Rhodium Complexed C2‐PAMAM Dendrimers Supported on Large Pore Davisil Silica as Catalysts for the Hydroformylation of Olefins

Polyamidoamine (PAMAM) dendrimers up to the third generation were grown for the first time on the surface of a large‐pore (18 nm) Davisil silica support. The supported dendrimers of generations 0, 1, 2 and 3 were phosphinomethylated and complexed with rhodium. All the generations were found to be very active for the hydroformylation of olefins. The hydroformylation of 1‐octene was accomplished with a turnover frequency of 1700 h⁻¹ at 70 °C. The G(1) material was found to be the most active when the different generations were compared at 50% conversion at 70 °C     

A new position regulation strategy for VTOL UAVs using IMU and GPS measurements

We propose a new position regulation strategy for VTOL-UAVs using IMU and GPS measurements. Since there is no sensor that measures the attitude, our approach does not rely on the knowledge (or reconstruction) of the system orientation as usually done in the existing literature. Instead, IMU and GPS measurements are directly incorporated in the control law. An important feature of the proposed strategy, is that the accelerometer is used to measure the apparent acceleration of the vehicle, as opposed to only measuring the gravity vector, which would otherwise lead to unexpected performance when the vehicle is accelerating (i.e. not in a hover configuration).     

Nanoporous zirconium oxide prepared using the supramolecular templating approach

Hexagonal (Hx-ZrO₂) and lamellar (L-ZrO₂) phases of zirconium oxide have been prepared using the supramolecular templating approach. Long chain primary alkyl amines led to the formation of lamellar phases, while quaternary ammonium surfactants gave hexagonal phases. The materials have been characterized by XRD, TG/DTG, IR, XPS, SEM and EDX techniques. The influence of various synthesis parameters such as (i) the ZrO₂ surfactant ratio, (ii) the surfactant/water ratio, (iii) the nature of surfactant, (iv) the crystallization temperature and (v) the crystallization time have been investigated. The final solid products were found to be thermally unstable regardless of their structure. Removal of the surfactant from the mesopores by solvent extraction without damaging the structure was not possible.     

Q2ABR: QoE‐aware adaptive video bit rate solution

In this paper, we propose a new adaptive bit rate (ABR) streaming method. This method is based on estimating and monitoring users' video streaming experience, their quality of experience (QoE). This ensures a good user QoE and optimises bandwidth utilisation by monitoring video buffer fill rate to ensure minimal data traffic. First, we achieve a QoE evaluation model based on network bandwidth, video segment representation, and dropped video frame rate parameters. Second, following our QoE evaluation model, we formulate an ABR method using the reinforcement learning (RL) paradigm to select video representations and using a breakpoint detection mechanism to monitor end‐user QoE variation. The proposed ABR method is called “QoE‐aware adaptive bit rate (Q2ABR)” and is composed of three individual modules, one for QoE estimation using machine learning methods, one for QoE variation monitoring using the breakpoint detection mechanism, and one for video representation selection using reinforcement learning. The design objective of Q2ABR is to ensure the overall QoE of these users while maintaining a minimum variation in the standard deviation of the users' QoE values. Third, the performance of the Q2ABR method is evaluated and compared with several existing ABR approaches in the literature using real traces that we collect on different transport scenarios (such as bus and train, among others). Since this method considers the user's perception of video quality as a regulator for optimising the overall video distribution network, good results are ensured in terms of the user's experience and buffer fill rate.     

Velocity‐free attitude stabilization with inertial vector measurements

This paper deals with the attitude stabilization problem of a rigid body, where neither the angular velocity nor the attitude is used in the feedback; only body‐referenced vector measurements are needed. The proposed control scheme is based on an angular velocity observer‐like system relying solely on vector measurements. The proposed controller ensures almost global asymptotic stability and provides some interesting performance properties through an appropriate tuning of the control gains. The performance and effectiveness of the proposed control scheme are illustrated via simulation results where the control gains are adjusted using a nonlinear optimization. Copyright © 2015 John Wiley & Sons, Ltd.     

A Comparative Study of Localization Methods in Indoor Environments

A comparative study, based on three different measurements (direction of ray arrival, time difference of arrival and received signal strength), to compute the unknown position of mobile stations in indoor environments is presented in this paper. The comparison is carried out considering the results of analyses in a real building in Madrid. To overcome the problems that arise in indoor areas due to the presence of non line of sight conditions, the fingerprinting technique is applied in each of the cases. Data for computations are provided by a simulation tool based on the uniform theory of diffraction and ray-tracing techniques. This information is stored in the fingerprinting database and contains information related to every mobile station, every reference node and every access point located inside the environment under analysis. Experimental results compare the mean error when localizing several mobile stations by using the three different approaches. The goal is to obtain high precision in the localization by means of alternative methods to the received signal strength classical measurement. These techniques will be useful in critical environments where high operational security requirement are demanded.     

Low-temperature processing and characterization of single-phase PZT powders by sol-gel method

A new sol-gel system using acetoin was developed and employed for the fabrication of PZT powders and films with compositions near the morphotropic phase boundary Pb(Zr_0.52Ti_0.48)O₃. Acetoin was used as chelating agent to replace the highly toxic methoxyethanol used in previous formulations. This route simplified the chemical processing of PZT-based solutions. Powders were completely crystallized by about 450 °C and contained the ferroelectric perovskite single phase. The firing temperature and time were to be the most important variables. Metallic lead formed only when excess Pb was incorporated. The precursor and the heat-treated powders have been characterized by using thermal analysis and X-ray diffractometry (XRD) studies. The average particle size, as measured from X-ray line broadening, was ∼35 nm.