MedHySol: Future federator project of massive production of solar hydrogen

Mediterranean Hydrogen Solar (MedHySol) is a federator project for development of a massive hydrogen production starting from solar energy and its exportation within a framework of a Euro–Maghrebian Cooperation project for industrial and energetic needs in the Mediterranean basin. The proposal of this project is included in the Algiers Declaration's on Hydrogen from Renewable Origin following the organization of the first international workshop on hydrogen which was held in 2005. Algeria is the privileged site to receive the MedHySol platform. The objective of the first step of the project is to realize a technological platform allowing the evaluation of emergent technologies of hydrogen production from solar energy with a significant size (10–100 kW) and to maintain the development of energetic rupture technologies. The second step of the project is to implement the most effective and less expensive technologies to pilot great projects (1–1000 MW). In this article we present the potentialities and the feasibility of MedHySol, as well as the fundamental elements for a scientific and technical supervision of this great project.     

A fair comparison of SAC-OCDMA system configurations based on two dimensional cyclic shift code and spectral direct detection

This paper investigates shortcomings that limit the performance of optical code division multiple access (OCDMA) systems including the low cardinality and data rate as well as the high power at reception. The main drawback for such systems known as multiple access interference accompanying by phase induced intensity noise is also investigated to effeciencly propose a novel two dimensional cyclic shift (2D-CS) code to be implemented in non-coherent OCDMA systems. The developed code is based on a one dimensional cyclic shift (1D-CS) code previously provided by research works processing spectral amplitude coding for optical code division multiple access (SAC-OCDMA) systems. Numerical results obtained by this study are therefore compared to previous studies employing different codes like two dimensional extended double weight (2D-EDW), two dimensional flexible cross correlation/modified double weight (2D-FCC/MDW), two dimensional perfect difference (2D-PD), two dimensional diluted perfect difference (2D-DPD), two dimensional multi service (2D-MS) and two dimensional zero cross correlation/multi diagonal (2D-ZCC/MD) codes. Accordingly, it is demonstrated that the proposed 2D-CS code outperforms all codes given previously in terms of system capacity where the small increasing percentage is about 40% compared to 2D-ZCC/MD and 2D-MS. Systems using 2D-CS code can support until 203 simultaneous users with a total code length equal to 171. System performance investigation leads to a BER and Q-Factor closely to1.0E?12 and 1.0E?27, and 6.6 dB and 10.6 dB at 20 km of single mode fiber length using white light source and Laser, respectively. Furthermore, such a code can be easily adopted by OCDMA systems for a long distance up to approximately 55 and 100 km.

     

Partial oxidation of methane on co-precipitated Ni–Mg/Al catalysts modified with copper or iron

Methane transformation to hydrogen and synthesis gas (CO + H₂) by heterogenous catalysts can play an important role to secure the supply of energy, chemicals and fuels in the future. Methane is the main constituent of natural gas and biogas and it is also found in crystalline hydrates at the continental slopes of many oceans. In view of this vast reserves and resources, the use of methane as chemical feedstock has to be intensified. In this present work, (NiMg)Al catalysts doped with Fe or Cu, prepared by co-precipitation method and characterized by different techniques, were studied in the partial oxidation of methane (T_reaction = 750 °C, CH₄/O₂ ratio = 2). The effect of catalyst composition and pre-treatment conditions of these catalysts were investigated. Also, these catalysts show a very high activity and selectivity in the partial oxidation reaction, which depends on the conditions of catalysts preparation. The obtained results indicated increasing of activity and selectivity with decreasing calcination temperature and increasing nickel and aluminium contents in the catalysts composition. The solid doped with iron constituted the best catalyst for the total oxidation of methane and for the water–gas shift reaction. On the other hand, the addition of copper was remarkably improved the catalytic performances of the (NiMg)Al solid. So, the presence of this element supported the partial oxidation of methane with production of syngas (CO + H₂). With the addition of iron or copper for the catalyst composition, we were observed (in our previous work) the possibility of formation of NiM (M = Fe or Cu) alloy which increased nickel particles dispersion. In the case of copper, the reducibility of NiO was also assisted (TPR results) which increased catalytic activity in partial oxidation of methane.     

Adaptive MRAC-based direct torque control with SVM for sensorless induction motor using adaptive observer

This paper presents an improved direct torque control (DTC) method for induction motor (IM) drive. The main drawback of the conventional DTC is the use of hysteresis comparators which leads to high torque and flux ripples. The improvement in this paper includes using the space vector modulation to preserve a constant switching frequency and to reduce totally flux and torque ripples. Besides, the torque and stator flux regulation will be done based on model reference adaptive control (MRAC) strategy to ensure a robust control against external disturbance and less sensitivity from machine parameter variation unlike the conventional proportional-integral (PI) controllers. Furthermore, a design of an adaptive observer based on Lyapunov stability is presented for speed/flux and load torque estimation. The observer can improve the control performances and decrease the cost and increase reliability of the global control system by reducing the number of sensors. The proposed strategy will be examined under simulation tests using Matlab/Simulink and experimental implementation with real-time interface (RTI) based on dSpace 1104 board.     

Experimental investigation of solar tower with chimney effect installed in CRTEn,Tunisia

This paper studies the performance of a solar tower power plant (STPP) with chimney effect based on renewable energy proposed for electricity production. That's way, a solar tower prototype was constructed and tested in the Research and Technology Centre of Energy (CRTEn), Borj Cédria, northern Tunisia.The design involves heating air using solar energy and the chimney effect to raise the hot air up the chimney stack. The hot air velocity increases by the use of a convergent nozzle to reach a suitable velocity which can run the wind turbine. The kinetic energy of the hot air is then converted to electricity by the wind turbine.During this study, the influence of the climatic conditions of Borj Cédria site (insulation, ambient temperature) as well as the chimney height and the collector diameter on the amount of electricity production were investigated.The distribution and the evolution of the temperature at different positions of the prototype as well as the electrical energy produced were determined.The results reveal that when the temperatures reach 45 °C, the electric power reaches an average value of about 0.3 W/m² for a solar tower prototype with 8 m of diameter and 2 m of height chimney.     

Combination of PDMS microfilters and micromixers based on flexible thermoplastic films for size sorting and mixing of microparticles

We present a study for the development of flexible microfilters based on sealing microstructured poly(dimethylsiloxane) (PDMS) to different functionalized thermoplastic films [polyimide (PI), polyethylene naphthalate (PEN), and polyethylene terephthalate (PET)]. The microfilter was manufactured by soft‐lithography and replica molding and then combined with plasma activation and chemical treatment using 3‐(aminopropyl)triethoxysilane (APTES). To demonstrate the functionality of the PDMS microfilters, poly(lactic‐co‐glycolic acid) (PLGA) microparticles (MPS) were filtered through the microfluidic device based on the three thermoplastic films. Subsequently, the mixing capabilities of a passive PDMS micromixer was observed with the injection of polymeric MPS (fluorescent and nonfluorescent) as fluidic mixers are not generally effective at mixing particles. On mixing nonfluorescent MPS (～<10–30 µm in diameter) a mixing performance of 13.3% at 5 mm was observed. Therefore, a PDMS microfiltering device was integrated with a PDMS micromixer using a simple and cost effective home‐made polymeric connector for filtration at a size sorting of 11 µm. The results exhibit that the combination of the two microfluidic devices can be achieved with size sorting and mixing of MPS with an improved mixing performance of 62.5% at 3 mm. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42088.     

Influence of regeneration conditions on the cyclic performance of amine-grafted mesoporous silica for CO2 capture: An experimental and statistical study

This work deals with the behavior of amine-grafted mesoporous silica (referred to as TRI-PE-MCM-41) throughout adsorption–desorption cycles in the presence of 5% CO₂/N₂ using various regeneration conditions in batch experiments. The criteria proposed to determine the optimum regeneration conditions are the working adsorption capacity, the rate of desorption and the change of adsorption capacity between consecutive cycles. Using a 2³ factorial design of experiments, the impact on the performance of the adsorbent of different levels of temperature, pressure, and flow rate of purge gas during desorption was determined. It was found that all the parameters under study have a statistically significant influence on the working adsorption capacity, but only temperature is influential with respect to desorption rate. Regeneration using temperature swing was found to be attractive, as the highest CO₂ adsorption capacity (1.95 mmol g^?1) and the fastest desorption rate (9.82×10^?4 mmol g^?1 s^?1) occurred when desorption was carried out at 150 °C. However, if vacuum is applied, regeneration can be achieved at a temperature as low as 70 °C with only a 13% penalty in terms of working adsorption capacity. It was also demonstrated that under the proper regeneration conditions, TRI-PE-MCM-41 is stable over 100 adsorption–desorption cycles.     

Cancer prognostics by direct detection of p53-antibodies on gold surfaces by impedance measurements

The identification and measurement of biomarkers is critical to a broad range of methods that diagnose and monitor many diseases. Serum auto-antibodies are rapidly becoming interesting targets because of their biological and medical relevance. This paper describes a highly sensitive, label-free approach for the detection of p53-antibodies, a prognostic indicator in ovarian cancer as well as a biomarker in the early stages of other cancers. This approach uses impedance measurements on gold microelectrodes to measure antibody concentrations at the picomolar level in undiluted serum samples. The biosensor shows high selectivity as a result of the optimization of the epitopes responsible for the detection of p53-antibodies and was validated by several techniques including microcontact printing, self-assembled-monolayer desorption ionization (SAMDI) mass spectrometry, and adhesion pull-off force by atomic force microscopy (AFM). This transduction method will lead to fast and accurate diagnostic tools for the early detection of cancer and other diseases.     

Preparation and characterization of CeO2–TiO2 support for Ru catalysts: Application in CWAO of p-hydroxybenzoic acid

The catalytic wet air oxidation of aqueous solutions of p-hydroxybenzoic acid has been carried out over CeO₂–TiO₂ supported ruthenium catalysts (Ru/Ce–Ti) at 140 °C and 50 bar of air. High activity of ruthenium supported catalysts was observed. It was found that the decrease of the molar ratio Ce/Ti from 3 to 1/3, improves the activity of Ru catalysts. The activity of the samples decreases in the following order: Ru/Ce–Ti (1/3) > Ru/CeO₂ ≈ Ru/TiO₂ > Ru/TiO₂DT51. Characterization of samples was performed by means of N₂ adsorption–desorption, XRD, UV–visible, TPR, SEM and TEM.     

Effects of frying on the fatty acid composition in farmed and wild gilthead sea bream (Sparus aurata)

The effects of frying in soybean (FWSO) and olive oils (FWOO) on the fatty acid composition of farmed and wild gilthead sea bream Sparus aurata were evaluated. The fat content increased with both frying treatments. However, after FWOO the moisture content of the fish was reduced to a greater extent than that in fish FWSO. The concentration of saturated fatty acids (SFA) decreased significantly during both frying processes ( P  < 0.01). However, the concentration of monounsaturated fatty acids (MUFA) increased significantly in fish fried in olive oil ( P  < 0.01). The fried fish contained a higher level of n-6 polyunsaturated fatty acids (PUFA) and a lower level of n-3 PUFA compared to raw fish. The n-3/n-6 ratio decreased in wild fish FWSO and FWOO from 0.94 ± 0.08 to 0.15 ± 0.01 and 0.15 ± 0.02, respectively. In farmed bream, the ratios decreased from 2.51 ± 0.03 to 0.18 ± 0.03 and 0.36 ± 0.01, respectively. The concentration of trans fatty acids decreased significantly in both fish types after frying ( P  < 0.05). The frying process widely affected the EPA and DHA content, limiting the positive effects of n-3 PUFA.