Novel hexagonal two dimensional ZnO nanosheets were successfully and economically synthesized using zinc acetate and urea based on a facile microwave hydrothermal method. The structure, morphology and size of the ZnO nanosheets were investigated by X-ray diffraction (X-ray), field emission scanning electron microscopy (FESEM), energy dispersive analysis of x-ray (EDS), transmission electron microscopy (TEM), selected area electron diffraction (SAED) and Fourier transform infrared spectroscopy (FTIR). X-ray analysis showed that the obtained ZnO nanosheets are crystalline corresponding to the pure ZnO phase with an average particle size of 12 nm. Optical properties of ZnO nanosheets were investigated by UV-Vis absorption and photoluminescence (PL) techniques. The band gap energy of ZnO nanosheets was found to be 3.29 eV. The photoluminescence (PL) measurement shows a strong UV emission, blue emission and blue-green emission bands. ZnO nano sheets possess a higher photocatalytic activity leading to the degradation of methylene blue (MB). The ZnO nanosheets are expected to have new opportunities in vast research areas and for application in catalysts and optoelectronic devices. 相似文献
Compacts made from chemically grade Fe2O3 were fired at 1473K for 6 hrs. The fired compacts were isothermally reduced either by hydrogen or carbon monoxide at 1073–1373K. The O2 weight‐loss resulting from the reduction process was continuously recorded as a function of time using TGA technique, whereas the volume change at different reduction conditions was measured by displacement method. Porosity measurements, microscopic examination and X‐ray diffraction analysis were used to characterize the fired and reduced products. The rate of reduction at both the initial and final stages was increased with temperature. The reduction mechanism deduced from the correlations between apparent activation energy values, structure of partially reduced compacts and application of gas‐solid reaction models revealed the reduction rate (dr/dt) at both the initial and final stages. At early stages, the reduction was controlled by a combined effect of gaseous diffusion and interfacial chemical reaction mechanism, while at the final stages the interfacial chemical reaction was the rate determining step. In H2 reduction, maximum swelling (80%) was obtained at 1373K, which was attributed to the formation of metallic iron plates. In CO reduction, catastrophic swelling (255%) was obtained at 1198K due to the formation of metallic iron plates and whiskers. 相似文献
A study on the value metal character of Zr in 0.1 M solutions of H2SO4, HNO3, and H3PO4 has been performed using the anode potential as the primary variable in galvanostatic, potentiostatic, and capacity measurements. A method of surface pre-treatment, which suppresses both O2 evolution and metal dissolution, has been described. Kinetic parameters of oxide growth have been calculated. The results indicate that:
(i) the high field approximation is applicable following an exponential law, and
(ii) the height and activation distance of the energy barrier for ion transport through the oxide phase (Verwey model) are the same three acids.
Measurements have been also made on the dielectric breakdown of oxide, and this occurs at potentials above 200 V. Direct capacity measurements give similar results as those based on reciprocal capacity calculated from galvanostatic experiments. It is concluded that the dominant anodic oxide species is ZrO2 having a dielectric constant of 25. Open circuit potential measurements show that Zr is spontaneously oxidized in the three acids. 相似文献
The static bending behavior of porous functionally graded (PFG) micro-plate under the geometrically nonlinear analysis is studied in this article. A small-scale nonlinear solution is established using the Von-Kármán hypothesis and the modified couple stress theory (MCST). To obtain the deflection of the plate, the Reddy higher-order plate theory coupled with isogeometric analysis (IGA) is utilized. The distribution of porosities is assumed to be even and uneven across the plate’s thickness and the effective material properties of porous functionally graded micro-plate are calculated using the refined rule-of-mixture hypothesis. The influence of power index, porosity parameter and material length scale parameter on the nonlinear behaviors of static bending of porous FGM micro-plates are also investigated using several numerical examples.
Abstract: Data envelopment analysis (DEA) is a non‐parametric method for measuring the efficiency and productivity of decision‐making units (DMUs). On the other hand data mining techniques allow DMUs to explore and discover meaningful, previously hidden information from large databases. Classification and regression (C&R) is the commonly used decision tree in data mining. DEA determines the efficiency scores but cannot give details of factors related to inefficiency, especially if these factors are in the form of non‐numeric variables such as operational style in the banking sector. This paper proposes a framework to combine DEA with C&R for assessing the efficiency and productivity of DMUs. The result of the combined model is a set of rules that can be used by policy makers to discover reasons behind efficient and inefficient DMUs. As a case study, we use the proposed methodology to investigate factors associated with the efficiency of the banking sector in the Gulf Cooperation Council countries. 相似文献