磷化液中通常含有亚硝酸钠、氟化钠等有害物质.为改善环境,选用污染小的复合促进剂,研制了一种常温锌系磷化液,并应用正交试验法得到了磷化工作液的最佳配比,考察了磷化温度、磷化时间及复合促进剂对磷化质量的影响.磷化工作液的适宜配方为:工业氧化锌5.5g/L,工业氯酸钠2.5g/L,工业硫酸镍2.6g/L,复合促进剂4.0g/L.常温下试件在该磷化液中形成的膜层CuSO4点滴试验时间＞80 s,3%NaCl溶液浸渍时间＞6 h,室内挂片60d无明显锈蚀.     

基于r2法刀具偏移计算实现

本文详细介绍了r2法实现刀具偏移计算的基本原理和实施方法.     

Ni-Cr合金真空钎焊金刚石界面微结构分析

钎焊单层超硬磨料砂轮极高的结合强度和接近理想的锋利形貌 ,使它在生产应用中显示出传统砂轮无法比拟的优异性能。这种新型超硬磨料砂轮以其卓越的磨削性能必将逐步取代传统单层电镀砂轮。本文在真空炉中用钎焊的方法 ,用Ni Cr合金钎料 ,适当控制钎焊温度、保温时间和冷却速度 ,实现了金刚石与钢基体的高强度连接。并用深腐蚀的方法处理钎焊后的试样 ,用扫描电镜、X 射线能谱仪 ,结合X 射线衍射结构分析 ,对金刚石与钎料界面微区结构进行了分析。结果表明 :在钎焊过程中 ,钎料会在金刚石界面形成富铬层并与金刚石表面的C元素反应生成Cr7C3 和Cr3 C2 ,其中Cr7C3 呈笋状生长 ,Cr3 C2 呈片状生长。Ni Cr合金与金刚石的冶金结合 ,是实现金刚石和钢基体有高结合强度的主要因素。最后通过磨削对比实验确证了金刚石与钎料有较高的结合强度