Pulsed laser deposition of La0.67Ca0.33MnO3 thin films on LiNbO3 and surface acoustic wave studies

Surface Acoustic Waves on piezoelectric substrates can be used to investigate the dynamic conductivity of thin films in a non-contact and very sensitive way, especially at low conductivities. Here, we report on such surface acoustic wave studies to characterize thin manganite film like La_0.67Ca_0.33MnO₃, exhibiting a Jan Teller effect with a strong electron phonon interaction and a metal insulator transition at high temperatures.

We report on the deposition of La_0.67Ca_0.33MnO₃ on piezoelectric substrates (LiNbO₃ in different crystal cuts, employing a pulsed laser deposition technique. The structural quality of the thin films are examined by X-Ray Diffraction, Scanning Electron Microscope and Energy Dispersive X-ray spectroscopy. For the electrical characterization, we employ the surface acoustic wave technique, accompanied by conventional direct current resistance measurements for comparison.     

Polyol method for the preparation of nanosized Gd2O3, boehmite and other oxides

A modified microwave-assisted polyol method was applied to prepare nanoparticulate ceramic powders of different oxides, i.e. Gd₂O₃, AlO(OH) (boehmite) and TiO₂. Due to the good dielectric properties of the utilised solvents, such as ethylene glycol, diethylene glycol and 1,4 butanediol, a significant decrease in reaction time was achieved under microwave heating. In the case of AlO(OH) and Gd₂O₃, <5 nm primary particle size were obtained. Boehmite was found to be intercalated with the solvent. The general applicability of the process is shown and the advantages in terms of properties and processibility are described. The powders thus prepared were investigated using X-ray diffractometry, electron microscopy and physisorption.     

Improving Point Cloud Accuracy Obtained from a Moving Platform for Consistent Pile Attack Pose Estimation

We present a perception system for enabling automated loading with waist-articulated wheel loaders. To enable autonomous loading of piled materials, using either above-ground wheel loaders or underground load-haul-dump vehicles, 3D data of the pile shape is needed. However, using common 3D scanners, the scan data is distorted while the wheel loader is moving towards the pile. Existing methods that make use of 3D scan data (for autonomous loading as well as tasks such as mapping, localisation, and object detection) typically assume that each 3D scan is accurate. For autonomous robots moving over rough terrain, it is often the case that the vehicle moves a substantial amount during the acquisition of one 3D scan, in which case the scan data will be distorted. We present a study of auto-loading methods, and how to locate piles in real-world scenarios with nontrivial ground geometry. We have compared how consistently each method performs for live scans acquired in motion, and also how the methods perform with different view points and scan configurations. The system described in this paper uses a novel method for improving the quality of distorted 3D scans made from a vehicle moving over uneven terrain. The proposed method for improving scan quality is capable of increasing the accuracy of point clouds without assuming any specific features of the environment (such as planar walls), without resorting to a “stop-scan-go” approach, and without relying on specialised and expensive hardware. Each new 3D scan is registered to the preceding using the normal-distributions transform (NDT). After each registration, a mini-loop closure is performed with a local, per-scan, graph-based SLAM method. To verify the impact of the quality improvement, we present data that shows how auto-loading methods benefit from the corrected scans. The presented methods are validated on data from an autonomous wheel loader, as well as with simulated data. The proposed scan-correction method increases the accuracy of both the vehicle trajectory and the point cloud. We also show that it increases the reliability of pile-shape measures used to plan an efficient attack pose when performing autonomous loading.     

NUMERICAL INVESTIGATION OF TRANSPORT PHENOMENA IN THE FUSION ZONE OF LASER BEAM WELDED JOINTS

The development of a steady-state process model for a numerical study of transport phenomena in the fusion zone of deep penetration laser beam welded joints is described. Based on the conservation equations of energy, momentum, and mass in dimensionless form, the three-dimensional modeling considers viscous, buoyancy, and friction forces as well as surface tension gradients. The developed simulation program enables the prediction of the local temperature and velocity distribution in the molten material. Consequently, the resultant weld pool dimensions dependent on the characteristic dimensionless groups can be derived.     

Fabrication Agency: Landesgartenschau Exhibition Hall

Advances in computation challenge established design approaches in architecture through a much deeper integration of form generation and materialisation. Tobias Schwinn , Research Associate at the Institute for Computational Design (ICD), University of Stuttgart, and Guest-Editor Achim Menges , Director of the ICD, introduce how the potentials and constraints of robotic fabrication can now be explored as generative drivers in agent-based design. This enables architectural innovation in unison with fabricability, structural capacity and spatial performance, as demonstrated by the Landesgartenschau Exhibition Hall in Schwäbisch Gmu"nd, Germany, the world's first building with a robotically fabricated segmented timber shell as its primary structure.     

Untersuchungen zur Tautomerie von o,o'-Dihydroxy-azofarbstoffen der Eriochrom-Reihe

Investigations on the Tautomerism of o,o'-Dihydroxy Azo Dyes of the Eriochrome Type Investigation of the u.v.-vis-, ¹H- and ¹³C-n.m.r. spectra of the title substances and the isomers 3 and 3p at different pH-values and in different solvent mixtures as well as of O,O'-dimethyl derivatives of 2 and 3 show that in aqueous solution as well the monoanions as the trianions exist in the azo forms only. The dianions exist in dependence on the solvents as mixtures of tautomers. The results of PPP calculations for different prototropic structures are in good accordance with the experimental results.     

Quantenchemische Untersuchungen zur Molekül- und Elektronenstruktur einfacher Azomethinimine und verwandter Verbindungen

Quantum Chemical Investigations of the Molecular and Electronic Structure of Simple Azomethine Imines and Related Compounds The molecular and electronic structure of simple azomethinimines are investigated by means of MINDO/3 and CNDO/2 calculations. The calculated molecular geometry is compared with X-ray results obtained for these compounds. Except for the NN-bond lengths MINDO/3 satisfactorily describes the molecular structure of azomethinimine and related π-electronic systems. The charges at the atoms along the conjugated chain are alternating as in polymethines. The terminal carbon atom carries a negative charge. This charge brings about an appreciable shielding of this carbon atom such as found in the ¹³C-n.m.r. spectrum. This result does not contradict a stabilization of azomethinimines in the crystal via = CH…︁OC interactions.     

Analysis of microRNAs in Exosomes of Breast Cancer Patients in Search of Molecular Prognostic Factors in Brain Metastases

Brain metastases are the most severe tumorous spread during breast cancer disease. They are associated with a limited quality of life and a very poor overall survival. A subtype of extracellular vesicles, exosomes, are sequestered by all kinds of cells, including tumor cells, and play a role in cell-cell communication. Exosomes contain, among others, microRNAs (miRs). Exosomes can be taken up by other cells in the body, and their active molecules can affect the cellular process in target cells. Tumor-secreted exosomes can affect the integrity of the blood-brain barrier (BBB) and have an impact on brain metastases forming. Serum samples from healthy donors, breast cancer patients with primary tumors, or with brain, bone, or visceral metastases were used to isolate exosomes and exosomal miRs. Exosomes expressed exosomal markers CD63 and CD9, and their amount did not vary significantly between groups, as shown by Western blot and ELISA. The selected 48 miRs were detected using real-time PCR. Area under the receiver-operating characteristic curve (AUC) was used to evaluate the diagnostic accuracy. We identified two miRs with the potential to serve as prognostic markers for brain metastases. Hsa-miR-576-3p was significantly upregulated, and hsa-miR-130a-3p was significantly downregulated in exosomes from breast cancer patients with cerebral metastases with AUC: 0.705 and 0.699, respectively. Furthermore, correlation of miR levels with tumor markers revealed that hsa-miR-340-5p levels were significantly correlated with the percentage of Ki67-positive tumor cells, while hsa-miR-342-3p levels were inversely correlated with tumor staging. Analysis of the expression levels of miRs in serum exosomes from breast cancer patients has the potential to identify new, non-invasive, blood-borne prognostic molecular markers to predict the potential for brain metastasis in breast cancer. Additional functional analyzes and careful validation of the identified markers are required before their potential future diagnostic use.